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Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (Text with EEA relevance)
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Precautionary statements — General
Code | General precautionary statements | Hazard class | Hazard category | Conditions for use |
---|---|---|---|---|
(1) | (2) | (3) | (4) | (5) |
P101 | If medical advice is needed, have product container or label at hand. | as appropriate | Consumer products | |
P102 | Keep out of reach of children. | as appropriate | Consumer products | |
[F1P103 | Read carefully and follow all instructions. | as appropriate | Consumer products – omit where P202 is used] |
Textual Amendments
F1Substituted by Commission Regulation (EU) 2019/521 of 27 March 2019 amending, for the purposes of its adaptation to technical and scientific progress Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (Text with EEA relevance).
Precautionary statements — Prevention
Code | Prevention precautionary statements | Hazard class | Hazard category | Conditions for use |
---|---|---|---|---|
(1) | (2) | (3) | (4) | (5) |
[F1P201 | Obtain special instructions before use. | Explosives (section 2.1) | Unstable explosive | |
Germ cell mutagenicity (section 3.5) | 1A,1B, 2 | Consumer products – omit where P202 is used | ||
Carcinogenicity (section 3.6) | 1A,1B, 2 | |||
Reproductive toxicity (section 3.7) | 1A,1B, 2 | |||
Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | |||
P202 | Do not handle until all safety precautions have been read and understood. | Flammable gases (section 2.2) | A, B (chemically unstable gases) | |
Germ cell mutagenicity (section 3.5) | 1A,1B, 2 | |||
Carcinogenicity (section 3.6) | 1A,1B, 2 | |||
Reproductive toxicity (section 3.7) | 1A,1B, 2 | |||
Reproductive toxicity, effects on or via lactation (section 3.7) | Additional category | ] | ||
[F1P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Explosives (section 2.1) | Divisions 1.1, 1.2, 1.3, 1.4, 1.5 | |
Flammable gases (section 2.2) | 1A, 1B, 2 | |||
Aerosols (section 2.3) | 1, 2, 3 | |||
Flammable liquids (section 2.6) | 1, 2, 3 | |||
Flammable solids (section 2.7) | 1, 2 | |||
Self-reactive substances and mixtures (section 2.8) | Types A, B, C, D, E, F | |||
Pyrophoric liquids (section 2.9) | 1 | |||
Pyrophoric solids (section 2.10) | 1 | |||
Oxidising liquids (section 2.13) | 1, 2, 3 | |||
Oxidising solids (section 2.14) | 1, 2, 3 | |||
Organic peroxides (section 2.15) | Types A, B, C, D, E, F | |||
Desensitised explosives (section 2.17) | 1, 2, 3, 4 | ] | ||
[F2P211 | Do not spray on an open flame or other ignition source. | Aerosols (section 2.3) | 1, 2 | ] |
[F3P212 | Avoid heating under confinement or reduction of the desensitising agent. | Desensitised explosives (section 2.17) | 1, 2, 3, 4 | ] |
[F4P220 | Keep away from clothing and other combustible materials. | Oxidising gases (Section 2.4) | 1 | |
Oxidising liquids (Section 2.13) | 1, 2, 3 | |||
Oxidising solids (Section 2.14) | 1, 2, 3] | |||
[ F5 | ||||
F5 ] | ||||
[F1P222 | Do not allow contact with air. | Flammable gases (section 2.2) | Pyrophoric gas |
|
Pyrophoric liquids (section 2.9) | 1 | |||
Pyrophoric solids (section 2.10) | 1] | |||
[F4P223 | Do not allow contact with water. | Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2 | — if emphasis of the hazard statement is deemed necessary |
[F1P230 | Keep wetted with … | Explosives (section 2.1) | Divisions 1.1, 1.2, 1.3, 1.5 | Manufacturer/supplier to specify appropriate material
|
Desensitised explosives (section 2.17) | 1, 2, 3, 4 | Manufacturer/supplier to specify appropriate material] | ||
P231 | Handle and store contents under inert gas/… | Pyrophoric liquids (Section 2.9) | 1 | … Manufacturer/supplier to specify appropriate liquid or gas if ‘ inert gas ’ is not appropriate. |
Pyrophoric solids (Section 2.10) | 1 | |||
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2, 3 | — if the substance or mixture reacts readily with moisture in air.… Manufacturer/supplier to specify appropriate liquid or gas if ‘ inert gas ’ is not appropriate.] | ||
P232 | Protect from moisture. | Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2, 3 | |
[F1P233 | Keep container tightly closed. | Flammable liquids (section 2.6) | 1, 2, 3 |
|
Pyrophoric liquids (section 2.9) | 1 | |||
Pyrophoric solids (section 2.10) | 1 | |||
Desensitised explosives (section 2.17) | 1, 2, 3, 4 | |||
Acute toxicity – inhalation (section 3.1) | 1, 2, 3 |
| ||
Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8) | 3 | |||
Specific target organ toxicity – single exposure; narcotic effects (section 3.8) | 3] | |||
