Council Directive of 12 June 1986 on limit values and quality objectives for discharges of certain dangerous substances included in List I of the Annex to Directive 76/464/EEC (86/280/EEC) (repealed)

ANNEX II U.K. SPECIFIC PROVISIONS

1.

Relating to carbon tetrachloride

2.

Relating to DDT

3.

Relating to pentachlorophenol

4.

[F1 Relating to aldrin, dieldrin, endrin and isodrin

5.

Relating to hexachlorobenzene

6.

Relating to hexachlorobutadiene

7.

Relating to chloroform]

8.

[F2 Relating to 1,2-dichloroethane (EDC)

9.

Relating to trichloroethylene (TRI)

10.

Relating to perchloroethylene (PER)

11.

Relating to trichlorobenzene (TCB).]

Textual Amendments

F1 Inserted by Council Directive of 16 June 1988 (88/347/EEC).

F2 Inserted by Council Directive of 27 July 1990 (90/415/EEC).

The numbering of the substances listed in this Annex corresponds to the list of 129 substances contained in the communication from the Commission to the Council of 22 June 1982(1).

Should substances be included in future in this Annex which are not set out in the abovementioned list, they shall be numbered in chronological order of inclusion beginning with No 130.

I. Specific provisions relating to carbon tetrachloride (No 13)(2) U.K.

CAS No 56-23-5(3)

Heading A (13): Limit values for emission standards U.K.

a Among the industrial establishments referred to under heading A, point 3, of Annex I, reference is made in particular to plants using carbon tetrachloride as solvent.
b A simplified monitoring procedure may be introduced if annual discharges do not exceed 30 kg a year.
c In view of the volatility of carbon tetrachloride and in order to ensure compliance with Article 3 (6), where a process involving agitation in the open air of effluent containing carbon tetrachloride is used, the Member States shall require compliance with the limit values upstream of the plant concerned; they shall ensure that all water likely to be polluted is taken fully into account.
d It is not possible at present to adopt limit values for this sector. The Council is to adopt such limit values at a later date, acting on a Commission proposal.
Type of industrial planta b	Type of average value	Limit values expressed asc		To be complied with as from
		weight	concentration
1. Carbon tetrachloride production by perchlorination	Monthly	a) process involving washing: 40 g CCl4 per tonne of total production capacity of CCl4 and perchlorethylene	1,5 mg/l	1. 1. 1988
		b) process not involving washing: 2,5 g/tonne	1,5 mg/l
	Daily	a) process involving washing: 80 g/tonne	3 mg/l
		b) process not involving washing: 5 g/tonne	3 mg/l
2. Production of chloromethanes by methane chlorination (including high-pressure electrolytic chlorine generation) and from methanol	Monthly	10 g CCl4 per tonne of total production capacity of chloromethanes	1,5 mg/l	1. 1. 1988
	Daily	20 g/tonne	3 mg/l
3. Production of chlorofluorocarbonsd	Monthly	—	—	—
	Daily	—	—	—

F3 Heading B (13): Quality objectives U.K.

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Textual Amendments

F3 Deleted by Directive 2008/105/EC of the European Parliament and of the Council of 16 December 2008 on environmental quality standards in the field of water policy, amending and subsequently repealing Council Directives 82/176/EEC, 83/513/EEC, 84/156/EEC, 84/491/EEC, 86/280/EEC and amending Directive 2000/60/EC of the European Parliament and of the Council.

Heading C (13): Reference method of measurement U.K.

1.

The reference method of measurement to be used for determining the presence of tetrachloride in effluents and water is gas chromatography.

2.

A sensitive detector must be used when concentration levels are below 0,5 mg/l and in this case the determination limit(4) is 0,1 μg/l. For concentration levels higher than 0,5 mg/l a determination limit(5) of 0,1 mg/l is acceptable.

2.

The accuracy and precision of the method must be ± 50 % at a concentration which represents twice the value of the determination limit(6).

II. Specific provisions relating to DDT (No 46)(7) (8) U.K.

CAS No 50 - 29 - 3(9)

STANDSTILL: U.K.

The concentration of DDT in the aquatic environment, sediments and/or molluscs and/or shellfish and/or fish must not increase significantly with time. U.K.

