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The Cosmetic Products (Safety) Regulations 2008

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Regulations 6 and 21(1)

SCHEDULE 4U.K.

This schedule has no associated Explanatory Memorandum

PART 1U.K.LIST OF SUBSTANCES WHICH COSMETIC PRODUCTS MUST NOT CONTAIN EXCEPT SUBJECT TO RESTRICTIONS AND CONDITIONS

[F1(*) As a preservative, see Schedule 6, Part 1, No 34.(**) This limit applies to the substance and not to the finished cosmetic product]

[F2(*) This limit applies to the substance and not to the finished cosmetic product.]

[F2(**) The sum of those substances used in combination should not exceed the limits given in column d.]

1 The substances may be used singly or in combination provided that the sum of the ratios of the levels of each of them in the cosmetic product expressed with reference to the maximum level authorised for each of them does not exceed 1.

2 Only if the concentration exceeds 0.05%.

3 These substances may be used singly or in combination provided that the sum of the ratios of the levels of each of them in the cosmetic product expressed with reference to the maximum level authorised for each of them does not exceed 2.

4 The quantity of sodium, potassium or lithium hydroxide is expressed as weight of sodium hydroxide. In cases of mixtures, the sum should not exceed the limits given in column d.

5 The concentration of sodium, potassium or lithium hydroxide is expressed as weight of sodium hydroxide. In case of mixtures, the sum should not exceed the limits given in column d.

6 As a preservative, see Schedule 6, Part 1, entry 3.

7 Solely for products which might be used for children under three years of age and which remain in prolonged contact with the skin.

8 As a preservative, see Schedule 6, Part 1, entry 9.

9 As a preservative, see Schedule 6, Part 1, entry 23.

10 As a preservative, see Schedule 6, Part 1, entry 8.

[F311 The free base and salts of this hair colouring ingredient, unless prohibited under Schedule 3, are permitted for use. ]

Reference numberSubstanceRestrictionsConditions of use and warnings which must be printed on the label
Field of application and/or useMaximum authorised concentration in the finished cosmetic productOther limitations and requirements
abcdef
1aBoric acid, borates and tetraborates with the exception of N,N-dimethyl anilium tatrakis (pentafluorophenyl) borate(a) Talc(a) 5% (by mass/mass as boric acid)(a) 1. Not to be used in products for children under 3 years of age(a) 1. Not to be used for children under 3 years of age
2. Not to be used on peeling or irritated skin if the concentration of free soluble borates exceeds 1.5% (by mass/mass as boric acid)2. Not to be used on peeling or irritated skin
(b) Products for all hygiene(b) 0,1 % (by mass/mass as boric acid)(b) 1. Not to be used in products for children under 3 years of age(b) 1. Not to be swallowed
2. Not to be used for children under 3 years of age
(c) Other products (excluding bath products and hair waving products)(c) 3% (by mass//mass as boric acid)(c) 1. Not to be used in products for children under 3 years of age(c) 1. Not to be used for children under 3 years of age
2. Not to be used on peeling or irritated skin if the concentration of free soluble borates exceeds 1.5% (by mass/mass as boric acid)2. Not to be used on peeling or irritated skin
1bTetraborates(a) Bath products(a) 18% (by mass/mass as boric acid)(a) Not to be used in products for children under 3 years of age(a) Not to be used for bathing children under 3 years of age
(b) Hair waving products(b) 8% (by mass/mass as boric acid)(b) Rinse well
2aThioglycollic acid and its salts(a) Hair waving or straightening products:(a) (b) (c): The directions must obligatorily incorporate the following sentences:(a):
— general use— 8% ready for use pH 7 to 9.5— Contains thioglycolate
— professional use— 11% ready for use pH 7 to 9.5— Follow the instructions
(b) Depilatories— 5% ready for use pH 7 to 12.7— Avoid contact with eyes—Keep out of reach of children
(c) Other hair-care products which are removed after application— 2% ready for use pH to 9.5— In the event of contact with eyes, rinse immediately with plenty of water and seek medical advice— For professional use only (b) and (c):
The abovementioned percentages are calculated as thioglycollic acid— Contains thioglycolate
— Follow the instructions
— Wear suitable gloves ((a) and (c) only)— Keep out of each of children
2bThioglycollic acid estersHair waving or straightening products:The directions for use must obligatorily incorporate the following sentences:— Contains thioglycolate
— Follow the instructions
— Keep out of reach of children
— For professional use only
— general use— 8% ready for use pH 6 to 9.5

