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Commission Directive 2008/84/EC (repealed)Show full title

Commission Directive 2008/84/EC of 27 August 2008 laying down specific purity criteria on food additives other than colours and sweeteners (Text with EEA relevance) (Codified version) (repealed)

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E 462 ETHYL CELLULOSE

SynonymsCellulose ethyl ether
DefinitionEthyl cellulose is cellulose obtained directly from fibrous plant material and partially etherified with ethyl groups
Chemical nameEthyl ether of cellulose
Chemical formulaThe polymers contain substituted anhydroglucose units with the following general formula:

C6H7O2(OR1)(OR2) where R1 and R2 may be any of the following:

  • H

  • CH2CH3

AssayContent not less than 44 % and not more than 50 % of ethoxyl groups (-OC2H5) on the dried basis (equivalent to not more than 2,6 ethoxyl groups per anhydroglucose unit)
DescriptionSlightly hygroscopic white to off-white, odourless and tasteless powder
Identification
A.Solubility
Practically insoluble in water, in glycerol and in propane-1,2-diol but soluble in varying proportions in certain organic solvents depending upon the ethoxyl content. Ethyl cellulose containing less than 46 to 48 % of ethoxyl groups is freely soluble in tetrahydrofuran, in methyl acetate, in chloroform and in aromatic hydrocarbon ethanol mixtures. Ethyl cellulose containing 46 to 48 % or more of ethoxyl groups is freely soluble in ethanol, in methanol, in toluene, in chloroform and in ethyl acetate
B.Film forming test
Dissolve 5 g of the sample in 95 g of an 80:20 (w/w) mixture of toluene ethanol. A clear, stable, slightly yellow solution is formed. Pour a few ml of the solution onto a glass plate and allow the solvent to evaporate. A thick, tough, continuous, clear film remains. The film is flammable
Purity
Loss on dryingNot more than 3 % (105 oC, 2 hours)
Sulphated ashNot more than 0,4 %
pH of a 1 % colloidal solutionNeutral to litmus
ArsenicNot more than 3 mg/kg
LeadNot more than 2 mg/kg
MercuryNot more than 1 mg/kg
CadmiumNot more than 1 mg/kg

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