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Commission Directive 2002/72/EC of 6 August 2002 relating to plastic materials and articles intended to come into contact with foodstuffs (Text with EEA relevance) (repealed)
When the UK left the EU, legislation.gov.uk published EU legislation that had been published by the EU up to IP completion day (31 December 2020 11.00 p.m.). On legislation.gov.uk, these items of legislation are kept up-to-date with any amendments made by the UK since then.
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Version Superseded: 27/03/2008
EU Directives are published on this site to aid cross referencing from UK legislation. Since IP completion day (31 December 2020 11.00 p.m.) no amendments have been applied to this version.
Editorial Information
Plastic material and articles shall not release primary aromatic amines in a detectable quantity (DL = 0,01 mg/kg of food or food simulant). The migration of the primary aromatic amines appearing in the lists in Annex II and III is excluded from this restriction.] ]
Editorial Information
X2 Substituted by Corrigendum to Commission Directive 2007/19/EC of 30 March 2007 amending Directive 2002/72/EC relating to plastic materials and articles intended to come into contact with food and Council Directive 85/572/EEC laying down the list of simulants to be used for testing migration of constituents of plastic materials and articles intended to come into contact with foodstuffs (Official Journal of the European Union L 91 of 31 March 2007).
Textual Amendments
F1 Substituted by Commission Directive 2007/19/EC of 30 March 2007 amending Directive 2002/72/EC relating to plastic materials and articles intended to come into contact with food and Council Directive 85/572/EEC laying down the list of simulants to be used for testing migration of constituents of plastic materials and articles intended to come into contact with foodstuffs (Text with EEA relevance).
a Quantity of substance used /quantity of formulation | ||
b [F2 [X3 OJ L 339, 30.12.1996, p. 1 .] ] ] | ||
Ref. No | OTHER SPECIFICATIONS | |
---|---|---|
[F311530 | Acrylic acid, 2-hydroxypropyl ester. It may contain up to 25 % (m/m) of acrylic acid, 2-hydroxyisopropyl ester (CAS No 002918-23-2)] | |
[F416690 | Divinylbenzene It may contain up to 45 % (m/m) of Ethylvinylbenzene | |
18888 | 3-Hydroxybutanoic acid-3-hydroxypentanoic acid, copolymer | |
Definition | The copolymers are produced by the controlled fermentation of Alcaligenes eutrophus using mixtures of glucose and propanoic acid as carbon sources. The organism used has not been genetically engineered and has been derived from a single wild-type organism Alcaligenes eutrophus strain HI6 NCIMB 10442. Master stocks of the organism are stored as freeze-dried ampoules. A submaster/working stock is prepared from the master stock and stored in liquid nitrogen and used to prepare inocula for the fermenter. Fermenter samples will be examined daily both microscopically and for any changes in colonial morphology on a variety of agars at different temperatures. The copolymers are isolated from heat treatment bacteria by controlled digestion of the other cellular components, washing and drying. These copolymers are normally offered as formulated, melt formed granules containing additives such as nucleating agents, plasticisers, fillers, stabilisers and pigments which all conform to the general and individual specifications | |
Chemical name | Poly(3-D-hydroxybutanoate-co-3-D-hydroxypentanoate) | |
CAS number | 080181-31-3 | |
Structural formula | where n/(m + n) greater than 0 and less or equal to 0,25 | |
Average molecular weight | Not less than 150 000 Daltons (measured by gel permeation chromatography) | |
Assay | Not less than 98 % poly(3-D-hydroxybutanoate-co-3-D-hydoxypentanoate) analysed after hydrolysis as a mixture of 3-D-hydroxybutanoic and 3-D-hydroxypentanoic acids | |
Description | White to off-white powder after isolation | |
Characteristics | ||
Identification tests: | ||
Solubility | Soluble in chlorinated hydrocarbons such as chloroform or dichloromethane but practically insoluble in ethanol, aliphatic alkanes and water | |
Restriction | QMA for crotonic acid is 0.05 mg/6 dm 2 | |
Purity | Prior to granulation the raw material copolymer powder must contain: | |
— nitrogen | Not more than 2 500 mg/kg of plastic | |
— zinc | Not more than 100 mg/kg of plastic | |
— copper | Not more than 5 mg/kg of plastic | |
— lead | Not more than 2 mg/kg of plastic | |
— arsenic | Not more than 1 mg/kg of plastic | |
— chromium | Not more than 1 mg/kg of plastic] | |
23547 | Polydimethylsiloxane (Mw > 6 800 ) | |
Minimum viscosity 100 × 10 –6 m 2 /s (= 100 centistokes) at 25 °C | ||