Heading A (46):

Limit values for emission standards^{a b}

a With regard to new plants, the best technical means available must already make it possible to lay down, for DDT, emission standards lower than 1 g/tonne substances produced.
b On the basis of experience gained in implementing this Directive, the Commission will submit to the Council, pursuant to Article 6 (3) of this Directive, in good time, proposals aimed at fixing more stringent limit values to enter into force by 1994.
c Among the industrial plants referred to under heading A, point 3, of Annex I, reference is made in particular to plants formulating DDT away from the production site and to the dicofol production industry.
d A simplified monitoring procedure may be introduced if annual discharges do not exceed 1 kg a year.
Type of industrial plantc d	Type of average value	Limit value espressed as		To be complied with as from
		g/tonne of substances produced, handled or used	mg/l of water discharged
Production of DDT including formulation of DDT on the same site	Monthly	8	0,7	1. 1. 1988
	Daily	16	1,3	1. 1. 1988
	Monthly	4	0,2	1. 1. 1991
	Daily	8	0,4	1. 1. 1991

F3 Heading B (46): Quality objectives U.K.

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Heading C (46): Reference method of measurement U.K.

1.

The reference method of measurement to be used for determining DDT in effluents and the aquatic environment is gas chromatography with electron capture detection after extraction by means of an appropriate solvent. The limit of determination(10) [X1 for total DDT is approximately 4 ng/l for the aquatic environment] and 1 μg/l for effluents, depending on the number of extraneous substances present in the sample.

2.

The reference method to be used for determining DDT in sediments and organisms is gas chromatography with electron capture detection after appropriate preparation of samples. The limit of determination(11) is 1 μg/kg.

3.

The accuracy and precision of the method must be ± 50 % at a concentration which represents twice the value of the limit of determination(12).

Editorial Information

X1 Substituted by Corrigendum to Council Directive 86/280/EEC of 12 June 1986 on limit values and quality objectives for discharges of certain dangerous substances included in List I of the Annex to Directive 76/464/EEC (Official Journal of the European Communities No L 181 of 4 July 1986).

III. Specific provisions relating to pentachlorophenol (No 102)(13) (14) U.K.

CAS 87-86-5(15)

STANDSTILL: U.K.

The concentration of PCP in sediments and/or molluscs and/or shellfish and/or fish must not increase significantly with time. U.K.

Heading A (102): Limit values for emission standards U.K.

a Among the industrial plants referred to under heading A, point 3, of Annex I, reference is made in particular to plants producing sodium pentachlorophenate by saponification and those producing pentachlorophenol by chlorination.
b A simplified monitoring procedure may be introduced if annual discharges do not exceed 3 kg a year.
Type of industrial planta b	Type of average value	Limit values expressed as		To be complied with as from
		g/tonne production/utilization capacity	mg/l of water discharged
Production of sodium pentachlorophenate by hydrolysis of hexachlorobenzene	Monthly	25	1	1. 1. 1988
	Daily	50	2	1. 1. 1988

F3 Heading B (102): Quality objectives U.K.

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Heading C (102): Reference method of measurement U.K.

1.

The reference method of measurement to be used for determining pentachlorophenol in effluents and the aquatic environment is high-pressure liquid chromatography with electron-capture detection after extraction by means of an appropriate solvent. The limit of determination(16) is 2 μg/l for effluents and 0,1 μg/l for the aquatic environment.

2.

The reference method to be used for determining pentachlorophenol in sediments and organisms is high-pressure liquid chromatography or gas chromatography with electroncapture (SIC! electron-capture) detection after appropriate preparation of samples. The limit of determination(17) is 1 μg/kg.

3.

The accuracy and precision of the method must be ± 50 % at a concentration which represents twice the value of the limit of determination(18).

[F1 IV. Specific provisions relating to: U.K.

a Aldrin is the chemical compound C 12 H 8 Cl 6 1, 2, 3, 4, 10, 10-hexachloro-1, 4, 4a, 5, 8, 8a-hexaydro-1, 4-endo-5, 8-exo-dimethanonaphtalene.
b Dieldrin is the chemical compound C 12 H 8 Cl 6 O 1, 2, 3, 4, 10, 10-hexachloro-6, 7-epoxy-1, 4, 4a, 5, 6, 7, 8, 8a-octahydro-1, 4-endo-5, 8-exo-dimethanonaphtalene.
c Endrin is the chemical compound C 12 H 8 Cl 6 O 1, 2, 3, 4, 10, 10-hexachloro-6, 7- epoxy-1, 4, 4a, 5, 6, 7, 8, 8a-octahydro-1, 4-endo-5, 8-endo-dimethanonapthalene.
d Isodrin is the chemical compound C 12 H 8 Cl 6 1, 2, 3, 4, 10, 10-hexachloro-1, 4, 4a, 5, 8, 8a-hexhaydro-1, 4-endo-5, 8-endo-dimethanonaphtalene.
— aldrin (No 1) a	CAS-No 309-00-2
— dieldrin (No 71) b	CAS-No 60-57-1
— endrin (No 77) c	CAS-No 72-20-8
— isodrin (No 130) d	CAS-No 465-73-6

Heading A (1, 71, 77, 130): Limit values for emission standards (19) U.K.

