ANNEX I

E 521 ALUMINIUM SODIUM SULPHATE

SynonymsSoda alum, sodium alum
Definition
Chemical nameAluminium sodium sulphate
Einecs233-277-3
Chemical formulaAlNa(SO4)2 · nH2O (n = 0 or 12)
Molecular weight242,09 (anhydrous)
AssayContent on the anhydrous basis not less than 96,5 % (anhydrous) and 99,5 % (dodecahydrate)
DescriptionTransparent crystals or white crystalline powder
Identification
A.Positive tests for aluminium, for sodium and for sulphate
B.Solubility
Dodecahydrate is freely soluble in water. The anhydrous form is slowly soluble in water. Both forms are insoluble in ethanol
Purity
Loss on dryingAnhydrous form: not more than 10,0 % (220 oC, 16h)
Dodecahydrate: not more than 47,2 % (50 oC-55 oC, 1h then 200 oC, 16h)
Ammonium saltsNo odour of ammonia detectable after heating
SeleniumNot more than 30 mg/kg
FluorideNot more than 30 mg/kg
ArsenicNot more than 3 mg/kg
LeadNot more than 5 mg/kg
MercuryNot more than 1 mg/kg