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ANNEX I

E 333 (iii) TRICALCIUM CITRATE

Synonyms

Tricalcium citrate

Tribasic calcium citrate

Definition
Chemical nameTricalcium citrate
Tricalcium salt of 2-hydroxy-1,2,3-propanetricarboxylic acid
Tetrahydrated tricalcium salt of citric acid
Einecs212-391-7
Chemical formula(C6H6O7)2Ca3·4H2O
Molecular weight570,51
AssayNot less than 97,5 % on the anhydrous basis
DescriptionFine white powder
Identification
A.Positive tests for citrate and for calcium
Purity
Loss on dryingNot more than 14,0 % determined by drying at 180 oC for four hours
OxalatesNot more than 100 mg/kg expressed as oxalic acid, after drying
FluorideNot more than 30 mg/kg (expressed as fluorine)
ArsenicNot more than 1 mg/kg
LeadNot more than 1 mg/kg
MercuryNot more than 1 mg/kg
Heavy metals (as Pb)Not more than 5 mg/kg
CarbonatesDissolving 1 g of calcium citrate in 10 ml 2 N hydrochloric acid must not liberate more than a few isolated bubbles