ANNEX II

Annex III to Directive 98/83/EC is amended as follows:

  1. (1)

    the introductory paragraph is replaced by the following:

    Member States shall ensure that the methods of analysis used for the purposes of monitoring and demonstrating compliance with this Directive are validated and documented in accordance with EN ISO/IEC 17025 or other equivalent standards accepted at international level. Member States shall ensure that laboratories or parties contracted by laboratories apply quality management system practices in accordance with EN ISO/IEC 17025 or other equivalent standards accepted at international level.

    In the absence of an analytical method meeting the minimum performance criteria set out in Part B, Member States shall ensure that monitoring is carried out using best available techniques not entailing excessive costs.

  2. (2)

    point 1 is amended as follows:

    1. (a)

      the heading of point 1 is replaced by the following:

      PART AMicrobiological parameters for which methods of analysis are specified
    2. (b)

      the third to the ninth paragraphs, including Note 1, are replaced by the following:

      The methods for microbiological parameters are:

      1. (a)

        Escherichia coli (E. coli) and coliform bacteria (EN ISO 9308-1 or EN ISO 9308-2)

      2. (b)

        Enterococci (EN ISO 7899-2)

      3. (c)

        Pseudomonas aeruginosa (EN ISO 16266)

      4. (d)

        enumeration of culturable microorganisms — colony count 22 °C (EN ISO 6222)

      5. (e)

        enumeration of culturable microorganisms — colony count 36 °C (EN ISO 6222)

      6. (f)

        Clostridium perfringens including spores (EN ISO 14189)

  3. (3)

    point 2 is amended as follows:

    1. (a)

      the heading of point 2 is replaced by the following:

      PART BChemical and indicator parameters for which performance characteristics are specified
    2. (b)

      point 2.1 is replaced by the following:

      1.Chemical and indicator parameters

      For the parameters set out in Table 1, the specified performance characteristics are that the method of analysis used must, as a minimum, be capable of measuring concentrations equal to the parametric value with a limit of quantification, as defined in Article 2(2) of Commission Directive 2009/90/EC17, of 30 % or less of the relevant parametric value and an uncertainty of measurement as specified in Table 1. The result shall be expressed using at least the same number of significant figures as for the parametric value considered in Parts B and C of Annex I.

      Until 31 December 2019 Member States may allow for the use of “trueness”, “precision” and “limit of detection” as specified in Table 2, as an alternative set of performance characteristics to “limit of quantification” and “uncertainty of measurement” as specified respectively in the first paragraph and Table 1.

      The uncertainty of measurement laid down in Table 1 shall not be used as an additional tolerance to the parametric values set out in Annex I.

      Table 1Minimum performance characteristic “Uncertainty of measurement”

      Parameters

      Uncertainty of measurement(See Note 1)% of the parametric value (except for pH)

      Notes

      Aluminium

      25

      Ammonium

      40

      Antimony

      40

      Arsenic

      30

      Benzo(a)pyrene

      50

      See Note 5

      Benzene

      40

      Boron

      25

      Bromate

      40

      Cadmium

      25

      Chloride

      15

      Chromium

      30

      Conductivity

      20

      Copper

      25

      Cyanide

      30

      See Note 6

      1,2-dichloroethane

      40

      Fluoride

      20

      Hydrogen ion concentration pH (expressed in pH units)

      0,2

      See Note 7

      Iron

      30

      Lead

      25

      Manganese

      30

      Mercury

      30

      Nickel

      25

      Nitrate

      15

      Nitrite

      20

      Oxidisability

      50

      See Note 8

      Pesticides

      30

      See Note 9

      Polycyclic aromatic hydrocarbons

      50

      See Note 10

      Selenium

      40

      Sodium

      15

      Sulphate

      15

      Tetrachloroethene

      30

      See Note 11

      Trichloroethene

      40

      See Note 11

      Trihalomethanes — total

      40

      See Note 10

      Total organic carbon (TOC)

      30

      See Note 12

      Turbidity

      30

      See Note 13

      Acrylamide, epichlorohydrin and vinyl chloride to be controlled by product specification.

