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ANNEX I

E 331 (i) MONOSODIUM CITRATE

Synonyms

Monosodium citrate

Monobasic sodium citrate

Definition
Chemical nameMonosodium citrate
Monosodium salt of 2-hydroxy-1,2,3-propanetricarboxylic acid
Chemical formula
(a)

C6H7O7Na (anhydrous)

(b)

C6H7O7Na· H2O (monohydrate)

Molecular weight
(a)

214,11 (anhydrous)

(b)

232,23 (monohydrate)

AssayContent not less than 99 % on the anhydrous basis
DescriptionCrystalline white powder or colourless crystals
Identification
A.Positive tests for citrate and for sodium
Purity
Loss on drying

Determined by drying at 180 oC for four hours:

  • anhydrous: not more than 1,0 %

  • monohydrate: not more than 8,8 %

OxalatesNot more than 100 mg/kg expressed as oxalic acid, after drying
pH of a 1 % aqueous solutionBetween 3,5 and 3,8
ArsenicNot more than 1 mg/kg
LeadNot more than 1 mg/kg
MercuryNot more than 1 mg/kg
Heavy metals (as Pb)Not more than 5 mg/kg