[F4P234 | Keep only in original packaging. | Explosives (Section 2.1) | Divisions 1.1, 1.2, 1.3, 1.4, 1.5 | |
Self-reactive substances and mixtures (Section 2.8) | Types A, B, C, D, E, F | |||
Organic peroxides (Section 2.15) | Types A, B, C, D, E, F | |||
Corrosive to metals (Section 2.16) | 1 | |||
P235 | Keep cool. | Flammable liquids (Section 2.6) | 1, 2, 3 | — for flammable liquids category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere |
Self-reactive substances and mixtures (Section 2.8) | Types A, B, C, D, E, F | — may be omitted if P411 is given on the label | ||
Self-heating substances and mixtures (Section 2.11) | 1, 2 | — may be omitted if P413 is given on the label | ||
Organic peroxides (Section 2.15) | Types A, B, C, D, E, F | — may be omitted if P411 is given on the label | ||
P240 | Ground and bond container and receiving equipment. | Explosives (Section 2.1) | Divisions 1.1, 1.2, 1.3, 1.4, 1.5 | — if the explosive is electrostatically sensitive |
Flammable liquids (Section 2.6) | 1, 2, 3 | — if the liquid is volatile and may generate an explosive atmosphere | ||
Flammable solids (Section 2.7) | 1, 2 | — if the solid is electrostatically sensitive | ||
Self-reactive substances and mixtures (Section 2.8) | Types A,B,C, D, E, F | — if electrostatically sensitive and able to generate an explosive atmosphere | ||
Organic peroxides (Section 2.15) | ||||
P241 | Use explosion-proof [electrical/ventilating/lighting/…] equipment. | Flammable liquids (Section 2.6) | 1, 2, 3 |
|
Flammable solids (Section 2.7) | 1, 2 |
| ||
P242 | Use non-sparking tools. | Flammable liquids (Section 2.6) | 1, 2, 3 | — if the liquid is volatile and may generate an explosive atmosphere and if the minimum ignition energy is very low. (This applies to substances and mixtures where the ignition energy is < 0,1 mJ, e.g. carbon disulphide). |
P243 | Take action to prevent static discharges. | Flammable liquids (Section 2.6) | 1, 2, 3 | — if the liquid is volatile and may generate an explosive atmosphere.] |
[F2P244 | Keep valves and fittings free from oil and grease. | Oxidising gases (section 2.4) | 1 | ] |
[F4P250 | Do not subject to grinding/shock/friction … | Explosives (Section 2.1) | Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5 | — if the explosive is mechanically sensitive… Manufacturer/supplier to specify applicable rough handling.] |
[F2P251 | Do not pierce or burn, even after use. | Aerosols (section 2.3) | 1, 2, 3 | ] |
P260 | Do not breathe dust/fume/gas/mist/vapours/spray. | Acute toxicity — inhalation (section 3.1) | 1, 2 | Manufacturer/supplier to specify applicable conditions. |
Specific target organ toxicity — single exposure (section 3.8) | 1, 2 | |||
Specific target organ toxicity — repeated exposure (section 3.9) | 1, 2 | |||
Skin corrosion (section 3.2) | 1A, 1B, 1C |
| ||
Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | |||
[F4P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. | Acute toxicity — inhalation (Section 3.1) | 3, 4 | — may be omitted if P260 is given on the labelManufacturer/supplier to specify applicable conditions. |
Respiratory sensitisation (Section 3.4) | 1, 1A, 1B | |||
Skin sensitisation (Section 3.4) | 1, 1A, 1B | |||
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8) | 3 | |||
Specific target organ toxicity — single exposure; narcotic effects (Section 3.8) | 3] | |||
P262 | Do not get in eyes, on skin, or on clothing. | Acute toxicity — dermal (section 3.1) | 1, 2 | |
[F4P263 | Avoid contact during pregnancy and while nursing. | Reproductive toxicity — effects on or via lactation (Section 3.7) | Additional category | ] |
P264 | Wash … thoroughly after handling. | Acute toxicity — oral (section 3.1) | 1, 2, 3, 4 | Manufacturer/supplier to specify parts of the body to be washed after handling. |
Acute toxicity — dermal (section 3.1) | 1, 2 | |||
Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
Skin irritation (section 3.2) | 2 | |||
Eye irritation (section 3.3) | 2 | |||
Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | |||
Specific target organ toxicity — single exposure (section 3.8) | 1, 2 | |||
Specific target organ toxicity — repeated exposure (section 3.9) | 1 | |||
P270 | Do not eat, drink or smoke when using this product. | Acute toxicity — oral (section 3.1) | 1, 2, 3, 4 | |
Acute toxicity — dermal (section 3.1) | 1, 2 | |||
Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | |||
Specific target organ toxicity — single exposure (section 3.8) | 1, 2 | |||
Specific target organ toxicity — repeated exposure (section 3.9) | 1 | |||