— may cause sensitisation

— In the event of contact with eyes, rinse immediately with plenty of water and seek medical advice

— professional use— 11% ready for use pH 6 to 9.5— Avoid contact with eyes— For professional use only
The abovementioned % are calculated as thioglycollic acid— Wear suitable gloves
3Oxalic acid, its esters and alkaline saltsHair care products5%For professional use only
4Ammonia6% calculated as ammonia (NH3)Above 2%: contains ammonia
5Tosylchloramide sodium (INN)0.2%
6Chlorates of alkali metals(a) Toothpaste(a) 5%
(b) Other uses(b) 3%
7Dichloromethane35%0.2% as maximum impurity content
8p-Phenylenediamine, its N-substituted derivatives and its salts; N-substituted derivatives of o-Phenylenediamine1, with the exception of those derivatives listed elsewhere in this Schedule and under reference numbers 364, 1309,1311 and 1312 in Schedule 3Oxidizing colouring agents for hair dyeing6% calculated as free base, subject to the provisions of “Combination Rule A” at the end of this schedule.
(a) general use(a) Can cause allergic reaction. Contains phenylenediamines. Do not use to dye eye lashes or eyebrows
(b) professional use(b) For professional use only. Contains phenylenediamines. Can cause an allergic reaction. Wear suitable gloves.
9Methylphenylene-diamines, their N-substituted derivatives and their salts(1) with the exception of substances numbers 364, 1310 and 1313 in Schedule 3.Oxidizing colouring agents for hair dyeing10% calculated as free base, subject to the provisions of “Combination Rule A” at the end of this schedule.
(a) general use(a) Can cause an allergic reaction. Contains phenylenediamines. Do not use to dye eyelashes or eyebrows.
(b) professional use(b) For professional use only. Contains phenylenediamines. Can cause an allergic reaction. Wear suitable gloves.
10Diaminophenols1Oxidizing colouring agents for hair dyeing10% calculated as free base, subject to the provisions of “Combination Rule A”
(a) general use(a) Can cause an allergic reaction. Contains diaminophenols. Do not use to dye eyelashes or eyebrows.
(b) professional use(b) For professional use only. Contains diaminophenols. Can cause allergic reaction. Wear suitable gloves.
11Dichlorophen (INN)0.5%Contains dichlorophen
12Hydrogen peroxide, and other compounds or mixture that release hydrogen peroxide, including carbamide peroxide and zinc peroxide(a) hair-care preparations12% of H2O2 (40 volumes), present or releasedWear suitable gloves
(b) Skin-care preparations4% of H2O2, present or released
(c) Nail hardening preparations2% of H2O2 present or released(a) (b) (c): Contains hydrogen peroxide.
(d) Oral hygiene products0.1% of H2O2, present or releasedAvoid contact with eyes.
Rinse immediately if product comes into contact with them
13FormaldehydeNail hardeners5% calculated as formaldehydeProtect cuticles with grease or oil. Contains formaldehyde2
14Hydroquinone3(a) Oxidising colouring agent for hair-dying:0.3%, subject to the provisions of “Combination Rule B”(a) 1. — Do not use to dye eyelashes or eyebrows
1. General use— Rinse the eyes immediately if the products comes into contact with them
— contains hydroquinone
2. Professional use2. — For professional use only
— Contains hydroquinone
— Rinse the eyes immediately if the product comes into contact with them
(b) Artificial nail systems0.02% (after mixing for use), %, subject to the provisions of “Combination Rule B”Professional use only(b) — For professional use only
— Avoid skin contact
— Read directions for use carefully
15aPotassium or sodium hydroxide(a) Nail cuticle solvent(a) 5% by weight4(a) Contains alkali. Avoid contact with eyes. Can cause blindness. Keep out of reach of children
(b) Hair straightener(b)(b)
1. General use1. 2% by weight41. Contains alkali. Avoid contact with eyes. Can cause blindness. Keep out of reach of children
2. Professional use2. 4.5% by weight42. For professional use only. Avoid contact with eyes. Can cause blindness.
(c) pH adjuster(c) Not to exceed pH 12.7(c) Keep out of each of children. Avoid contact with eyes
   — depilatories
(d) Other uses as pH adjuster(d) Not to exceed pH 11
15bLithium hydroxide(a) Hair straighteners(a)(a)
1. General use1. 2%5 by weight1. Contains alkali
Avoid contact with eyes
Can cause blindness
Keep out of each of children
2. Professional use2. 4.5%(6) by weight