a Among the industrial plants referred to under heading A, point 3, of Annex I, reference is made in particular to plants formulating aldrin, and/or dieldrin and/or endrin away from the production site.
b These figures take account of the total amount of water passing through the plant.
c If possible, daily values should not exceed twice the monthly value.
Type of industrial plant a	Type of average value				To be complied with as from
		Limit value expressed as	Weight	Concentration in effluent μg/l of water discharged b
Production of aldrin and/or dieldrin and/or endrin including formulation of these substances on the same site	Monthly	3 g per tonne of total production capacity (g/tonne)	2	1. 1. 1989
	Daily	15 g per tonne of total production capacity (g/tonne) c	10 c	1. 1. 1989

F3 Heading B (1, 71, 77, 130): Quality objectives U.K.

[ F3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .]

F3 Standstill: U.K.

F3 . . . . . U.K.

Heading C (1, 71, 77, 130): Reference method of measurement U.K.

1.

The reference method of measurement to be used for determining aldrin, dieldrin, endrin and/or isodrin in effluents and the aquatic environment is gas chromatography with electron-capture detection after extraction by means of an appropriate solvent. The limit of determination (20) for each substance is 2,5 ng/l for the aquatic environment and 400 ng/l for effluents, depending on the number of parasite substances present in the sample.

2.

The reference method to be used for determining aldrin, dieldrin and/or endrin and/or isodrin in sediments and organisms is gas chromatography with electron-capture detection after appropriate preparation of samples. The limit of determination is 1 μg/kg dry weight for each separate substance.

3.

The accuracy and precision of the method must be ± 50 % at a concentration which represents twice the value of the limit of determination.

V. Specific dispositions relating to hexachlorobenzene (HCB) (No 83) U.K.

CAS-118-74-1

Heading A (83): Limit values for emission standards U.K.

Standstill: U.K.

There must be no significant direct or indirect increase over time in pollution arising from discharges of HCB and affecting concentrations in sediments and/or molluscs and/or shellfish and/or fish. U.K.

a A simplified monitoring procedure may be introduced if annual discharges do not exceed 1 kg a year.
b Among the industrial plants referred to in Annex I, heading A, point 3, reference is made in particular to industrial plants producing quintozene and tecnazene, industrial plants producing chlorine by chlor-alkali electrolysis with graphite electrodes, industrial rubber processing plants, plants manufacturing pyrotechnic products and plants producing vinylchloride.
c On the basis of experience gained in implementing the Directive, and taking into account the fact that the use of best technical means already makes it possible to apply in some cases much more stringent values than those indicated above, the Council shall decide, on the basis of proposals from the Commission, upon more stringent limit values, such decision to be taken by 1 January 1995.
d It is not possible at present to adopt limit values for this sector. The Council shall adopt such limit values at a later stage, acting on a proposal from the Commission. In the meantime, Member States will apply national emission standards in accordance with Annex I, heading A, point 3.
Type of industrial plant a b c	Type of average value	Limit values expressed as		To be complied with as from
		weight	concentration
1. HCB production and processing	monthly	10 g HCB/tonne of HCB production capacity	1 mg/l of HCB	1. 1. 19990
	daily	20 g HCB/tonne of HCB production capacity	2 mg/l of HCB
2. Production of perchloro ethylene (PER) and carbon tetrachloride (CCl 4 ) by perchlorination	monthly	1,5 g HCB/tonne of PER + CCl 4 total production capacity	1,5 mg/l of HCB	1. 1. 1990
	daily	3g HCB/tonne of PER + CCl 4 total production capacity	3 mg/l of HCB
3. Production of trichloroethylene and/or perchloroethylene by any other process d	monthly	—	—	—
	daily	—	—	—

F3 Heading B (83): Quality objectives U.K.

F3 Standstill: U.K.

F3 . . . . . U.K.

[ F3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .]

Heading C (83): Reference method of measurement U.K.

1.

The reference method of measurement to be used for determining the presence of HCB in effluents and waters is gas chromatography with electron-capture detection after extraction by means of an appropriate solvent.

The limit of determination (21) for HCB shall be within the range 1 to 10 ng/l for waters and 0,5 to 1 μg/l for effluents depending on the number of extraneous substances present in the sample.

2.

The reference method to be used for determining HCB in sediments and organisms is gas chromatography with electron-capture detection after appropriate preparation of the sample. The limit of determination (22) shall be within the range 1 to 10 μg/kg of dry matter.

3.

The accuracy and precision of the method must be ± 50 % at a concentration which represents twice the value of the limit of determination (23) .

VI. Specific provisions relating to hexachlorobutadiene (HCBD) (No 84) U.K.

CAS-87-68-3

Heading A (84): Limit values for emission standards U.K.