P271 | Use only outdoors or in a well-ventilated area. | Acute toxicity — inhalation (section 3.1) | 1, 2, 3, 4 | |
Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) | 3 | |||
Specific target organ toxicity — single exposure; narcosis (section 3.8) | 3 | |||
[F6P272 | Contaminated work clothing should not be allowed out of the workplace. | Skin sensitisation (section 3.4) | 1, 1A, 1B | ] |
P273 | Avoid release to the environment. | Hazardous to the aquatic environment — acute aquatic hazard (section 4.1) | 1 |
|
Hazardous to the aquatic environment — [F6long-term aquatic hazard (section 4.1)] | 1, 2, 3, 4 | |||
[ F7 ] | ||||
[F1P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Explosives (section 2.1) | Unstable explosive and divisions 1.1, 1.2, 1.3, 1.4, 1.5 | Manufacturer/supplier to specify the appropriate type of personal protective equipment. |
Flammable gases (section 2.2) | Pyrophoric gas | |||
Flammable liquids (section 2.6) | 1, 2, 3 | |||
Flammable solids (section 2.7) | 1, 2 | |||
Self-reactive substances and mixtures (section 2.8) | Types A, B, C, D, E, F | |||
Pyrophoric liquids (section 2.9) | 1 | |||
Pyrophoric solids (section 2.10) | 1 | |||
Self-heating substances and mixtures (section 2.11) | 1, 2 | |||
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2, 3 | |||
Oxidizing liquids (section 2.13) | 1, 2, 3 | |||
Oxidizing solids (section 2.14) | 1, 2, 3 | |||
Organic peroxides (section 2.15) | Types A, B, C, D, E, F | |||
Desensitised explosives (section 2.17) | 1, 2, 3, 4 | |||
Acute toxicity – dermal (section 3.1) | 1, 2, 3, 4 |
Manufacturer/supplier may further specify type of equipment where appropriate. | ||
Skin corrosion (section 3.2) | 1A, 1B, 1C |
Manufacturer/supplier may further specify type of equipment where appropriate. | ||
Skin irritation (section 3.2) | 2 |
Manufacturer/supplier may further specify type of equipment where appropriate. | ||
Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
Serious eye damage (section 3.3) | 1 |
Manufacturer/supplier may further specify type of equipment where appropriate. | ||
Eye irritation (section 3.3) | 2 | |||
Germ cell mutagenicity (section 3.5) | 1A, 1B, 2 | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | ||
Carcinogenicity (section 3.6) | 1A, 1B, 2 | |||
Reproductive toxicity (section 3.7) | 1A, 1B, 2] | |||
[ F8 | ||||
F8 | ||||
F8 | ||||
F8 ] | ||||
[F4P282 | Wear cold insulating gloves and either face shield or eye protection. | Gases under pressure (Section 2.5) | Refrigerated liquefied gas | |
P283 | Wear fire resistant or flame retardant clothing. | Oxidising liquids (Section 2.13) | 1 | |
Oxidising solids (Section 2.14) | 1 | |||
P284 | [In case of inadequate ventilation] wear respiratory protection. | Acute toxicity — inhalation (Section 3.1) | 1, 2 | — text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use.Manufacturer/supplier to specify equipment. |
Respiratory sensitisation (Section 3.4) | 1, 1A, 1B] | |||
[ F8 ] | ||||
[F4P231 + P232 | Handle and store contents under inert gas/… Protect from moisture. | Pyrophoric liquids (Section 2.9) | 1 | … Manufacturer/supplier to specify the appropriate liquid or gas if ‘ inert gas ’ is not appropriate. |
Pyrophoric solids (Section 2.10) | 1 | |||
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2, 3 | — if the substance or mixture reacts readily with moisture in air.… Manufacturer/supplier to specify appropriate liquid or gas if ‘ inert gas ’ is not appropriate.] | ||
[ F5 ] |
Textual Amendments
F2Substituted by Commission Regulation (EU) No 487/2013 of 8 May 2013 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (Text with EEA relevance).
F3Inserted by Commission Regulation (EU) 2019/521 of 27 March 2019 amending, for the purposes of its adaptation to technical and scientific progress Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (Text with EEA relevance).
F4Substituted by Commission Regulation (EU) 2016/918 of 19 May 2016 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (Text with EEA relevance).
F5 Deleted by Commission Regulation (EU) 2016/918 of 19 May 2016 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (Text with EEA relevance).
F6Substituted by Commission Regulation (EU) No 286/2011 of 10 March 2011 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (Text with EEA relevance).
F7Deleted by Commission Regulation (EU) No 286/2011 of 10 March 2011 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (Text with EEA relevance).
F8Deleted by Commission Regulation (EU) No 487/2013 of 8 May 2013 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (Text with EEA relevance).