2. For professional use only

Avoid contact with eyes

Can cause blindness

(b) pH adjuster – for depilatories(b) pH value not to exceed pH 12.7(b) Contains alkali
Keep out of reach of children
Avoid contact with eyes
(c) Other uses – as pH adjuster (for rinse-off products only)(c) pH value not to exceed pH 11
15cCalcium hydroxide(a) Hair straighteners containing two components: calcium hydroxide and a guanidine salt(a) 7% by weight of calcium hydroxide(a) Contains alkali
Avoid contact with eyes
Keep out of reach of children
Can cause blindness
(b) pH adjuster – for depilatories(b) pH value not to exceed pH 12.7(b) Contains alkali
Keep out of reach of children
Avoid contact with eyes
(c) Other uses (e.g. pH adjuster, processing aid)(c) pH value not to exceed pH 11
161-Naphthol (CAS No 90-15-3) and its saltsOxidising colouring agents for hair dyeing2.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.0%Can cause allergic reaction
17Sodium nitriteRust inhibitor0.2%Do not use with secondary and/or tertiary amines or other substances forming nitrosamines
18NitromethaneRust inhibitor0.3%
19[omitted]
20[omitted]
21Quinine and its salts(a) Shampoos(a) 0.5% calculated as quinine base
(b) Hair lotions(b) 0.2% calculated as quinine base
22Resorcinol3(a) Oxidizing colouring agent for hair dyeing(a) 5%(a)
1. general use1. Contains resorcinol. Rinse hair well after application. Do not use to dye eyelashes or eyebrows.
Rinse eyes immediately if product comes into contact with them
2. professional use2. For professional use only. Contains resorcinol.
Rinse eyes immediately if product comes into contact with them
(b) hair lotions and shampoos(b) 0.5%(b) Contains resorcinol
23(a) Alkali sulfides(a) Depilatories(a) 2% calculated as sulphur(a) pH value not to exceed 12.7(a) Keep out of reach of children.
Avoid contact with eyes
(b) Alkaline earth sulfides2 (see Schedule 5, Part 1)(b) Depilatories(b) 6% calculated as sulphur(b) pH value not to exceed 12.7(b) Keep out of reach of children.
Avoid contact with eyes
24Water-soluble zinc salts with the exception of zinc 4-hydroxy-benzenesulfonate and zinc pyrithione1% calculated as zinc
25Zinc 4-hydroxybenzene sulfonateDeodorants, antiperspirants and astringent lotions6% calculated as a percentage of anhydrous substanceAvoid contact with eyes
26Sodium monofluorophosphateOral hygiene products0.15 % calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15 %Contains ammonium monofluorophosphate
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
27Sodium monofluorophosphateOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains sodium monofluorophosphate
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
28Potassium monofluorophosphateOral Hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains potassium monofluorophosphate
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19thMarch 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
29Contains Calcium monofluorophosphateOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Calcium monofluorophosphate
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
30Calcium FluorideOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Calcium monofluorophosphate
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th January 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
31Sodium fluorideOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains Sodium fluoride
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
32Potassium fluorideOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains potassium fluoride
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
33Ammonium fluorideOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains ammonium fluoride
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
34Aluminium fluorideOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains aluminium fluoride
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
35Stannous fluorideOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains stannous fluoride
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
36Hexadecyl ammonium fluorideOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains hexadecyl ammonium fluoride
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
373-(N-Hexadecyl-N-2-hydroxyethylammonio) propylbis (2-hydroxyethyl) ammoniumdifluorideOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains 3-(N-Hexadecyl-N-2-hydroxyethylammonio) propylbis (2-hydroxyethyl) ammoniumdifluoride
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
38NN'N'-Tris(polyoxyethylene)-N-hexadecylpropylene-diamine dihydrofluorideOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains NN'N'-Tris(polyoxyethylene)-N-hexadecylpropylene-diamine dihydrofluoride
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
39Octadecenyl-ammonium fluorideOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains octadecenyl-ammonium fluoride
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th | March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
40Sodium fluorosilicateOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains sodium fluorosilicate
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
41Potassium fluorosilicateOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains potassium fluorosilicate
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
42Ammonium fluorosilicateOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains ammonium fluorosilicate
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
43Magnesium fluorosilicateOral hygiene products0.15% calculated as F. When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%Contains magnesium fluorosilicate
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
441,3-Bis (hydroxymethyl)imidazolidine-2-thione(a) Hair-care preparations(a) Up to 2%(a) Prohibited in aerosol dispensers (sprays)Contains 1,3-bis (hydroxymethyl)imidazolidine-2-thione
(b) Nail-care preparations(b) Up to 2%(b) The pH of the product as applied must be less than 4
[F145]