Standstill: U.K.

There must be no significant direct or indirect increase over time in pollution arising from discharges of HCB and affecting concentrations in sediments and/or molluscs and/or shellfish and/or fish. U.K.

a A simplified monitoring procedure may be introduced if annual discharges do not exceed 1 kg a year.
b Among the industrial plants referred to in Annex I, heading A, point 3, reference is made in particular to industrial plants using HCBD for technical puposes.
c On the basis of experience gained in implementing this Directive, and taking into account the fact that the use of best technical means already makes it possible to apply in some cases much more stringent values than those indicated above, the Council shall decide on the basis of proposals from the Commission, upon more stringent limit values, such decison to be taken by 1 January 1995.
d It is not possible at present to adopt limit values for this sector. The Council shall adopt such values at a later stage, acting on a proposal from the Commission. In the meantime, Member States will apply national emission standards in accordance with Annex I, heading A, point 3.
Type of industrial plant a b c	Type of average value	Limit values expressed as		To be complied with as from
		weight	concentration
1. Production of perchloroethylene (PER) and carbon tetrachloride (CCl 4 ) by perchlorination	monthly	1,5 g HCBD/tonne of total production capacity of PER + CCl 4	1,5 mg/l of HCBD
	daily	3 g HCBD/tonne of total production capacity of PER + CCl 4	3 mg/l of HCBD	1. 1. 1990
2. Production of trichloroethylene and/or perchloroethylene by any other process d	monthly	—	—	—
	daily	—	—	—

F3 Heading B (84): Quality objectives U.K.

F3 Standstill: U.K.

F3 . . . . . U.K.

[ F3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .]

Heading C (84): Reference method of measurement U.K.

1.

The reference method of measurement to be used for determining HCBD in effluents and waters is gas chromatography with electron-capture detection after extraction by means of an appropriate solvent.

The limit of determination (24) for HCBD shall be within the range 1 to 10 ng/l for waters and 0,5 to 1 μg/l for effluents, depending on the number of extraneous substances present in the sample.

2.

The reference method to be used for determining HCDB in sediments and organisms is gas chromatogaphy with electron-capture detection after appropriate preparation of the sample. The limit of determination (25) shall be within the range 1 to 10 μg/kg of dry matter.

3.

The accuracy and precison of the method must be ± 50 % at a concentration which represents twice the value of the limit of determination (26) .

VII. Specific provisions relating to chloroform (CHCl ₃ ) (No 23) (27) U.K.

CAS-67-66-3

Heading A (23): Limit values for emission standards U.K.

a Among the industrial plants referred to under heading A, point 3 of Annex I, special reference is made, in the case of chloroform, to plants manufacturing monomer vinyl chloride using dichlorethane pyrolysis, those producing bleached pulp and other plants using CHCl 3 as a solvent and plants in which cooling waters or other effluents are chlorinated. The Council shall adopt limit values for these sectors at a later stage, acting on proposals from the Commission.
b A simplified monitoring procedure may be introduced if annual discharges do not exceed 30 kg a year.
c Daily average limit values are equal to twice the monthly average values.
d In view of the volatility of chloroform and in order to ensure compliance with Article 3 (6), where a process involving agitation in the open air of effluent containing chloroform is used, the Member States shall require compliance with the limit values upstream of the plant concerned; they shall ensure that all water likely to be polluted is taken fully into account.
e I.e. by hydrochlorination of methanol, then chlorination of methyl chloride.
f It is not possible at present to adopt limit values for this sector. The Council shall adopt such limit values at a later date, acting on a proposal from the Commission. In the meantime, Member States will apply national emission standards in accordance with Annex I, heading A, point 3.
Type of industrial plant a b	c d Limit value (monthly averages) expressed as		To be complied with as from
	weight	concentration
1. Production of chloromethanes from methanol or from a combination of methanol and methane e	10 g CHCl 3 /tonne of total production capacity of chloromethanes	1 mg/l	1. 1. 1990
2. Production of chloromethanes by chlorination of methane	7,5 g CHCl 3 /tonne of total production capacity of chloromethanes	1 mg/l	1. 1. 1990
3. Production of chlorofluorocarbon CFC f	—	—	—

F3 Heading B (23): Quality objectives U.K.

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Heading C (23): Reference method of measurement U.K.

1.

The reference method of measurement to be used for determining the presence of chloroform in effluents and the aquatic environment is gas chromatography.

Α sensitive detector must be used when concentration levels are below 0,5 mg/l and in this case the determination limit (28) is 0,1 μg/l. For concentration levels higher than 0,5 mg/l a determination limit of 0,1 mg/l is acceptable.

2.

The accuracy and precision of the method must be ± 50 % at a concentration which represents twice the value of the determination limit.]

