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Commission Directive 2002/72/EC (repealed)Dangos y teitl llawn

Commission Directive 2002/72/EC of 6 August 2002 relating to plastic materials and articles intended to come into contact with foodstuffs (Text with EEA relevance) (repealed)

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[X1ANNEX II U.K. LIST OF MONOMERS AND OTHER STARTING SUBSTANCES WHICH MAY BE USED IN THE MANUFACTURE OF PLASTIC MATERIALS AND ARTICLES

GENERAL INTRODUCTION U.K.

1. This Annex contains the list of monomers or other starting substances. The list includes: U.K.

  • substances undergoing polymerisation, which includes polycondensation, polyaddition or any other similar process, to manufacture macromolecules,

  • natural or synthetic macromolecular substances used in the manufacture of modified macromolecules, if the monomers or the other starting substances required to synthesise them are not included in the list,

  • substances used to modify existing natural or synthetic macromolecular substances.

[F12. The following substances are not included even if they are intentionally used and are authorised: U.K.

(a)

salts (including double salts and acid salts) of aluminium, ammonium, calcium, iron, magnesium, potassium and sodium of authorised acids, phenols or alcohols. However, names containing … acid(s), salts appear in the lists, if the corresponding free acid(s) is (are) not mentioned;

(b)

salts (including double salts and acid salts) of zinc of authorised acids, phenols or alcohols. For these salts a Group SML = 25 mg/kg (expressed as Zn) apply. The same restriction for Zn applies to:

(i)

substances whose name contains … acid(s), salts which appear in the lists, if the corresponding free acid(s) is (are) not mentioned,

(ii)

substances referred to in note 38 of Annex VI.]

3. The list also does not include the following substances although they may be present: U.K.

(a)

substances which could be present in the finished product as:

  • impurities in the substances used,

  • reaction intermediates,

  • decomposition products;

(b)

oligomers and natural or synthetic macromolecular substances as well as their mixtures, if the monomers or starting substances required to synthesise them are included in the list;

(c)

mixtures of the authorised substances.

The materials and articles which contain the substances indicated under points (a), (b) and (c) shall comply with the requirements stated in Article 2 of Directive 89/109/EEC.

4. Substances shall be of good technical quality as regards the purity criteria. U.K.

5. The list contains the following information: U.K.

  • column 1 (Ref. No): the EEC packaging material reference number of the substances on the list,

  • column 2 (CAS No): the CAS (Chemical Abstracts Service) registry number,

  • column 3 (Name): the chemical name,

  • column 4 (Restrictions and/or specifications): These may include:

    • specific migration limit (SML),

    • maximum permitted quantity of the substance in the finished material or article (QM),

    • maximum permitted quantity of the substance in the finished material or article expressed as mg per 6 dm 2 of the surface in contact with foodstuffs (QMA),

    • any other restriction specifically mentioned,

    • any type of specifications related to the substance or to the polymer.

6. If a substance appearing on the list as an individual compound is also covered by a generic term, the restrictions applying to this substance shall be those indicated for the individual compound. U.K.

7. Where there is any inconsistency between the CAS number and the chemical name, the chemical name shall take precedence over the CAS number. If there is an inconsistency between the CAS number reported in EINECS and the CAS Registry, the CAS number in the CAS Registry shall apply. U.K.

8. A number of abbreviations or expressions are used in column 4 of the table, the meanings of which are as follows: U.K.

DL

=

Detection limit of the method of analysis;

FP

=

Finished material or article;

NCO

=

Isocyanate moiety;

ND

=

not detectable. For the purpose of this Directive not detectable means that the substance should not be detected by a validated method of analysis which should detect it at the detection limit (DL) specified. If such a method does not currently exist, an analytical method with appropriate performance characteristics at the detection limit may be used, pending the development of a validated method;

[F2QM

=

Maximum permitted quantity of the residual substance in the material or article. For the purpose of this Directive the quantity of the substance in the material or article shall be determined by a validated method of analysis. If such a method does not currently exist, an analytical method with appropriate performance characteristics at the specified limit may be used, pending the development of a validated method;]

QM(T)

=

Maximum permitted quantity of the residual substance in the material or article expressed as total of moiety or substance(s) indicated. For the purpose of this Directive the quantity of the substance in the material or article should be determined by a validated method of analysis. If such a method does not currently exist, an analytical method with appropriate performance characteristics at the specified limit may be used, pending the development of a validated method;

QMA

=

Maximum permitted quantity of the residual substance in the finished material or article expressed as mg per 6 dm 2 of the surface in contact with foodstuffs. For the purpose of this Directive the quantity of the substance in the surface of the material or article should be determined by a validated method of analysis. If such a method does not currently exist, an analytical method with appropriate performance characteristics at the specified limit may be used, pending the development of a validated method;

QMA(T)