Precautionary statements — Response
Code | Response precautionary statements | Hazard class | Hazard category | Conditions for use |
---|---|---|---|---|
(1) | (2) | (3) | (4) | (5) |
[F1P301 | IF SWALLOWED: | Acute toxicity – oral (section 3.1) | 1, 2, 3, 4 | |
Skin corrosion (section 3.2) | 1, 1A, 1B, 1C | |||
Aspiration Hazard (section 3.10) | 1 | |||
P302 | IF ON SKIN: | Pyrophoric liquids (section 2.9) | 1 | |
Pyrophoric solids (section 2.10) | 1 | |||
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2 | |||
Acute toxicity – dermal (section 3.1) | 1, 2, 3, 4 | |||
Skin irritation (section 3.2) | 2 | |||
Skin sensitisation (section 3.4) | 1, 1A, 1B] | |||
P303 | IF ON SKIN (or hair): | Flammable liquids (section 2.6) | 1, 2, 3 | |
Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
[F6P304 | IF INHALED: | Acute toxicity — inhalation (section 3.1) | 1, 2, 3, 4 | |
Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
Respiratory sensitisation (section 3.4) | 1, 1A, 1B | |||
Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) | 3 | |||
Specific target organ toxicity — single exposure; narcosis (section 3.8) | 3] | |||
P305 | IF IN EYES: | Skin corrosion (section 3.2) | 1A, 1B, 1C | |
Serious eye damage/eye irritation (section 3.3) | 1 | |||
Eye irritation (section 3.3) | 2 | |||
P306 | IF ON CLOTHING: | Oxidising liquids (section 2.13) | 1 | |
Oxidising solids (section 2.14) | 1 | |||
[ F8 ] | ||||
[F2P308 | IF exposed or concerned: | Germ cell mutagenicity (section 3.5) | 1A, 1B, 2 | |
Carcinogenicity (section 3.6) | 1A, 1B, 2 | |||
Reproductive toxicity (section 3.7) | 1A, 1B, 2 | |||
Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | |||
Specific target organ toxicity, single exposure (section 3.8) | 1, 2] | |||
[ F8 ] | ||||
[F2P310 | Immediately call a POISON CENTER/doctor/… | Acute toxicity — oral (section 3.1) | 1, 2, 3 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. |
Acute toxicity — dermal (section 3.1) | 1, 2 | |||
Acute toxicity — inhalation (section 3.1) | 1, 2 | |||
Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
Serious eye damage/eye irritation (section 3.3) | 1 | |||
Aspiration hazard (section 3.10) | 1 | |||
P311 | Call a POISON CENTER/doctor/… | Acute toxicity — inhalation (section 3.1) | 3 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. |
Respiratory sensitisation (section 3.4) | 1, 1A, 1B | |||
Specific target organ toxicity — single exposure (section 3.8) | 1, 2 | |||
[F4P312 | Call a POISON CENTRE/doctor/… if you feel unwell. | Acute toxicity — oral (Section 3.1) | 4 | … Manufacturer/supplier to specify the appropriate source of emergency medical advice. |
Acute toxicity — dermal (Section 3.1) | 3, 4 | |||
Acute toxicity — inhalation (Section 3.1) | 4 | |||
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8) | 3 | |||
Specific target organ toxicity — single exposure; narcotic effects (Section 3.8) | 3] ] | |||
[F6P313 | Get medical advice/attention. | Skin irritation (section 3.2) | 2, 3 | |
Eye irritation (section 3.3) | 2 | |||
Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
Germ cell mutagenicity (section 3.5) | 1A, 1B, 2 | |||
Carcinogenicity (section 3.6) | 1A, 1B, 2 | |||
Reproductive toxicity (section 3.7) | 1A, 1B, 2 | |||
Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category] | |||
P314 | Get medical advice/attention if you feel unwell. | Specific target organ toxicity — repeated exposure (section 3.9) | 1, 2 | |
P315 | Get immediate medical advice/attention. | Gases under pressure (section 2.5) | Refrigerated liquefied gas | |
[F4P320 | Specific treatment is urgent (see … on this label). | Acute toxicity — inhalation (Section 3.1) | 1, 2 | — if immediate administration of antidote is required.… Reference to supplemental first aid instruction. |
P321 | Specific treatment (see … on this label). | Acute toxicity — oral (Section 3.1) | 1, 2, 3 | — if immediate administration of antidote is required.… Reference to supplemental first aid instruction. |
Acute toxicity, dermal (Section 3.1) | 1, 2, 3, 4 | — if immediate measures such as specific cleansing agent are advised.… Reference to supplemental first aid instruction. | ||
Acute toxicity — inhalation (Section 3.1) | 3 | — if immediate specific measures are required.… Reference to supplemental first aid instruction. | ||
Skin corrosion (Section 3.2) | 1, 1A, 1B, 1C | … Reference to supplemental first aid instruction. Manufacturer/supplier may specify a cleansing agent if appropriate. | ||
Skin irritation (Section 3.2) | 2 | |||
Skin sensitisation (Section 3.4) | 1, 1A, 1B | |||
Specific target organ toxicity — single exposure (Section 3.8) | 1 | — if immediate measures are required.… Reference to supplemental first aid instruction.] | ||
[ F8 | ||||
F8 ] | ||||
P330 | Rinse mouth. | Acute toxicity — oral (section 3.1) | 1, 2, 3, 4 | |
Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
P331 | Do NOT induce vomiting. | Skin corrosion (section 3.2) | 1A, 1B, 1C | |
Aspiration hazard (section 3.10) | 1 | |||