[F2 VIII. Specific provisions relating to 1,2-dichloroethane (EDC) (No 59) (29) U.K.

CAS — 107-06-2

Heading A (59): Limit values for emission standards (30) U.K.

a The purified EDC production capacity includes that fraction of the EDC which is not cracked in the vinyl chloride (VC) production unit associated with the EDC production unit and which is recycled to the EDC purification section of the plant. Production or processing capacity is the capacity authorized by administration or, failing that, the highest annual quantity produced or processed over the four years prior to the granting or review of the authorization. The capacity authorized by the administration should not differ greatly from actual production.
b A simplified monitoring procedure may be introduced where annual discharges do not exceed 30 kg/year.
c These limit values relate: for sectors (a) and (b), to purified EDC production capacity in tonnes, for sector (c), to EDC processing capacity expressed in tonnes. However, in the case of sector (b), if the processing and utilization capacity is greater than the production capacity, the limit values shall be applied in relation to the global processing and utilization capacity. If there are several plants on the same site, the limit values shall apply to the plants taken together.
d Without prejudice to the provisions of heading A (4) in Annex I, these concentration limits relate to the following reference volumes: (a) 2 m 3 /tonne of purified EDC production capacity; (b) 2,5 m 3/ tonne of purified EDC production capacity; (c) 2,5 m 3 /tonne of EDC processing capacity.
e The limit values take account of all diffuse internal sources and/or of EDC used as a solvent within the industrial production site; this will ensure a reduction in EDC discharges of more than 99 %. Nevertheless, the combination of the best available technology and the absence of any diffuse internal source enables reduction amounts greater than 99,9 % to be achieved. On the basis of the experience acquired in the application of the present measures, the Commission will present to the Council in good time proposals for more severe limit values to be applied from 1998.
f Where a Member State takes the view that, owing to the integration of EDC production with the manufacture of other chlorinated hydrocarbons, an EDC production process is unlikely to comply with these limit values by the 1 January 1993 deadline, it must advise the Commission thereof before 1 January 1991. A programme for the reduction of EDC discharges which will enable these limit values to be complied with by 1 January 1997 will be submitted to the Commission no later than 31 December 1993. The following limit value must, meanwhile, be complied with as at 1 January 1993: 40 g EDC/tonne of purified EDC produciton capacity (monthly and daily averages). The limit value expressed as concentration is deduced on the basis of the volume of water discharged by the plant(s) concerned.
g The production of the folllowing substances specifically is involved here: ethylene diamine, ethylene polyamine, 1.1.1.-trichloroethane, trichloroethylene and perchloroethylene.
h These limit values apply only to plants the annual discharges from which exceed 30 kg/year.
i It is not possible at present to adopt limit values for this sector. The Council shall adopt such limit values at a later stage, acting on a proposal from the Commission. In the meantime, Member States will apply national limit values in accordance with Annex I, heading A, point 3.
Type of industrial plant a b	Type of average value	Limit values expressed as		To be complied with as from
		weight (g/tonne) c	concentration (mg/litre) d
a) Production only of 1,2-dichloroethane (without processing or use on the same site)	Monthly	4	2	1. 1. 1993
		2,5	1,25	1. 1. 1995
	Daily	8	4	1. 1. 1993
		5	2,5	1. 1. 1995
b) Production of 1,2-dichloroethane, and processing or use at the same site, except for the use defined in (e) below e f	Monthly	12	6	1. 1. 1993
		5	2,5	1. 1. 1995
	Daily	24	12	1. 1. 1993
		10	5	1. 1. 1995
c) Processing of 1,2-dichloroethane into substances other than vinyl chloride g	Monthly	2,5	1	1. 1. 1993
	Daily	5	2	1. 1. 1993
d) Use of EDC for degreasing metals (away from an industrial site covered by (b)) h	Monthly	—	0,1	1. 1. 1993
	Daily	—	0,2	1. 1. 1993
e) use of EDC in the production of ion exchangers i	Monthly	—	—	—
	Daily	—	—	—

F3 Heading B (59): quality objectives U.K.

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Heading C (59): reference method measurement U.K.

1.

The reference method of measurement to be used for determining the presence of 1,2-dichloroethane in effluents and the water environment is gas chromatography with electron capture (SIC! electron-capture) detection after extraction by means of an appropriate solvent or gas chromatography following isolation by means of the ‘ purge and trap ’ process and trapping by using a cryogenically cooled capillary trap. The limit of determination is 10 μg/litre for effluents and 1 μg/litre for the water environment.

2.

The accuracy and precision of the method must be plus or minus 50 % at a concentration which represents twice the value of the limit of determination.

3.