=

Maximum permitted quantity of the residual substance in the material or article expressed as mg of total of moiety or substance(s) indicated per 6 dm 2 of the surface in contact with foodstuffs. For the purpose of this Directive the quantity of the substance in the surface of the material or article should be determined by a validated method of analysis. If such a method does not currently exist, an analytical method with appropriate performance characteristics at the specified limit may be used, pending the development of a validated method;

SML

=

Specific migration limit in food or in food simulant, unless it is specified otherwise. For the purpose of this Directive the specific migration of the substance should be determined by a validated method of analysis. If such a method does not currently exist, an analytical method with appropriate performance characteristics at the specified limit may be used, pending the development of a validated method;

SML(T)

=

Specific migration limit in food or in food simulant expressed as total of moiety or substance(s) indicated. For the purpose of this Directive the specific migration of the substances should be determined by a validated method of analysis. If such a method does not currently exist, an analytical method with appropriate performance characteristics at the specified limit may be used, pending the development of a validated method.

Section A U.K.

List of authorised monomers and other starting substances

Ref. No. CAS No Name Restrictions and/or specifications
(1) (2) (3) (4)
10030 000514-10-3 Abietic acid
10060 000075-07-0 Acetaldehyde SML(T) = 6 mg/kg ( 2 )
10090 000064-19-7 Acetic acid
10120 000108-05-4 Acetic acid, vinyl ester SML = 12 mg/kg
10150 000108-24-7 Acetic anhydride
10210 000074-86-2 Acetylene
[F310599/90A 061788-89-4 Acids, fatty, unsaturated (C 18 ), dimers, distilled QMA(T) = 0,05 mg/6 dm 2 ( 27 )
10599/91 061788-89-4 Acids, fatty, unsaturated (C 18 ), dimers, non distilled QMA(T) = 0,05 mg/6 dm 2 ( 27 )
10599/92A 068783-41-5 Acids, fatty, unsaturated (C 18 ), dimers, hydrogenated, distilled QMA(T) = 0,05 mg/6 dm 2 ( 27 )
10599/93 068783-41-5 Acids, fatty, unsaturated (C 18 ), dimers, hydrogenated, non distilled QMA(T) = 0,05 mg/6 dm 2 ( 27 )]
10630 000079-06-1 Acrylamide SML = ND (DL = 0,01 mg/kg)
10660 015214-89-8 2-Acrylamido-2-methylpropanesulphonic acid SML = 0,05 mg/kg
10690 000079-10-7 Acrylic acid [F4SML(T) = 6 mg/kg ( 36 )]
10750 002495-35-4 Acrylic acid, benzyl ester [F4SML(T) = 6 mg/kg ( 36 )]
10780 000141-32-2 Acrylic acid, n-butyl ester [F4SML(T) = 6 mg/kg ( 36 )]
10810 002998-08-5 Acrylic acid, sec-butyl ester [F4SML(T) = 6 mg/kg ( 36 )]
10840 001663-39-4 Acrylic acid, tert-butyl ester [F4SML(T) = 6 mg/kg ( 36 )]
[ F5 ]
[F411005 012542-30-2 Acrylic acid, dicyclopentenyl ester QMA = 0,05 mg/6 dm 2]
11245 002156-97-0 Acrylic acid, dodecyl ester SML = 0,05 mg/kg ( 1 )
11470 000140-88-5 Acrylic acid, ethyl ester [F4SML(T) = 6 mg/kg ( 36 )]
[F411500 000103-11-7 Acrylic acid, 2-ethylhexyl ester SML = 0,05 mg/kg]
11510 000818-61-1 Acrylic acid, hydroxyethyl ester See Acrylic acid, monoester with ethyleneglycol