[F1P332 | If skin irritation occurs: | Skin irritation (section 3.2) | 2 | may be omitted if P333 is given on the label.] |
[F6P333 | If skin irritation or rash occurs: | Skin sensitisation (section 3.4) | 1, 1A, 1B | ] |
[F4P334 | Immerse in cool water [or wrap in wet bandages]. | Pyrophoric liquids (Section 2.9) | 1 | — text in square brackets to be used for pyrophoric liquids and solids |
Pyrophoric solids (Section 2.10) | 1 | |||
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2 | Use only ‘ immerse in cool water. ’ Text in square brackets should not be used.] | ||
P335 | Brush off loose particles from skin. | Pyrophoric solids (section 2.10) | 1 | |
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2 | |||
P336 | Thaw frosted parts with lukewarm water. Do not rub affected area. | Gases under pressure (section 2.5) | Refrigerated liquefied gas | |
P337 | If eye irritation persists: | Eye irritation (section 3.3) | 2 | |
P338 | Remove contact lenses, if present and easy to do. Continue rinsing. | Skin corrosion (section 3.2) | 1A, 1B, 1C | |
Serious eye damage/eye irritation (section 3.3) | 1 | |||
Eye irritation (section 3.3) | 2 | |||
[F2P340 | Remove person to fresh air and keep comfortable for breathing. | Acute toxicity — inhalation (section 3.1) | 1, 2, 3, 4 | |
Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
Respiratory sensitisation (section 3.4) | 1, 1A, 1B | |||
Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) | 3 | |||
Specific target organ toxicity — single exposure; narcosis (section 3.8) | 3] | |||
[ F8 ] | ||||
[F6P342 | If experiencing respiratory symptoms: | Respiratory sensitisation (section 3.4) | 1, 1A, 1B | ] |
[ F8 ] | ||||
P351 | Rinse cautiously with water for several minutes. | Skin corrosion (section 3.2) | 1A, 1B, 1C | |
Serious eye damage/eye irritation (section 3.3) | 1 | |||
Eye irritation (section 3.3) | 2 | |||
[F2P352 | Wash with plenty of water/… | Acute toxicity — dermal (section 3.1) | 1, 2, 3, 4 | …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. |
Skin irritation (section 3.2) | 2 | |||
Skin sensitisation (section 3.4) | 1, 1A, 1B] | |||
[F4P353 | Rinse skin with water [or shower]. | Flammable liquids (Section 2.6) | 1, 2, 3 | — text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical. |
Skin corrosion (Section 3.2) | 1, 1A, 1B, 1C] | |||
P360 | Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. | Oxidising liquids (section 2.13) | 1 | |
Oxidising solids (section 2.14) | 1 | |||
[F2P361 | Take off immediately all contaminated clothing. | Flammable liquids (section 2.6) | 1, 2, 3 | |
Acute toxicity — dermal (section 3.1) | 1, 2, 3 | |||
Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
P362 | Take off contaminated clothing. | Acute toxicity, dermal (section 3.1) | 4 | |
Skin irritation (section 3.2) | 2 | |||
Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
P363 | Wash contaminated clothing before reuse. | Skin corrosion (section 3.2) | 1A, 1B, 1C | ] |
[F9P364 | And wash it before reuse. | Acute toxicity, dermal (section 3.1) | 1, 2, 3, 4 | |
Skin irritation (section 3.2) | 2 | |||
Skin sensitisation (section 3.4) | 1, 1A, 1B | ] | ||
[F1P370 | In case of fire: | Explosives (section 2.1) | Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5 | |
Oxidising gases (section 2.4) | 1 | |||
Flammable liquids (section 2.6) | 1, 2, 3 | |||
Flammable solids (section 2.7) | 1, 2 | |||
Self-reactive substances and mixtures (section 2.8) | Types A, B, C, D, E, F | |||
Pyrophoric liquids (section 2.9) | 1 | |||
Pyrophoric solids (section 2.10) | 1 | |||
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2, 3 | |||
Oxidising liquids (section 2.13) | 1, 2, 3 | |||
Oxidising solids (section 2.14) | 1, 2, 3 | |||
Organic Peroxides (section 2.15) | Types A, B, C, D, E, F | |||
Desensitised explosives (section 2.17) | 1, 2, 3 | |||
P371 | In case of major fire and large quantities: | Oxidising liquids (section 2.13) | 1 | |
Oxidising solids (section 2.14) | 1 | |||
Desensitised explosives (section 2.17) | 4 | ] | ||
[F4P372 | Explosion risk. | Explosives (Section 2.1) | Unstable explosives and Divisions 1.1, 1.2, 1.3, and 1.5 | |
Division 1.4 | — except for explosives of division 1.4 (compatibility group S) in transport packaging. | |||
Self-reactive substances and mixtures (Section 2.8) | Type A | |||
Organic peroxides (Section 2.15) | Type A | |||
P373 | DO NOT fight fire when fire reaches explosives. | Explosives (Section 2.1) | Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.5 | |
Division 1.4 | — except for explosives of division 1.4 (compatibility group S) in transport packaging. | |||
Self-reactive substances and mixtures (Section 2.8) | Type A | |||
Organic peroxides (Section 2.15) | Type A] | |||
[ F5 ] | ||||
[F1P375 | Fight fire remotely due to the risk of explosion. | Explosives (section 2.1) | Division 1.4 |
|
Self-reactive substances and mixtures (section 2.8) | Type B | |||
Oxidising liquids (section 2.13) | 1 | |||
Oxidising solids (section 2.14) | 1 | |||
Organic peroxides (section 2.15) | Type B | |||