Member States may determine concentrations of EDC by reference to the quantity of AOX, EOX or VOX, provided that the Commission is first satisfied that these methods give equivalent results and until the general solvent Directive is adopted.

The Member States concerned will establish regularly the relationship in concentration between EDC and the parameter used.

IX. Specific provisions relating to trichloroethylene (TRI) (No 121) (31) U.K.

CAS 79.01.6

Heading A (121): limit values for emission standards (32) U.K.

a A simplified monitoring procedure may be introduced where annual discharges do not exceed 30 kg/year.
b For sector (a), limit values for TRI discharges to overall TRI + PER production capacity. For existing plant using dehydrochlorination of tetrachloroethane, the capacity of production is equivalent to the capacity of TRI-PER production, the ratio of TRI-PER production taken at one third. Production or processing capacity is the capacity authorized by the administration or, failing that, the highest annual quantity produced or processed over the four years prior to the granting or review of the authorization. The capacity authorized by the administration should not differ greatly from actual production.
c Without prejudice to the provisions of heading A (4) in Annex I, TRI limit concentrations relate to the following reference values: sector (a), 5 m 3 /tonne of TRI + PER production.
d These limit values apply only to industrial plants the annual discharges from which exceed 30 kg/year.
Type of industrial plants a	Type of average value	Limit values expressed as		To be complied with as from
		weight (g/tonne) b	concentration (mg/litre) c
a) Trichloroethylene (TRI) and perchloroethylene (PER) production	Monthly	10	2	1. 1. 1993
		2,5	0,5	1. 1. 1995
	Daily	20	4	1. 1. 1993
		5	1	1. 1. 1995
b) Use of TRI for degreasing metals d	Monthly		0,1	1. 1. 1993
	Daily		0,2	1. 1. 1993

F3 Heading B (121): quality objectives U.K.

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Heading C (121): reference method of measurement U.K.

1.

The reference method of measurement to be used for determining the presence of trichloroethylene (TRI) in effluents and the water environment is gas chromatography with electron-capture detection after extraction by means of an appropriate solvent.

The limit of determination for TRI is 10 μg/litre for the effluents and 0,1 μg/litre for the water environment.

2.

The accuracy and precision of the method must be plus or minus 50 % at a concentration which represents twice the value of the limit of determination.

3.

Member States may determine concentrations of TRI by reference to the quantity of AOX, EOX or VOX provided that the Commission is first satisfied that these methods give equivalent results and until the general solvent Directive is adopted.

X. Specific provisions relating to perchloroethylene (PER) (No 111) (33) U.K.

CAS-127-18-4

Heading A (111): limit values for emission standards (34) U.K.

a A simplified monitoring procedure may be introduced where annual discharges do not exceed 30 kg/year.
b For sectors (a) and (b) the limit values for PER discharges relate either to overall TRI + PER production capacity or to overall TETRA + PER capacity. Production or processing capacity is the capacity authorized by the administration or, failing that, the highest annual quantity produced or processed over the four years prior to the granting or review of the authorization. The capacity authorized by the administration should not differ greatly from actual production.
c Without prejudice to the provisions of heading A (4) in Annex I, PER limit concentrations relate to the following reference volumes: (a), 5 m 3 /tonne of TRI + PER production, (b), 2 m 3 /tonne of TETRA + PER production.
d These limit values apply only to industrial plants the annual discharges from which exceed 30 kg/year.
e It is not possible at present to adopt limit values for this sector. The Council shall adopt them at a later stage, acting on a proposal from the Commission. In the meantime, Member States will apply national emission standards in accordance with Annex I, heading A, point 3.
Type of industrial plant a	Type of average value	Limit values expressed as		To be complied with as from
		weight (g/tonne) b	concentration (mg/litre) c
a) Trichloroethylene (TRI) and perchloroethylene (PER) production (TRI-PER processes)	Monthly	10	2	1. 1. 1993
		2,5	0,5	1. 1. 1995
	Daily	20	4	1. 1. 1993
		5	1	1. 1. 1995
b) Carbon tetrachloride and perchloroethylene production (TETRA-PER processes)	Monthly	10	5	1. 1. 1993
		2,5	1,25	1. 1. 1995
	Daily	20	10	1. 1. 1993
		5	2,5	1. 1. 1995
c) Use of PER for degreasing metals d	Monthly	—	0,1	1. 1. 1993
	Daily	—	0,2	1. 1. 1993
d) Chlorofluorocarbon production e	Monthly	—	—	—
	Daily	—	—	—

F3 Heading B (111): quality objectives U.K.

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Heading C (111): reference method of measurement U.K.

1.

The reference method of measurement to be used for determining the presence of perchloroethylene (PER) in effluents and the water environment is gas chromatography with electron capture detection after extraction by means of an appropriate solvent.