11530 [F200999-61-1] Acrylic acid, 2-hydroxypropyl ester [F2QMA = 0,05 mg/6 dm 2 for the sum of acrylic acid, 2-hydroxypropyl ester and acrylic acid, 2-hydroxyisopropyl ester and in compliance with the specifications laid down in Annex V]
11590 000106-63-8 Acrylic acid, isobutyl ester [F4SML(T) = 6 mg/kg ( 36 )]
11680 000689-12-3 Acrylic acid, isopropyl ester [F4SML(T) = 6 mg/kg ( 36 )]
11710 000096-33-3 Acrylic acid, methyl ester [F4SML(T) = 6 mg/kg ( 36 )]
11830 000818-61-1 Acrylic acid, monoester with ethyleneglycol [F4SML(T) = 6 mg/kg ( 36 )]
11890 002499-59-4 Acrylic acid, n-octyl ester [F4SML(T) = 6 mg/kg ( 36 )]
11980 000925-60-0 Acrylic acid, propyl ester [F4SML(T) = 6 mg/kg ( 36 )]
12100 000107-13-1 Acrylonitrile SML = ND (DL= 0,020 mg/kg, analytical tolerance included)
12130 000124-04-9 Adipic acid
12265 004074-90-2 Adipic acid, divinyl ester QM = 5 mg/kg in FP. Or use only as comonomer
12280 002035-75-8 Adipic anhydride
12310 Albumin
12340 Albumin, coagulated by formaldehyde
12375 Alcohols, aliphatic, monohydric, saturated, linear, primary (C 4 -C 22 )
12670 002855-13-2 1-Amino-3-aminomethyl-3,5,5-trimethylcyclohexane SML = 6 mg/kg
12761 000693-57-2 12-Aminododecanoic acid SML= 0,05 mg/kg
12763 000141-43-5 2-Aminoethanol SML = 0,05 mg/kg. Not for use in polymers contacting foods for which simulant D is laid down in Directive 85/572/EEC and for indirect food contact only, behind the PET layer
12765 084434-12-8 N-(2-Aminoethyl)-beta-alanine, sodium salt SML= 0,05 mg/kg
[F412786 000919-30-2 3-Aminopropyltriethoxysilane Residual extractable content of 3-aminopropyltriethoxysilane to be less than 3 mg/kg filler. To be used only for the reactive surface treatment of inorganic fillers]
12788 002432-99-7 11-Aminoundecanoic acid SML= 5 mg/kg
12789 007664-41-7 Ammonia
12820 000123-99-9 Azelaic acid
12970 004196-95-6 Azelaic anhydride
13000 001477-55-0 1,3-Benzenedimethanamine SML= 0,05 mg/kg
13060 004422-95-1 1,3,5-Benzenetricarboxylic acid trichloride QMA = 0,05 mg/6 dm 2 (measured as 1,3,5-Benzenetricarboxylic acid)
13075 000091-76-9 Benzoguanamine See 2,4-Diamino-6-phenyl-1,3,5-triazine
13090 000065-85-0 Benzoic acid
13150 000100-51-6 Benzyl alcohol
13180 000498-66-8 Bicyclo[2.2.1]hept-2-ene (=Norbornene) SML= 0,05 mg/kg
13210 001761-71-3 Bis(4-aminocyclohexyl)methane SML= 0,05 mg/kg
[F413317 132459-54-2 N,N′-Bis[4-(ethoxycarbonyl)phenyl]-1,4,5,8-naphthalenetetracarboxydiimide SML = 0,05 mg/kg. Purity > 98,1 % (w/w). To be used only as co-monomer (max 4 %) for polyesters (PET, PBT)]
[F313323 000102-40-9 1,3-Bis(2-hydroxyethoxy)benzene SML = 0,05 mg/kg]
13326 000111-46-6 Bis(2-hydroxyethyl)ether See Diethyleneglycol
13380 000077-99-6 2,2-Bis(hydroxymethyl)-1-butanol See 1,1,1-Trimethylolpropane
13390 000105-08-8 1,4-Bis(hydroxymethyl)cyclohexane
13395 004767-03-7 2,2-Bis(hydroxymethyl)propionic acid QMA = 0,05 mg/6 dm 2
13480 000080-05-7 2,2-Bis(4-hydroxyphenyl)propane [F2SML(T) = 0,6 mg/kg ( 28 )]
13510 001675-54-3 2,2-Bis(4-hydroxyphenyl)propane bis(2,3-epoxypropyl) ether (=BADGE) According to Commission Directive 2002/16/EC of 20 February 2002 on the use of certain epoxy derivatives in materials and articles intended to come into contact with foodstuffs ( OJ L 51, 22.2.2002, p. 27 )