[F1Benzyl alcohol (*)

CAS No 100-51-6]

[F1(a) Solvent ]

[F1(b)

The presence of the substance must be indicated in the list of ingredients referred to in regulation 12(2) when its concentration exceeds:

— 0.001% in leave-on products

— 0.01% in rinse-off products]

[F1(b) fragrance/ aromatic compositions/their raw materials]
466-methylcoumarinOral hygiene products0.003%
47Nicomethanol hydrofluorideOral hygiene products0.15% calculated as FContains nicomethanol hydrofluoride
When mixed with other fluorine compounds permitted under this Schedule, total F concentration must not exceed 0.15%For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
48Silver nitrateSolely for products intended for colouring eyelashes and eyebrows4%— Contains silver nitrate
— Rinse the eyes immediately if product comes into contact with them
49Selenium disulfideAntidandruff shampoos1%— Contains selenium disulphide
— Avoid contact with eyes or damaged skin
50Aluminium zirconium chloride hydroxide complexes AlxZr(OH)yClz and the aluminium zirconium chloride hydroxide glycine complexesAntiperspirants20% as anhydrous aluminium zirconium chloride hydroxide 5.4% as zirconium1. The ratio of the number of aluminium atoms to that of zirconium atoms must be between two and 10Do not apply to irritated or damaged skin
2. The ratio of the number of (Al + Zr) atoms to that of chlorine atoms must be between 0.9 and 2.1
3. Prohibited in aerosol dispensers (sprays)
51Quinolin-8-ol and bis (8-hydroxy-quinolium) sulphateStabilizer for hydrogen peroxide in rinse-off hair-care preparations0.3 % calculated as base
Stabilizer for hydrogen peroxide in non-rinse-off hair-care preparations0.03 % calculated as base
52MethanolDenaturant for ethanol and isopropyl alcohol5 % calculated as a percentage of ethanol and isopropyl alcohol
53Etidronic acid and its salts (1-hydroxyethylidene-di-phosphonic acid and its salts)(a) Hair-care1.5% expressed as etidronic acid
(b) Soap0.2% expressed as etidronic acid
541-Phenoxy-propan-2-olRinse-off products only2%Prohibited in oral hygiene products
As a preservative, see Schedule 6, Part I, No 43
55Omitted
56Magnesium fluorideDental hygiene products0.15% calculated as F. When mixed with other flourine compounds permitted under this Schedule, total F concentration must not exceed 0.15%.Contains magnesium fluoride
For any toothpaste containing 0.1 to 0.15% fluoride unless it is already labelled as contra-indicated for children (e.g. “for adult use only”) the following labelling is obligatory from 19th March 2009:
“Children of 6 years and younger: use a pea sized amount for supervised brushing to minimise swallowing. In case of intake of fluoride from other sources consult a dentist or doctor.”
57Strontium chloride hexahydrate(a) Toothpaste3.5% calculated as strontium. When mixed with other permitted strontium products the total strontium content must not exceed 3,5 %Contains strontium chloride. Frequent use by children is not advisable
(b) Shampoo and face care products2,1 %, calculated as strontium. When mixed with other permitted strontium products the total strontium content must not exceed 2,1 %
58Strontium acetate hemihydrateToothpaste3.5% calculated as strontium. When mixed with other permitted strontium products the total strontium content must not exceed 3,5 %Contains strontium acetate. Frequent use by children is not advisable
59Talc: Hydrated magnesium silicate(a) Powdery products intended to be used for children under three years of ageKeep powder away from children's nose and mouth
(b) other products
60Fatty acid dialkylamides and dialkanolamidesMaximum secondary amine content: 0.5%— Do not use with nitrosating systems
— Maximum secondary amine content: 5% (applies to raw materials)
— Maximum nitrosamine content: 50 μg/kg
— Keep in nitrite-free containers
61Monoalkylamines, monoalkanolamines and their saltsMaximum secondary amine content: 0.5%— Do not use with nitrosating systems
— Minimum purity: 99 %
— Maximum secondary amine content: 0,5 % (applies to raw materials)
— Maximum nitrosamine content: 50 μg/kg
— Keep in nitrite-free containers
62Trialkylamines, trialkanolamines and their salts(a) Non-rinse-off products(a) 2.5%(a) (b)
(b) Other products— Do not use with nitrosating systems
— Minimum purity: 99%
— Maximum secondary amine content: 0.5% (applies to raw materials)
— Maximum nitrosamine content: 50 μg/kg
— Keep in nitrite-free containers
63Strontium hydroxidepH-regulator in depilatory products3.5% calculated as strontiumpH value not to exceed 12.7— Keep out of reach of children
— Avoid contact with the eyes
64Strontium peroxideRinse-off hair care preparations professional use4.5 % calculated as strontium in the ready-for-use preparationAll products must meet the hydrogen peroxide release requirements— Avoid contact with eyes
— Rinse eyes immediately if product comes into contact with them
— For professional use only
— Wear suitable gloves
65Benzalkonium Chloride, bromide and saccharinate(a) Rinse-off hair (head) care products(a) 3% (as benzalkonium chloride(a) In the final products the concentrations of benzalkonium chloride, bromide and saccharinate with an alkyl chain of C14, or less must not exceed 0,1 % (as benzalkonium chloride)(a) Avoid contact with the eyes
(b) Other products(b) 0.1% (as benzalkonium chloride)(b) Avoid contact with the eyes
66Polyacrylamides(a) Body-care leave-on products(a) Maximum residual acrylamide content 0.1 mg/kg
(b) Other cosmetic products(b) Maximum residual acrylamide content 0.1kg/mg
67Amyl cinnamal (CAS No 122-40-7)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
F4. . .F4. . .F4. . .
69Cinnamyl alcohol (CAS No 104-54-1)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
70Citral (CAS No 5392-40-5)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
71Eugenol (CAS No 97-53-0)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
[F172]