The limit of determination for PER is 10 μg/litre for effluents and 0,1 μg/litre for the water environment.

2.

The accuracy and precison of the method must be plus or minus 50 % at a concentration which represents twice the value of the limit of determination.

3.

Member States may determine concentration of PER by reference to the quantity of AOX, EOX or VOX, provided that the Commission is first satisfied that these methods give equivalent results and until the general solvent Directive is adopted.

The Member States concerned will establish regularly the relationship in concentration between PER and the parameter used.

Xl. Specific provisions relating to trichlorobenzene (35) (TCB) (117, 118) (36) U.K.

Heading A (117, 118): limit values for emission standards U.K.

Standstill: U.K.

There must be no significant direct or indirect increase over time in pollution arising from discharges of TCB and affecting concentrations in sediments and/or molluscs and/or shellfish and/or fish. U.K.

a The limit values for discharges of TCB (sum of the three isomers) are given: for sector (a): in relation to the total TCB production capacity, for sector (b): in relation to the total production or processing capacity for mono- and dichlorobenzenes. Production or processing capacity is the capacity authorized by the administration or, failing that, the highest annual quantity produced or processed over the four years prior to the granting or review of the authorization. The capacity authorized by the administration should not differ greatly from actual production.
b Without prejudice to the provisions of heading A (4) in Annex I, limit concentrations relate to the following reference volumes: sector (a): 10 m 3 /tonne of TCB produced or processed, sector (b): 10 m 3 /tonne of mono- and dichlorobenzene produced or processed.
c For the existing plants discharging less than 50 kg/year by 1 January 1995, the limit values which are to be complied with at this date are equal to half of the limit values which are to be complied with as from 1 January 1993.
Type of industrial plant	Type of average value	Limit values expressed as		To be complied with as from
		weight (g/tonne) a	concentration (mg/litre) b
a) Production of TCB via dehydrochlorination of HCH and/or processing TCB	Monthly	25	2,5	1. 1. 1993
		10	1	1. 1. 1995
	Daily	50	5	1. 1. 1993
		20	2	1. 1. 1995
b) Production and/or processing of chlorobenzene via chlorination of benzene c	Monthly	5	0,5	1. 1. 1993
		0,5	0,05	1. 1. 1995
	Daily	10	1	1. 1. 1993
		1	0,1	1. 1. 1995

F3 Heading B (117, 118): quality objectives U.K.

F3 Standstill: U.K.

F3 . . . . . U.K.

[ F3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

F3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

F3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .]

Heading C (117, 118): reference method of measurement U.K.

1.

The reference method of measurement to be used for determining the presence of trichlorobenzene (TCB) in effluents and the water environment is gas chromatography with electron capture (SIC! electron-capture) detection after extraction by means of an appropriate solvent. The limit of determination for each isomer separately is 1 μg/litre for effluents and 10 ng/litre for the water environment.

2.

The reference method to be used for determining TCB in sediments and organisms is gas chromatography with electron capture detection after appropriate preparation of the sample. The limit of determination for each isomer separately is 1 μg/kg of dry matter.

3.

Member States may determine concentrations of TCB by reference to the quantity of AOX or EOX, provided that the Commission is first satisfied that these methods give equivalent results and until the general solvent Directive is adopted.

The Member States concerned will establish regularly the relationship in concentration between TCB and the parameter used.

4.

The accuracy and precision of the method must be plus or minus 50 % at a concentration which represents twice the value of the limit of determination.]

(1)

OJ No C 176, 14.7.1982, p. 3.

(2)

Article 5 applies in particular to use of carbon tetrachloride in industrial laundries.

(3)

CAS (Chemical Abstract Service) number.

(4)

The ‘determination limit’^xg of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(5)

The ‘determination limit’^xg of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(6)

The ‘determination limit’^xg of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(7)

[The sum of the isomers 1,1,1-trichloro-2,2 bis ( p -chlorophenyl) ethane;

1,1,1-trichloro-2 ( o -chlorophenyl)-2-( p -chlorophenyl) ethane;

1,1-dichloro-2,2 bis ( p -chlorophenyl) ethylene; and

1,1-dichloro-2,2 bis ( p -chlorophenyl) ethane.]

(8)

Article 5 applies to DDT if sources other than those mentioned in this Annex are identified.

(9)

CAS (Chemical Abstract Service) number.

(10)

The ‘limit of determination’^xg of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(11)

The ‘limit of determination’^xg of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(12)

The ‘limit of determination’^xg of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(13)

The chemical compound 2,3,4,5,6-Pentachloro-l-hydroxybenzene and its salts.

(14)

Article 5 applies to pentachlorophenol, and particularly to its use for treating wood.