13530 038103-06-9 2,2-Bis(4-hydroxyphenyl)propane bis(phthalic anhydride) SML = 0,05 mg/kg
13550 000110-98-5 Bis(hydroxypropyl) ether See Dipropyleneglycol
13560 0005124-30-1 Bis(4-isocyanatocyclohexyl)methane See Dicyclohexylmethane-4,4′-diisocyanate
13600 047465-97-4 3,3-Bis(3-methyl-4-hydroxyphenyl)2-indolinone SML = 1,8 mg/kg
13607 000080-05-7 Bisphenol A See 2,2-Bis(4-hydroxyphenyl)propane
13610 001675-54-3 Bisphenol A bis(2,3-epoxypropyl) ether See 2,2-Bis(4-hydroxyphenyl)propane bis(2,3-epoxypropyl) ether
13614 038103-06-9 Bisphenol A bis(phthalic anhydride) See 2,2-Bis(4-hydroxyphenyl)propane bis(phthalic anhydride)
13617 000080-09-1 Bisphenol S See 4,4′-Dihydroxydiphenyl sulphone
13620 010043-35-3 Boric acid SML(T) = 6 mg/kg ( 23 ) (expressed as Boron) without prejudice to the provisions of Directive 98/83/EC on water for human consumption ( OJ L 330, 5.12.1998, p. 32 ).
13630 000106-99-0 Butadiene QM = 1 mg/kg in FP or SML = not detectable (DL = 0,020 mg/kg, analytical tolerance included)
13690 000107-88-0 1,3-Butanediol
13720 000110-63-4 1,4-Butanediol [F1SML(T) = 5 mg/kg ( 24 )]
13780 002425-79-8 1,4-Butanediol bis(2,3-epoxypropyl)ether QM = 1 mg/kg in FP (expressed as Epoxy group, Mw = 43)
13810 000505-65-7 1,4-Butanediol formal QMA = 0,05 mg/6 dm 2
13840 000071-36-3 1-Butanol
13870 000106-98-9 1-Butene
13900 000107-01-7 2-Butene
13932 000598-32-3 3-Buten-2-ol QMA = ND (DL = 0,02 mg/6 dm 2 ) To be used only as a comonomer for the preparation of polymeric additive
14020 000098-54-4 4-tert-Butylphenol SML = 0,05 mg/kg
14110 000123-72-8 Butyraldehyde
14140 000107-92-6 Butyric acid
14170 000106-31-0 Butyric anhydride
14200 000105-60-2 Caprolactam SML(T) = 15 mg/kg ( 5 )
14230 002123-24-2 Caprolactam, sodium salt SML(T) = 15 mg/kg ( 5 ) (expressed as Caprolactam)
[F414260 000502-44-3 Caprolactone SML = 0,05 mg/kg (expressed as the sum of caprolactone and 6-hydroxyhexanoic acid)]
14320 000124-07-2 Caprylic acid
14350 000630-08-0 Carbon monoxide
14380 000075-44-5 Carbonyl chloride QM = 1 mg/kg in FP
14411 008001-79-4 Castor oil
14500 009004-34-6 Cellulose
14530 007782-50-5 Chlorine
14570 000106-89-8 1-Chloro-2,3-epoxypropane See Epichlorohydrin
14650 000079-38-9 Chlorotrifluoroethylene QMA = 0,5 mg/6 dm 2
14680 000077-92-9 Citric acid
14710 000108-39-4 m -Cresol
14740 000095-48-7 o -Cresol
14770 000106-44-5 p -Cresol
[F314800 003724-65-0 Crotonic acid QMA(T) = 0,05 mg/6 dm 2 ( 33 )]
14841 000599-64-4 4-Cumylphenol SML = 0,05 mg/kg
14880 000105-08-8 1,4-Cyclohexanedimethanol See 1,4-Bis(hydroxymethyl)cyclohexane
14950 003173-53-3 Cyclohexyl isocyanate [F2QM(T) = 1 mg/kg in FP (expressed as NCO) ( 26 )]
15030 000931-88-4 Cyclooctene SML = 0,05 mg/kg. For use only in polymers contacting foods for which simulant A is laid down in Directive 85/572/EEC
15070 001647-16-1 1,9-Decadiene SML = 0,05 mg/kg
15095 000334-48-5 Decanoic acid
15100 000112-30-1 1-Decanol
15130 000872-05-9 1-Decene SML = 0,05 mg/kg
15250 000110-60-1 1,4-Diaminobutane
15272 000107-15-3 1,2-Diaminoethane See Ethylenediamine
15274 000124-09-4 1,6-Diaminohexane See Hexamethylenediamine
15310 000091-76-9 2,4-Diamino-6-phenyl-1,3,5-triazine QMA = 5 mg/6 dm 2
[ F6
F6 ]