[F1Hydroxycitronellal

CAS No 107-75-5]

[F1(a) Oral products ]

[F1(a) (b)

The presence of the substance

must be indicated in the list of

ingredients referred to in

regulation 12(2) when its concentration

exceeds:

— 0.001% in leave-on products

— 0.01% in rinse-off products]

[F1(b) Other products ] [F1(b) 1.0%]
[F173]

[F1Isoeugenol

CAS No 97-54-1]

[F1(a) Oral products ]

[F1(a) (b)

The presence of the substance

must be indicated in the list of

ingredients referred to in

regulation 12(2) when its concentration

exceeds:

— 0.001% in leave-on products

— 0.01% in rinse-off products]

[F1(b) Other products] [F1(b) 0.02%]
74Amyl cinnamyl alcohol (CAS No 101-85-9)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
75Benzyl salicylate (CAS No 118-58-1)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
76Cinnamal (CAS No 104-55-2)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
77Coumarin (CAS No 91-64-5)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
78Geraniol (CAS No 106-24-1)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
79Hydroxy-methylpentylcyclohexenecarboxaldehyde (CAS No 31906-04-4)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
80Anisyl alcohol (CAS No 105-13-5)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
81Benzyl cinnamate (CAS No 103-41-3)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
82Farnesol (CAS No 4602-84-0)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
832-(4-tert-Butylbenzyl) propionaldehyde (CAS No 80-54-6)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
84Linalool (CAS No 78-70-6)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
85Benzyl benzoate (CAS No 120-51-4)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
86Citronellol (CAS No 106-22-9)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
87Hexylcinnam-aldehyde (CAS No 101-86-0)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
[F188]

[F1d-Limonene

CAS No 5989-27-5]

[F1The presence of the substance

must be indicated in the list of

ingredients referred to in

regulation 12(2) when its concentration

exceeds:

— 0.001% in leave-on products

— 0.01% in rinse-off products]

[F1Peroxide value less than

20 mmoles/L (**)]

[F189]

[F1Methyl 2-octynoate

CAS No 111-12-6

Methyl heptine

carbonate]

[F1(a) Oral products]

[F1(b) 0.01% when used alone

When present in combination

with methyl

octine carbonate, the

combined level in the

finished product should

not exceed 0.01% (of

which methyl octine

carbonate should not be

more than 0.002%)]

[F1(a) (b)

The presence of the substance

must be indicated in the list of

ingredients referred to in

regulation 12(2) when its concentration

exceeds:

— 0.001% in leave-on products

— 0.01% in rinse-off products]