      Table 2Minimum performance characteristics “Trueness”, “precision” and “limit of detection” — may be used until 31 December 2019

      Parameters

      Trueness(See Note 2)% of the parametric value (except for pH)

      Precision(See Note 3)% of the parametric value (except for pH)

      Limit of detection(See Note 4)% of the parametric value (except for pH)

      Notes

      Aluminium

      10

      10

      10

      Ammonium

      10

      10

      10

      Antimony

      25

      25

      25

      Arsenic

      10

      10

      10

      Benzo(a)pyrene

      25

      25

      25

      Benzene

      25

      25

      25

      Boron

      10

      10

      10

      Bromate

      25

      25

      25

      Cadmium

      10

      10

      10

      Chloride

      10

      10

      10

      Chromium

      10

      10

      10

      Conductivity

      10

      10

      10

      Copper

      10

      10

      10

      Cyanide

      10

      10

      10

      See Note 6

      1,2-dichloroethane

      25

      25

      10

      Fluoride

      10

      10

      10

      Hydrogen ion concentration pH (expressed in pH units)

      0,2

      0,2

      See Note 7

      Iron

      10

      10

      10

      Lead

      10

      10

      10

      Manganese

      10

      10

      10

      Mercury

      20

      10

      20

      Nickel

      10

      10

      10

      Nitrate

      10

      10

      10

      Nitrite

      10

      10

      10

      Oxidisability

      25

      25

      10

      See Note 8

      Pesticides

      25

      25

      25

      See Note 9

      Polycyclic aromatic hydrocarbons

      25

      25

      25

      See Note 10

      Selenium

      10

      10

      10

      Sodium

      10

      10

      10

      Sulphate

      10

      10

      10

      Tetrachloroethene

      25

      25

      10

      See Note 11

      Trichloroethene

      25

      25

      10

      See Note 11

      Trihalomethanes — total

      25

      25

      10

      See Note 10

      Turbidity

      25

      25

      25

      Acrylamide, epichlorohydrin and vinyl chloride to be controlled by product specification.

    3. (c)

      point 2.2 is replaced by the following:

      2.Notes to Tables 1 and 2

      Note 1

      Uncertainty of measurement is a non-negative parameter characterising the dispersion of the quantity values being attributed to a measurand, based on the information used. The performance criterion for measurement uncertainty (k = 2) is the percentage of the parametric value stated in the table or better. Measurement uncertainty shall be estimated at the level of the parametric value, unless otherwise specified.

      Note 2

      Trueness is a measure of systematic error, i.e. the difference between the mean value of the large number of repeated measurements and the true value. Further specifications are those set out in ISO 5725.

      Note 3

      Precision is a measure of random error and is usually expressed as the standard deviation (within and between batches) of the spread of results from the mean. Acceptable precision is twice the relative standard deviation. This term is further specified in ISO 5725.

      Note 4

      Limit of detection is either:

      • three times the standard deviation within a batch of a natural sample containing a low concentration of the parameter, or

      • five times the standard deviation of a blank sample (within a batch).

      Note 5

      If the value of uncertainty of measurement cannot be met, the best available technique should be selected (up to 60 %).

      Note 6

      The method determines total cyanide in all forms.

      Note 7

      Values for trueness, precision and uncertainty of measurement are expressed in pH units.

      Note 8

      Reference method: EN ISO 8467

      Note 9

      The performance characteristics for individual pesticides are given as an indication. Values for the uncertainty of measurement as low as 30 % can be achieved for several pesticides, higher values up to 80 % may be allowed for a number of pesticides.

      Note 10

      The performance characteristics apply to individual substances, specified at 25 % of the parametric value in Part B of Annex I.

      Note 11

      The performance characteristics apply to individual substances, specified at 50 % of the parametric value in Part B of Annex I.

      Note 12

      The uncertainty of measurement should be estimated at the level of 3 mg/l of the total organic carbon (TOC). CEN 1484 Guidelines for the determination of TOC and dissolved organic carbon (DOC) shall be used.

      Note 13

      The uncertainty of measurement should be estimated at the level of 1,0 NTU (nephelometric turbidity units) in accordance with EN ISO 7027.

  4. (4)

    point 3 is deleted.