15565 000106-46-7 1,4-Dichlorobenzene SML = 12 mg/kg
15610 000080-07-9 4,4′-Dichlorodiphenyl sulphone SML = 0,05 mg/kg
15700 005124-30-1 Dicyclohexylmethane-4,4′-diisocyanate QM(T) = 1 mg/kg (expressed as NCO ( 26 )
15760 000111-46-6 Diethyleneglycol SML(T) = 30 mg/kg ( 3 )
15790 000111-40-0 Diethylenetriamine SML = 5 mg/kg
15820 000345-92-6 4,4′-Difluorobenzophenone SML = 0,05 mg/kg
15880 000120-80-9 1,2-Dihydroxybenzene SML = 6 mg/kg
15910 000108-46-3 1,3-Dihydroxybenzene SML = 2,4 mg/kg
15940 000123-31-9 1,4-Dihydroxybenzene SML = 0,6 mg/kg
15970 000611-99-4 4,4′-Dihydroxybenzophenone SML(T) = 6 mg/kg ( 15 )
16000 000092-88-6 4,4′-Dihydroxybiphenyl SML = 6 mg/kg
16090 000080-09-1 4,4′-Dihydroxydiphenyl sulphone SML = 0,05 mg/kg
16150 000108-01-0 Dimethylaminoethanol SML = 18 mg/kg
[F316210 006864-37-5 3,3'-Dimethyl-4,4'-diaminodicyclohexylmethane SML = 0,05 mg/kg ( 32 ). To be used only in polyamides.]
16240 000091-97-4 3,3′-Dimethyl-4,4′-diisocyanatobiphenyl QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
16360 000576-26-1 2,6-Dimethylphenol SML = 0,05 mg/kg
16390 000126-30-7 2,2-Dimethyl-1,3-propanediol SML = 0,05 mg/kg
16450 000646-06-0 1,3-Dioxolane SML = 0,05 mg/kg
16480 000126-58-9 Dipentaerythritol
[F316540 000102-09-0 Diphenyl carbonate SML = 0,05 mg/kg]
16570 004128-73-8 Diphenylether-4,4′-diisocyanate QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
16600 005873-54-1 Diphenylmethane-2,4′-diisocyanate QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
16630 000101-68-8 Diphenylmethane-4,4′-diisocyanate QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
16650 000127-63-9 Diphenyl sulphone SML(T) = 3 mg/kg ( 25 )
16660 000110-98-5 Dipropyleneglycol
16690 001321-74-0 Divinylbenzene QMA = 0,01 mg/6 dm 2 or SML = ND (DL = 0,02 mg/kg, analytical tolerance included) for the sum of divinylbenzene and ethylvinylbenzene and in compliance with the specifications laid down in Annex V
16694 013811-50-2 N,N′-Divinyl-2-imidazolidinone QM = 5 mg/kg in FP
16697 000693-23-2 n-Dodecanedioic acid
16704 000112-41-4 1-Dodecene SML = 0,05 mg/kg
16750 000106-89-8 Epichlorohydrin QM = 1 mg/kg in FP
16780 000064-17-5 Ethanol
16950 000074-85-1 Ethylene
[F416955 000096-49-1 Ethylene carbonate Residual content = 5 mg/kg of hydrogel at a maximum ratio of 10 g of hydrogel to 1 kg of food. The hydrolysate contains ethyleneglycol having an SML = 30 mg/kg]
16960 000107-15-3 Ethylenediamine SML = 12 mg/kg
16990 000107-21-1 Ethyleneglycol SML(T) = 30 mg/kg ( 3 )
17005 000151-56-4 Ethyleneneimine SML = ND (DL = 0,01 mg/kg)
17020 000075-21-8 Ethylene oxide QM = 1 mg/kg in FP
17050 000104-76-7 2-Ethyl-1-hexanol SML = 30 mg/kg
[F317110 016219-75-3 5-Ethylidenebicyclo[2,2,1]hept-2-ene QMA = 0,05 mg/6 dm 2 . The ratio surface/quantity of food shall be lower than 2 dm 2 /kg]
17160 000097-53-0 Eugenol SML = ND (DL = 0,02 mg/kg, analytical tolerance included)
17170 061788-47-4 Fatty acids, coco
17200 068308-53-2 Fatty acids, soya
17230 061790-12-3 Fatty acids, tall oil
17260 000050-00-0 Formaldehyde SML(T) = 15 mg/kg ( 22 )
17290 000110-17-8 Fumaric acid
17530 000050-99-7 Glucose
18010 000110-94-1 Glutaric acid
18070 000108-55-4 Glutaric anhydride
18100 000056-81-5 Glycerol