Desensitised explosives (section 2.17) | 1, 2, 3, 4] | |||
P376 | Stop leak if safe to do so. | Oxidising gases (section 2.4) | 1 | |
[F1P377 | Leaking gas fire: Do not extinguish, unless leak can be stopped safely. | Flammable gases (section 2.2) | 1A, 1B, 2 | ] |
[F4P378 | Use … to extinguish. | Flammable liquids (Section 2.6) | 1, 2, 3 | — if water increases risk… Manufacturer/supplier to specify appropriate media |
Flammable solids (Section 2.7) | 1, 2 | |||
Self-reactive substances and mixtures (Section 2.8) | Types B, C, D, E, F | |||
Pyrophoric liquids (Section 2.9) | 1 | |||
Pyrophoric solids (Section 2.10) | 1 | |||
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2, 3 | |||
Oxidising liquids (Section 2.13) | 1, 2, 3 | |||
Oxidising solids (Section 2.14) | 1, 2, 3 | |||
Organic peroxides (Section 2.15) | Types B, C, D, E, F | |||
[F1P380 | Evacuate area. | Explosives (section 2.1) | Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 | |
Self-reactive substances and mixtures (section 2.8) | Types A, B | |||
Oxidising liquids (section 2.13) | 1 | |||
Oxidising solids (section 2.14) | 1 | |||
Organic peroxides (section 2.15) | Types A, B | |||
Desensitised explosives (section 2.17) | 1, 2, 3, 4 | ] | ||
[F1P381 | In case of leakage, eliminate all ignition sources | Flammable gases (section 2.2) | 1A, 1B, 2 | ] ] |
P390 | Absorb spillage to prevent material damage. | Corrosive to metals (section 2.16) | 1 | |
P391 | Collect spillage. | Hazardous to the aquatic environment – acute aquatic hazard (section 4.1) | 1 | |
Hazardous to the aquatic environment – [F6long-term aquatic hazard (section 4.1)] | 1, 2 | |||
[F2P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER/doctor/… | Acute toxicity — oral (section 3.1) | 1, 2, 3 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. |
Aspiration hazard (section 3.10) | 1 | |||
[F1P301 + P312 | IF SWALLOWED: Call a POISON CENTER/doctor/… if you feel unwell | Acute toxicity – oral (section 3.1) | 4 | … Manufacturer/supplier to specify the appropriate source of emergency medical advice] ] |
[ F5 ] | ||||
[F4P302 + P334 | IF ON SKIN: Immerse in cool water or wrap in wet bandages. | Pyrophoric liquids (Section 2.9) | 1 | ] |
[ F8 ] | ||||
[F2P302 + P352 | IF ON SKIN: Wash with plenty of water/… | Acute toxicity — dermal (section 3.1) | 1, 2, 3, 4 | …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. |
Skin irritation (section 3.2) | 2 | |||
Skin sensitisation (section 3.4) | 1, 1A, 1B] | |||
[ F5 | ||||
F5 ] | ||||
[F2P304 + P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. | Acute toxicity — inhalation (section 3.1) | 1, 2, 3, 4 | |
Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
Respiratory sensitisation (section 3.4) | 1, 1A, 1B | |||
Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) | 3 | |||
Specific target organ toxicity — single exposure; narcosis (section 3.8) | 3] | |||
[ F8 ] | ||||
[ F5 | ||||
F5 | ||||
F5 ] | ||||
P306 + P360 | IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. | Oxidising liquids (section 2.13) | 1 | |
Oxidising solids (section 2.14) | 1 | |||
[F2P308 + P311 | IF exposed or concerned: Call a POISON CENTER/doctor/… | Specific target organ toxicity — single exposure (section 3.8) | 1, 2 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice.] |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. | Germ cell mutagenicity (section 3.5) | 1A, 1B, 2 | |
Carcinogenicity (section 3.6) | 1A, 1B, 2 | |||
Reproductive toxicity (section 3.7) | 1A, 1B, 2 | |||
Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | |||
[ F8 ] | ||||
[F4P332 + P313 | If skin irritation occurs: Get medical advice/attention. | Skin irritation (Section 3.2) | 2 | — may be omitted when P333 + P313 is given on the label.] |
[F6P333 + P313 | If skin irritation or rash occurs: Get medical advice/attention. | Skin sensitisation (section 3.4) | 1, 1A, 1B | ] |
[F10P336 + P315 | Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention. | Gases under pressure (Section 2.5) | Refrigerated liquefied gas | ] |
[ F5 | ||||
F5 ] | ||||
P337 + P313 | If eye irritation persists: Get medical advice/attention. | Eye irritation (section 3.3) | 2 | |
[F2P342 + P311 | If experiencing respiratory symptoms: Call a POISON CENTER/doctor/… | Respiratory sensitisation (section 3.4) | 1, 1A, 1B | …Manufacturer/supplier to specify the appropriate source of emergency medical advice.] |
[F9P361 + P364 | Take off immediately all contaminated clothing and wash it before reuse. | Acute toxicity, dermal (section 3.1) | 1, 2, 3 | |
P362 + P364 | Take off contaminated clothing and wash it before reuse. | Acute toxicity, dermal (section 3.1) | 4 | |
Skin irritation (section 3.2) | 2 | |||
Skin sensitisation (section 3.4) | 1, 1A, 1B] | |||
P370 + P376 | In case of fire: Stop leak if safe to do so. | Oxidizing gases (section 2.4) | 1 | |
[F4P370 + P378 | In case of fire: Use … to extinguish. | Flammable liquids (Section 2.6) | 1, 2, 3 | — if water increases risk.… Manufacturer/sup-plier to specify appropriate media. |