[F524903 | Syrups, hydrolysed starch, hydrogenated | |
In compliance with the purity criteria for maltitol syrup E 965(ii) (Commission Directive 95/31/EC ( OJ L 178, 28.7.1995, p. 1 ) as last amended by 2004/46/EC ( OJ L 114, 21.04.2004, p. 15 ))] | ||
25385 | Triallylamine | |
40 mg/kg hydrogel at a ratio of 1 kg food to a maximum of 1,5 grams of hydrogel. For use only in hydrogels intended for non-direct food contact use. | ||
38320 | 4-(2-Benzoxazolyl)-4′-(5-methyl-2-benzoxazolyl) stilbene | |
Not more than 0,05 %w/w (quantity of substance used/quantity of the formulation) | ||
[F2 [X342080 | Carbon black Specifications:
| |
[F543480 | Charcoal, activated | |
To be used only in PET at maximum 10 mg/kg of polymer. Same purity requirements as for Vegetable Carbon (E 153) set out by Commission Directive 95/45/EC (( OJ L 226, 22.9.1995, p. 1 ). Directive as last amended by Directive 2004/47/EC ( OJ L 113, 20.4.2004, p. 24 )) with exception of ash content which can be up to 10 % (w/w)] | ||
43680 | Chlorodifluoromethane | |
Content of chlorofluoromethane less than 1 mg/kg of the substance | ||
47210 | Dibutylthiostannoic acid polymer | |
Molecular unit = (C 8 H 18 S 3 Sn 2 )n (n = 1,5-2) | ||
[F564990 | Maleic anhydride-styrene, copolymer, sodium salt | |
MW fraction < 1 000 is less than 0,05 % (w/w) | ||
67155 | Mixture of 4-(2-Benzoxazolyl)-4'-(5-methyl-2-benzoxazolyl)stilbene, 4,4'-bis(2-benzoxazolyl) stilbene and 4,4'-bis(5-methyl-2-benzoxazolyl)stilbene | |
Mixture obtained from the manufacturing process in the typical ratio of (58-62 %):(23-27 %): (13-17 %)] | ||
[F2 [X372081/10 | Petroleum hydrocarbon resins (hydrogenated) Specifications: Petroleum hydrocarbon resins, hydrogenated are produced by the catalytic or thermal polymerisation of dienes and olefins of the aliphatic, alicyclic and/or monobenzenoid arylalkene types from distillates of cracked petroleum stocks with a boiling range not greater than 220 °C, as well as the pure monomers found in these distillation streams, subsequently followed by distillation, hydrogenation and additional processing. Properties:
| |
76721 | Polydimethylsiloxane (Mw > 6 800 ) | |
Minimum viscosity 100 × 10 –6 m 2 /s (= 100 centistokes) at 25 °C | ||
[F1 [X276845 | Polyester of 1,4-butanediol with caprolactone MW fraction < 1 000 is less than 0,5 % (w/w)] ] | |
[F576815 | Polyester of adipic acid with glycerol or pentaerythritol, esters with even numbered, unbranched C12-C22 fatty acids | |
MW fraction < 1 000 is less than 5 % (w/w)] | ||
[F377895 | Polyethyleneglycol (E0 = 2-6) monoalkyl (C 16 -C 18 ) ether The composition of this mixture is as follows:
| |
[F579600 | Polyethyleneglycol tridecyl ether phosphate | |
Polyethyleneglycol (EO ≤ 11) tridecyl ether phosphate (mono-and dialkyl ester) with a maximum 10 % content of polyethyleneglycol (EO ≤ 11) tridecylether] | ||
[F2 [X381500 | Polyvinylpyrrolidone The substance shall meet the purity criteria established in Commission Directive 96/77/EC] ] b | |
83595 | Reaction product of di-tert-butylphosphonite with biphenyl, obtained by condensation of 2,4-di-tert-butylphenol with Friedel Craft reaction product of phosphorous trichloride and biphenyl | |
Composition:
| ||
Other specifications:
| ||
[F1 [X288640 | Soybean oil, epoxidized Oxirane < 8 %, iodine number < 6] ] | |
95859 | Waxes, refined, derived from petroleum based or synthetic hydrocarbon feedstocks | |
The product should have the following specifications:
| ||
95883 | White mineral oils, paraffinic derived from petroleum based hydrocarbon feedstocks | |
The product should have the following specifications:
|
Editorial Information
X3 Inserted by Corrigendum to Commission Directive 2007/19/EC of 30 March 2007 amending Directive 2002/72/EC relating to plastic materials and articles intended to come into contact with food and Council Directive 85/572/EEC laying down the list of simulants to be used for testing migration of constituents of plastic materials and articles intended to come into contact with foodstuffs (Official Journal of the European Union L 91 of 31 March 2007).
Textual Amendments
F2 Inserted by Commission Directive 2007/19/EC of 30 March 2007 amending Directive 2002/72/EC relating to plastic materials and articles intended to come into contact with food and Council Directive 85/572/EEC laying down the list of simulants to be used for testing migration of constituents of plastic materials and articles intended to come into contact with foodstuffs (Text with EEA relevance).
F3 Inserted by Commission Directive 2004/19/EC of 1 March 2004 amending Directive 2002/72/EC relating to plastic materials and articles intended to come into contact with foodstuffs (Text with EEA relevance).
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