18220 068564-88-5 N-Heptylaminoundecanoic acid SML = 0,05 mg/kg ( 1 )
18250 000115-28-6 Hexachloroendomethylenetetrahydrophthalic acid SML = ND (DL = 0,01 mg/kg)
18280 000115-27-5 Hexachloroendomethylenetetrahydrophthalic anhydride SML = ND (DL = 0,01 mg/kg)
18310 036653-82-4 1-Hexadecanol
18430 000116-15-4 Hexafluoropropylene SML = ND (DL = 0,01 mg/kg)
18460 000124-09-4 Hexamethylenediamine SML = 2,4 mg/kg
18640 000822-06-0 Hexamethylene diisocyanate QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
18670 000100-97-0 Hexamethylenetetramine SML(T) = 15 mg/kg ( 22 ) (expressed as Formaldehyde)
[F318700 000629-11-8 1,6-Hexanediol SML = 0,05 mg/kg]
18820 000592-41-6 1-Hexene SML = 3 mg/kg
18867 000123-31-9 Hydroquinone See 1,4-Dihydroxybenzene
18880 000099-96-7 p-Hydroxybenzoic acid
[F318896 001679-51-2 4-(Hydroxymethyl)-1-cyclohexene SML = 0,05 mg/kg]
18897 016712-64-4 6-Hydroxy-2-naphthalenecarboxylic acid SML = 0,05 mg/kg
18898 000103-90-2 N-(4-Hydroxyphenyl) acetamide [F2SML = 0,05 mg/kg]
19000 000115-11-7 Isobutene
19060 000109-53-5 Isobutyl vinyl ether QM = 5 mg/kg in FP
19110 004098-71-9 1-Isocyanato-3-isocyanatomethyl-3,5,5-trimethylcyclohexane QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
19150 000121-91-5 Isophthalic acid SML = 5 mg/kg
19210 001459-93-4 Isophthalic acid, dimethyl ester SML = 0,05 mg/kg
19243 000078-79-5 Isoprene See 2-Methyl-1,3-butadiene
19270 000097-65-4 Itaconic acid
19460 000050-21-5 Lactic acid
19470 000143-07-7 Lauric acid
19480 002146-71-6 Lauric acid, vinyl ester
19490 000947-04-6 Laurolactam SML = 5 mg/kg
19510 011132-73-3 Lignocellulose
19540 000110-16-7 Maleic acid SML(T) = 30 mg/kg ( 4 )
19960 000108-31-6 Maleic anhydride SML(T) = 30 mg/kg ( 4 ) (expressed as maleic acid)
19975 000108-78-1 Melamine See 2,4,6-triamino-1,3,5-triazine
19990 000079-39-0 Methacrylamide SML = ND (DL = 0,02 mg/kg, analytical tolerance included)
20020 000079-41-4 Methacrylic acid [F4SML(T) = 6 mg/kg ( 37 )]
20050 000096-05-9 Methacrylic acid, allyl ester SML = 0,05 mg/kg
20080 002495-37-6 Methacrylic acid, benzyl ester [F4SML(T) = 6 mg/kg ( 37 )]
20110 000097-88-1 Methacrylic acid, butyl ester [F4SML(T) = 6 mg/kg ( 37 )]
20140 002998-18-7 Methacrylic acid, sec-butyl ester [F4SML(T) = 6 mg/kg ( 37 )]
20170 000585-07-9 Methacrylic acid, tert-butyl ester [F4SML(T) = 6 mg/kg ( 37 )]
20260 000101-43-9 Methacrylic acid, cyclohexyl ester SML = 0,05 mg/kg
20410 002082-81-7 Methacrylic acid, diester with 1,4-butanediol SML = 0,05 mg/kg
[F320440 000097-90-5 Methacrylic acid, diester with ethyleneglycol SML = 0,05 mg/kg]
20530 002867-47-2 Methacrylic acid, 2-(dimethylamino)-ethyl ester SML = ND (DL = 0,02 mg/kg, analytical tolerance included)
20590 000106-91-2 Methacrylic acid, 2,3-epoxypropyl ester QMA = 0,02 mg/6 dm 2
20890 000097-63-2 Methacrylic acid, ethyl ester [F4SML(T) = 6 mg/kg ( 37 )]
21010 000097-86-9 Methacrylic acid, isobutyl ester [F4SML(T) = 6 mg/kg ( 37 )]
21100 004655-34-9 Methacrylic acid, isopropyl ester [F4SML(T) = 6 mg/kg ( 37 )]
21130 000080-62-6 Methacrylic acid, methyl ester [F4SML(T) = 6 mg/kg ( 37 )]
21190 000868-77-9 Methacrylic acid, monoester with ethyleneglycol [F4SML(T) = 6 mg/kg ( 37 )]