Flammable solids (Section 2.7) | 1, 2 | |||
Self-reactive substances and mixtures (Section 2.8) | Types C, D, E, F | |||
Pyrophoric liquids (Section 2.9) | 1 | |||
Pyrophoric solids (Section 2.10) | 1 | |||
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2, 3 | |||
Oxidising liquids (Section 2.13) | 1, 2, 3 | |||
Oxidising solids (Section 2.14) | 1, 2, 3 | |||
Organic peroxides (Section 2.15) | Types C, D, E, F] | |||
[F10P301 + P330 + P331 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. | Skin corrosion (Section 3.2) | 1, 1A, 1B, 1C | |
P302 + P335 + P334 | IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]. | Pyrophoric solids (Section 2.10) | 1 | — text in square brackets to be used for pyrophoric solids |
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2 | — use only ‘ Immerse in cold water ’ . Text in square brackets should not be used. | ||
P303 + P361 + P353 | IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. | Flammable liquids (Section 2.6) | 1, 2, 3 | — text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical. |
Skin corrosion (Section 3.2) | 1, 1A, 1B, 1C | |||
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. | Skin corrosion (Section 3.2) | 1, 1A, 1B, 1C | |
Serious eye damage/eye irritation (Section 3.3) | 1 | |||
Eye irritation (Section 3.3) | 2 | ] | ||
[ F5 ] | ||||
[F1P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. | Explosives (section 2.1) | Division 1.4 |
|
Desensitised explosives (section 2.17) | 1, 2, 3 | |||
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. | Oxidising liquids (section 2.13) | 1 | |
Oxidising solids (section 2.14) | 1 | |||
Desensitised explosives (section 2.17) | 4] | |||
[F10P370 + P372 + P380 + P373 | In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives | Explosives (Section 2.1) | Unstable explosives and divisions 1.1, 1.2, 1.3, 1.5 | |
Division 1.4 | — except for explosives of division 1.4 (compatibility group S) in transport packaging. | |||
Self-reactive substances and mixtures (Section 2.8) | Type A | |||
Organic peroxides (Section 2.15) | Type A | |||
P370 + P380 + P375 + [P378] | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish]. | Self-reactive substances and mixtures (Section 2.8) | Type B | — text in square brackets to be used if water increases risk.… Manufacturer/supplier to specify appropriate media. |
Organic peroxides (Section 2.15) | Type B] |
Textual Amendments
F9 Inserted by Commission Regulation (EU) No 487/2013 of 8 May 2013 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (Text with EEA relevance).
F10Inserted by Commission Regulation (EU) 2016/918 of 19 May 2016 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (Text with EEA relevance).
Precautionary statements — Storage
Code | Storage precautionary statements | Hazard class | Hazard category | Conditions for use |
---|---|---|---|---|
(1) | (2) | (3) | (4) | (5) |
[F1P401 | Store in accordance with … | Explosives (section 2.1) | Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 | … Manufacturer/supplier to specify local/regional/national/international regulations as applicable. |
Desensitised explosives (section 2.17) | 1, 2, 3, 4] | |||
P402 | Store in a dry place. | Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2, 3 | |
[F1P403 | Store in a well-ventilated place. | Flammable gases (section 2.2) | 1A, 1B, 2 | |
Oxidising gases (section 2.4) | 1 | |||
Gases under pressure (section 2.5) | Compressed gas | |||
Liquefied gas | ||||
Refrigerated liquefied gas | ||||
Dissolved gas | ||||
Flammable liquids (section 2.6) | 1, 2, 3 |
| ||
Self-reactive substances and mixtures (section 2.8) | Types A, B, C, D, E, F |
| ||
Organic peroxides (section 2.15) | ||||
Acute toxicity – inhalation (section 3.1) | 1, 2, 3 |
| ||
Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8) | 3 | |||
Specific target organ toxicity – single exposure; narcotic effects (section 3.8) | 3] | |||
P404 | Store in a closed container. | Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2, 3 | |
P405 | Store locked up. | Acute toxicity — oral (section 3.1) | 1, 2, 3 | |
Acute toxicity — dermal (section 3.1) | 1, 2, 3 | |||
Acute toxicity — inhalation (section 3.1) | 1, 2, 3 | |||
Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
Germ cell mutagenicity (section 3.5) | 1A, 1B, 2 | |||
Carcinogenicity (section 3.6) | 1A, 1B, 2 | |||
Reproductive toxicity (section 3.7) | 1A, 1B, 2 | |||
Specific target organ toxicity — single exposure (section 3.8) | 1, 2 | |||
Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) | 3 | |||
Specific target organ toxicity — single exposure; narcosis (section 3.8) | 3 | |||
Aspiration hazard (section 3.10) | 1 | |||
[F4P406 | Store in a corrosion-resistant/… container with a resistant inner liner. | Corrosive to metals (Section 2.16) | 1 | — may be omitted if P234 is given on the label… Manufacturer/supplier to specify other compatible materials.] |
[F4P407 | Maintain air gap between stacks or pallets. | Self-heating substances and mixtures (Section 2.11) | 1, 2 | ] |