(15)

CAS (Chemical Abstract Service) number.

(16)

The ‘limit of determination’^xg of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(17)

The ‘limit of determination’^xg of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(18)

The ‘limit of determination’^xg of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(19)

[F1 The limit values indicated in this heading shall apply to the total discharge of aldrin, dieldrin and endrin.

If the effluent resulting from the production or use of aldrin, dieldrin and/or endrin (including formulation of these substances) also contains isodrin, the limit values laid down above shall apply to the total discharges of aldrin, dieldrin, endrin and isodrin.

(20)

The ‘limit of determination’ ^x g of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(21)

The ‘limit of determination’ ^x g of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(22)

The ‘limit of determination’ ^x g of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(23)

The ‘limit of determination’ ^x g of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(24)

The ‘limit of determination’ ^x g of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(25)

The ‘limit of determination’ ^x g of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(26)

The ‘limit of determination’ ^x g of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.

(27)

In the case of chloroform, Article 3 of Directive 76/464/EEC shall apply to discharges from industrial processes which may in themselves contribute significantly to the level of chloroform in the aqueous effluent; in particular it shall apply to those mentioned under Heading A of this Annex. Article 5 of this Directive applies if sources other than those listed in this Annex are identified.

(28)

The ‘determination limit’ ^x g of a given substance is the smallest quantity, quantitatively determinable in a sample on the basis of a given working method, which can still be distinguished from zero.]

(29)

[F2 Article 5 of Directive 86/280/EEC applies in particular to EDC used as a solvent away from production or processsing site if annual discharges amount to less than 30 kg/year. Such small discharges may be exempted from requirements of Article 3 of Directive 76/464/EEC. Notwithstanding Article 5 (3) of Directive 86/280/EEC, Member States must implement their specific programmes no later than 1 January 1993. They must communicate them to the Commission at the same time.

(30)

In view of the volatility of EDC and in order to ensure compliance with Article 3 (6) of Directive 86/280/EEC, where the process used involves open-air agitation containing EDC, Member States must require compliance with the limit values upstream of the plants concerned; they must ensure that all waters likely to be polluted are properly taken into account.

(31)

Article 5 of Directive 86/280/EEC applies in particular to TRI used as solvent for dry-cleaning for the extraction of grease or odours and for degreasing metals where annual discharges amount to less than 30 kg/year. Such small discharges may be exempted from the requirements of Article 3 of Directive 76/464/EEC. Notwithstanding Article 5 (3) of Directive 86/280/EEC, Member States must implement their specific programmes no later than 1 January 1993. They must communicate them to the Commission at the same time.

(32)

In view of the volatility of trichloroethylene and in order to ensure compliance with Article 3 (6) of Directive 86/280/EEC, where the process used involves open-air agitation of the effluents containing trichloroethylene, Member States must require compliance with the limit values upstream of the plants concerned; they must ensure that all waters likely to be polluted are properly taken into account.

(33)

Article 5 of Directive 86/280/EEC applies in particular to PER used as solvent for dry-cleaning for the extraction of grease or odours and for degreasing metals where annual discharges amount to less than 30 kg/year. Such small discharges may be exempted from the requirements of Article 3 of Directive 76/464/EEC. Notwithstanding Article 5 (3) of Directive 86/280/EEC, Member States must implement their specific programmes no later than 1 January 1993. They must communicate them to the Commission at the same time.

(34)

In view of the volatility of perchloroethylene and in order to ensure compliance with Article 3 (6) of Directive 86/280/EEC, where the process used involves open-air agitation of the effluents containing perchloroethylene, the Member States must require compliance with the limit values upstream of the plants concerned; they must ensure that all waters likely to be polluted are properly taken into account.

(35)

Article 5 of Directive 86/280/EEC applies in particular to TCB used as a solvent or colouring support in the textile industry, or as component of the oils used in transformers until such time as there is specific Community legislation on this subject. Notwithstanding Article 5 (3), Member States must implement their specific programmes no later than 1 January 1993. They must communicate them to the Commission at the same time.

(36)

TCB may occur as one of the following three isomers:

• 1, 2, 3-TCB — CAS 87/61-6;

• 1, 2, 4-TCB — CAS 120-82-1 (No 118 of the EEC list);

• 1, 3, 5-TCB — CAS 180-70-3.

Technical TCB (No 117 of EEC list) is a mixture of these three isomers, with a preponderance of 1,2,4-TCB, and may also contain small quantities of di-and-tetrachlorobenzene.

In any case, these provisions apply to the total TCB (the sum of the three isomers).]

Textual Amendments

F1 Inserted by Council Directive of 16 June 1988 (88/347/EEC).

F2 Inserted by Council Directive of 27 July 1990 (90/415/EEC).