21280 002177-70-0 Methacrylic acid, phenyl ester [F4SML(T) = 6 mg/kg ( 37 )]
21340 002210-28-8 Methacrylic acid, propyl ester [F4SML(T) = 6 mg/kg ( 37 )]
[F421370 010595-80-9 Methacrylic acid, 2-sulphoethyl ester QMA = ND (DL = 0,02 mg/6 dm 2 )]
[F321400 054276-35-6 Methacrylic acid, sulphopropyl ester QMA = 0,05 mg/6 dm 2]
21460 000760-93-0 Methacrylic anhydride [F4SML(T) = 6 mg/kg ( 37 )]
21490 000126-98-7 Methacrylonitrile SML = ND (DL = 0,020 mg/kg, analytical tolerance included)
21520 001561-92-8 Methallylsulphonic acid, sodium salt SML = 5 mg/kg
21550 000067-56-1 Methanol
21640 000078-79-5 2-Methyl-1,3-butadiene QM = 1 mg/kg in FP or SML = ND (DL = 0,02 mg/kg, analytical tolerance included)
21730 000563-45-1 3-Methyl-1-butene QMA = 0,006 mg/6 dm 2 . For use only in Polypropylene
21765 106246-33-7 4,4′-Methylenebis(3-chloro-2,6-diethylaniline) QMA = 0,05 mg/6 dm 2
21821 000505-65-7 1,4-(Methylenedioxy)butane See 1,4-Butanediol formal
21940 000924-42-5 N-Methylolacrylamide SML = ND (DL = 0,01 mg/kg)
22150 000691-37-2 4-Methyl-1-pentene [F2SML = 0,05 mg/kg]
[F422210 000098-83-9 alpha-Methylstyrene SML = 0,05 mg/kg]
22331 025513-64-8 [F2Mixture of (35-45 % w/w) 1,6-diamino-2,2,4-trimethylhexane and (55-65 % w/w)1,6-diamino-2,4,4-trimethylhexane] QMA = 5 mg/6 dm 2
22332 [F2] Mixture of (40 % w/w) 2,2,4-trimethylhexane-1,6-diisocyanate and (60 % w/w) 2,4,4-trimethylhexane-1,6-diisocyanate QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
22350 000544-63-8 Myristic acid
22360 001141-38-4 2,6-Naphthalenedicarboxylic acid SML = 5 mg/kg
22390 000840-65-3 2,6-Naphthalenedicarboxylic acid, dimethyl ester SML = 0,05 mg/kg
22420 003173-72-6 1,5-Naphthalene diisocyanate QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
22437 000126-30-7 Neopentylglycol See 2,2-Dimethyl-1,3-propanediol
22450 009004-70-0 Nitrocellulose
22480 000143-08-8 1-Nonanol
22550 000498-66-8 Norbornene See Bicyclo[2.2.1]hept-2-ene
22570 000112-96-9 Octadecyl isocyanate QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
22600 000111-87-5 1-Octanol
22660 000111-66-0 1-Octene SML = 15 mg/kg
22763 000112-80-1 Oleic acid
[F322775 000144-62-7 Oxalic acid SML(T) = 6 mg/kg ( 29 )]
22778 007456-68-0 4,4′-Oxybis(benzenesulphonyl azide) QMA = 0,05 mg/6 dm 2
22780 000057-10-3 Palmitic acid
22840 000115-77-5 Pentaerythritol
22870 000071-41-0 1-Pentanol
22900 000109-67-1 1-Pentene SML = 5 mg/kg
[F422932 001187-93-5 Perfluoromethyl perfluorovinyl ether SML = 0,05 mg/kg. Only to be used for anti-stick coatings]
22937 001623-05-8 Perfluoropropylperfluorovinyl ether SML = 0,05 mg/kg
22960 000108-95-2 Phenol
23050 000108-45-2 1,3-Phenylenediamine SML = ND (DL = 0,02 mg/kg, analytical tolerance included)
[F323070 000102-39-6 (1,3-Phenylenedioxy)diacetic acid QMA = 0,05 mg/6 dm 2]
23155 000075-44-5 Phosgene See Carbonyl chloride
23170 007664-38-2 Phosphoric acid
23175 000122-52-1 Phosphorous acid, triethyl ester QM = ND (DL = 1 mg/kg in FP)
23187 Phthalic acid See Terephthalic acid
23200 000088-99-3 o-Phthalic acid
23230 000131-17-9 Phthalic acid, diallyl ester SML = ND (DL = 0,01 mg/kg)
23380 000085-44-9 Phthalic anhydride
23470 000080-56-8 alpha-Pinene
23500 000127-91-3 beta-Pinene
23547