[F2P410 | Protect from sunlight. | Aerosols (section 2.3) | 1,2, 3 | |
Gases under pressure (section 2.5) | Compressed gas Liquefied gas Dissolved gas | — may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, Model Regulations, unless those gases are subject to (slow) decomposition or polymerisation | ||
Self-heating substances and mixtures (section 2.11) | 1, 2 | |||
Organic peroxides (section 2.15) | Types A, B, C, D, E, F | ] | ||
[F4P411 | Store at temperatures not exceeding … °C/… °F. | Self-reactive substances and mixtures (Section 2.8) | Types A, B, C, D, E, F | — if temperature control is required (according to Annex I, Section 2.8.2.4 or 2.15.2.3) or if otherwise deemed necessary.… Manufacturer/supplier to specify temperature using the applicable temperature scale. |
Organic peroxides (Section 2.15) | Types A, B, C, D, E, F | |||
P412 | Do not expose to temperatures exceeding 50 °C/ 122 °F. | Aerosols (Section 2.3) | 1, 2, 3 | Manufacturer/supplier to use applicable temperature scale. |
P413 | Store bulk masses greater than … kg/… lbs at temperatures not exceeding … °C/… °F. | Self-heating substances and mixtures (Section 2.11) | 1, 2 | … Manufacturer/supplier to specify mass and temperature using applicable scale. |
P420 | Store separately. | Self-reactive substances and mixtures (Section 2.8) | Types A, B, C, D, E, F | |
Self-heating substances and mixtures (Section 2.11) | 1,2 | |||
Oxidising liquids (Section 2.13) | 1 | |||
Oxidising solids (Section 2.14) | 1 | |||
Organic peroxides (Section 2.15) | Types A,B,C,D,E,F] | |||
[ F5 | ||||
F5 ] | ||||
P402 + P404 | Store in a dry place. Store in a closed container. | Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2, 3 | |
[F4P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. | Acute toxicity — inhalation (Section 3.1) | 1, 2, 3 | — if the substance or mixture is volatile and may generate a hazardous atmosphere. |
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8) | 3 | |||
Specific target organ toxicity — single exposure; narcosis (Section 3.8) | 3 | |||
P403 + P235 | Store in a well-ventilated place. Keep cool. | Flammable liquids (Section 2.6) | 1, 2, 3 | — for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. | Gases under pressure (Section 2.5) | Compressed gas | — P410 may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, unless those gases are subject to (slow) decomposition or polymerisation. |
Liquefied gas | ||||
Dissolved gas | ||||
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. | Aerosols (Section 2.3) | 1, 2, 3 | Manufacturer/ supplier to use applicable temperature scale.] |
[ F5 ] |
Precautionary statements — Disposal
Code | Disposal precautionary statements | Hazard class | Hazard category | Conditions for use |
---|---|---|---|---|
(1) | (2) | (3) | (4) | (5) |
[F1P501 | Dispose of contents/container to … | Flammable liquids (section 2.6) | 1, 2, 3 | … in accordance with local/regional/national/international regulation (to be specified). Manufacturer/supplier to specify whether disposal requirements apply to contents, container or both. |
Self-reactive substances and mixtures (section 2.8) | Types A, B, C, D, E, F | |||
Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2, 3 | |||
Oxidising liquids (section 2.13) | 1, 2, 3 | |||
Oxidising solids (section 2.14) | 1, 2, 3 | |||
Organic peroxides (section 2.15) | Types A, B, C, D, E, F | |||
Desensitised explosives (section 2.17) | 1, 2, 3, 4 | |||
Acute toxicity – oral (section 3.1) | 1, 2, 3, 4 | |||
Acute toxicity – dermal (section 3.1) | 1, 2, 3, 4 | |||
Acute toxicity – inhalation (section 3.1) | 1, 2, 3 | |||
Skin corrosion (section 3.2) | 1, 1A, 1B, 1C | |||
Respiratory sensitisation (section 3.4) | 1, 1A, 1B | |||
Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
Germ cell mutagenicity (section 3.5) | 1A, 1B, 2 | |||
Carcinogenicity (section 3.6) | 1A, 1B, 2 | |||
Reproductive toxicity (section 3.7) | 1A, 1B, 2 | |||
Specific target organ toxicity – single exposure (section 3.8) | 1, 2 | |||
Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8) | 3 | |||
Specific target organ toxicity – single exposure; narcotic effects (section 3.8) | 3 | |||
Specific target organ toxicity – repeated exposure (section 3.9) | 1, 2 | |||
Aspiration hazard (section 3.10) | 1 | |||
Hazardous to the aquatic environment – acute aquatic hazard (section 4.1) | 1 | |||
Hazardous to the aquatic environment – chronic aquatic hazard (section 4.1) | 1, 2, 3, 4] | |||
[F4P502 | Refer to manufacturer or supplier for information on recovery or recycling | Hazardous to the ozone layer (Section 5.1) | 1 | ] |
[F3P503 | Refer to manufacturer/ supplier/… for information on disposal/recovery/ recycling | Explosives (section 2.1) | Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 | … Manufacturer/supplier to specify appropriate source of information in accordance with local/regional/national/international regulations as applicable.] ] |
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