ANNEX I

E 242 DIMETHYL DICARBONATE

Synonyms

DMDC

Dimethyl pyrocarbonate

Definition

Chemical name

Dimethyl dicarbonate

Pyrocarbonic acid dimethyl ester

Einecs

224-859-8

Chemical formula

C4H6O5

Molecular weight

134,09

Assay

Content not less than 99,8 %

Description

Colourless liquid, decomposes in aqueous solution. It is corrosive to skin and eyes and toxic by inhalation and ingestion

Identification

A.

Decomposition

After dilution positive tests for CO2 and methanol

B.

Melting point

17 oC

Boiling point

172 oC with decomposition

C.

Density 20 oC

Approximately 1,25 g/cm3

D.

Infrared spectrum

Maxima at 1 156 and 1 832 cm- 1

Purity

Dimethyl carbonate

Not more than 0,2 %

Chlorine, total

Not more than 3 mg/kg

Arsenic

Not more than 3 mg/kg

Lead

Not more than 5 mg/kg

Mercury

Not more than 1 mg/kg

Heavy metals (as Pb)

Not more than 10 mg/kg