009016-00-6

063148-62-9

Polydimethylsiloxane (Mw >  6 800 ) In compliance with the specifications laid down in Annex V
23590 025322-68-3 Polyethyleneglycol
23651 025322-69-4 Polypropyleneglycol
23740 000057-55-6 1,2-Propanediol
23770 000504-63-2 1,3-Propanediol SML = 0,05 mg/kg
23800 000071-23-8 1-Propanol
23830 000067-63-0 2-Propanol
23860 000123-38-6 Propionaldehyde
23890 000079-09-4 Propionic acid
23920 000105-38-4 Propionic acid, vinyl ester SML(T) = 6 mg/kg ( 2 ) (expressed as Acetaldehyde)
23950 000123-62-6 Propionic anhydride
23980 000115-07-1 Propylene
24010 000075-56-9 Propylene oxide QM = 1 mg/kg in FP
24051 000120-80-9 Pyrocatechol See 1,2-Dihydroxybenzene
24057 000089-32-7 Pyromellitic anhydride SML = 0,05 mg/kg (expressed as Pyromellitic acid)
24070 073138-82-6 Resin acids and Rosin acids
24072 000108-46-3 Resorcinol See 1,3-Dihydroxybenzene
24073 000101-90-6 Resorcinol diglycidyl ether QMA = 0,005 mg/6 dm 2 . Not for use in polymers contacting foods for which simulant D is laid down in Directive 85/572/EEC and for indirect food contact only, behind the PET layer.
24100 008050-09-7 Rosin
24130 008050-09-7 Rosin gum See Rosin
24160 008052-10-6 Rosin tall oil
24190 [F1008050-09-7] Rosin wood [F4See Rosin (Reference No 24100)]
24250 009006-04-6 Rubber, natural
24270 000069-72-7 Salicylic acid
24280 000111-20-6 Sebacic acid
24430 002561-88-8 Sebacic anhydride
24475 001313-82-2 Sodium sulphide
24490 000050-70-4 Sorbitol
24520 008001-22-7 Soybean oil
24540 009005-25-8 Starch, edible
24550 000057-11-4 Stearic acid
24610 000100-42-5 Styrene
24760 026914-43-2 Styrenesuphonic acid SML = 0,05 mg/kg
24820 000110-15-6 Succinic acid
24850 000108-30-5 Succinic anhydride
24880 000057-50-1 Sucrose
24887 006362-79-4 5-Sulphoisophthalic acid, monosodium salt SML = 5 mg/kg
24888 003965-55-7 5-Sulphoisophthalic acid, monosodium salt, dimethyl ester SML = 0,05 mg/kg
[F424903 068425-17-2 Syrups, hydrolysed starch, hydrogenated In compliance with the specifications laid down in Annex V]
24910 000100-21-0 Terephthalic acid SML = 7,5 mg/kg
24940 000100-20-9 Terephthalic acid dichloride SML(T) = 7,5 mg/kg (expressed as Terephthalic acid)
24970 000120-61-6 Terephthalic acid, dimethyl ester
25080 001120-36-1 1-Tetradecene SML = 0,05 mg/kg
25090 000112-60-7 Tetraethyleneglycol
25120 000116-14-3 Tetrafluoroethylene SML = 0,05 mg/kg
25150 000109-99-9 Tetrahydrofuran SML = 0,6 mg/kg
25180 000102-60-3 N,N,N′,N′,-Tetrakis(2-hydroxypropyl)ethylenediamine
25210 000584-84-9 2,4-Toluene diisocyanate QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
25240 000091-08-7 2,6-Toluene diisocyanate QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
25270 026747-90-0 2,4-Toluene diisocyanate dimer QM(T) = 1 mg/kg (expressed as NCO) ( 26 )
25360 Trialkyl(C5-C15)acetic acid, 2,3-epoxypropyl ester QM = 1 mg/kg in FP (expressed as Epoxy group, Mw = 43)
25380 Trialkyl acetic acid (C7-C17), vinyl esters (= Vinyl versatate) QMA = 0,05 mg/6 dm 2
25385 000102-70-5 Triallyamine In compliance with the specifications laid down in Annex V
25420 000108-78-1 2,4,6-Triamino-1,3,5-triazine SML = 30 mg/kg
25450 026896-48-0 Tricyclodecanedimethanol SML = 0,05 mg/kg
25510 000112-27-6 Triethyleneglycol
[F425540 000528-44-9 Trimellitic acid SML(T) = 5 mg/kg ( 35 )
25550 000552-30-7 Trimellitic anhydride SML(T) = 5 mg/kg ( 35 ) (expressed as trimellitic acid)]
25600 000077-99-6 1,1,1-Trimethylolpropane SML = 6 mg/kg
25840 003290-92-4 1,1,1-Trimethylolpropane trimethacrylate SML = 0,05 mg/kg
25900 000110-88-3 Trioxane SML = 0,05 mg/kg
25910 024800-44-0 Tripropyleneglycol
25927 027955-94-8 1,1,1-Tris(4-hydroxyphenol)ethane QM= 0,5 mg/kg in FP. For use only in polycarbonates
25960 000057-13-6 Urea
26050 000075-01-4 Vinyl chloride See Council Directive 78/142/EEC
26110 000075-35-4 Vinylidene chloride QM = 5 mg/kg in FP or SML = ND (DL = 0,05 mg/kg)
26140 000075-38-7 Vinylidene fluoride SML = 5 mg/kg
26155 001072-63-5 1-Vinylimidazole QM = 5 mg/kg in FP
26170 003195-78-6 N-Vinyl-N-methylacetamide QM = 2 mg/kg in FP
26320 002768-02-7 Vinyltrimethoxysilane QM = 5 mg/kg in FP
26360 007732-18-5 Water In compliance with Directive 98/83/EC

Section B U.K.

List of monomers and other starting substances which may continue to be used pending a decision on inclusion in Section A

Ref. No CAS No Name Restrictions and/or specifications
(1) (2) (3) (4)
[ F6
F6
F6
F6 ]
[ F5 ]
13050 000528-44-9 1,2,4-Benzenetricarboxylic acid See Trimellitic acid
[ F5 ]
[ F6 ]
15730 000077-73-6 Dicyclopentadiene
[ F6
F6 ]
18370 000592-45-0 1,4-Hexadiene
[ F6 ]
[ F5 ]
[ F6 ]
21970 000923-02-4 N-Methylolmethacrylamide
[ F5
F5
F5 ]
26230 000088-12-0 Vinylpyrrolidone ]

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