[F1(b) Other products]
903-Methyl-4-(2,6,6-tri-methyl-2-cyclohexen-1-yl)-3-buten-2-one (CAS No 127-51-5)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
91Oak moss extract (CAS No 90028-68-5)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
92Tree moss extract (CAS No 90028-67-4)The presence of the substance must be indicated in the list of ingredients referred to in regulation 12 when its concentration exceeds
— 0.001% in leave-on products
— 0.01% in rinse-off products
93

2,4-Diamino-pyrimidine-3-oxide

(CAS No 74638-76-9)

Hair care formulations1.5%
94Benzoyl peroxideArtificial nail systems0.7% (after mixing)Professional use only— For professional use only
— Avoid skin contact
— Read directions for use carefully
95Hydroquinone methyletherArtificial nail systems0.02% (after mixing)Professional use only— For professional use only
— Avoid skin contact
— Read directions for use carefully
96Musk xylene (CAS No 81-15-2)All cosmetic products, with the exception of oral care products(a) 1.0% in fine fragrance
(b) 0.4% in eau de toilette
(c) 0.03% in other products
97Musk ketone (CAS No 81-14-1)All cosmetic products, with the exception of oral care products(a) 1.4% in fine fragrance
(b) 0.56% in eau de toilette
(c) 0.042% in other products
98Salicylic acid6(a) Rinse-off hair products(a) 3.0%Not to be used in preparations for children under three years of age, except for shampoos.Not to be used for children under three years of age7
(b) Other products(b) 2.0%For purposes other than inhibiting the development of micro-organisms in the product.
This purpose has to be apparent from the presentation of the product.
99Inorganic sulfites and bisulfites8(a) Oxidative hair dye products(a) 0.67% (expressed as free SO2)For purpose other than inhibiting the development of micro-organisms in the product.
(b) Hair straightening products(b) 6.7% (expressed as free SO2)
(c) Self tanning products for the face(c) 0.45% (expressed as free SO2)This purpose has to be apparent from the presentation of the product.
(d) Other self tanning products(d) 0.40% (expressed as free SO2)
100

Triclocarban9

(CAS No 101-20-2)

Rinse-off products1.5%

Purity criteria:

3,3',4,4'-

Tetrachloroazobenzene

≤=1ppm: 3,3',4,4'- Tetrachloroazoxybenzene ≤=1ppm

For purposes other than inhibiting the development of micro-organisms in the product.
This purpose has to be apparent from the presentation of the product.
101

Zinc pyrithione10

(CAS No 13463-41-7)

Leave-on hair products0.1%For purposes other than inhibiting the development of micro-organisms in the product.
This purpose has to be apparent from the presentation of the product.
[F5102]

[F5Glyoxal (INCI)

(CAS No 107-22-2)]

[F50.01%]
[F2103]

[F2Abies alba cone oil and extract

CAS No 90028-76-5]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2104]

[F2Abies alba needle oil and extract

CAS No 90028-76-5]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2105]

[F2Abies pectinata needle oil and extract

CAS No 92128-34-2]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2106]

[F2Abies sibirica needle oil and extract

CAS No 91697-89-1]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2107]

[F2Abies balsamea needle oil and extract

CAS No 85085-34-3]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2108]

[F2Pinus mugo pumilio leaf and twig oil and extract

CAS No 90082-73-8]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2109]

[F2Pinus mugo leaf and twig oil

and extract

CAS No 90082-72-7]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2110]

[F2Pinus sylvestris leaf and twig oil and extract

CAS No 84012-35-1]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2111]

[F2Pinus nigra leaf and twig oil and extract

CAS No 90082-74-9]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2112]

[F2Pinus palustris leaf and twig oil and extract

CAS No 97435-14-8]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2113]

[F2Pinus pinaster leaf and twig oil and extract

CAS No 90082-75-0]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2114]

[F2Pinus pumila leaf and twig oil and extract

CAS No 97676-05-6]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2115]

[F2Pinus species leaf and twig oil and extract

CAS No 94266-48-5]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2116]

[F2Pinus cembra leaf and twig oil and extract

CAS No 92202-04-5]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2117]

[F2Pinus cembra leaf and twig

extract acetylated

CAS No 94334-26-6]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2118]

[F2Picea Mariana Leaf Oil and Extract

CAS No 91722-19-9]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2119]

[F2Thuja Occidentalis Leaf Oil and Extract

CAS No 90131-58-1]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2120]

[F2Thuja Occidentalis Stem Oil

CAS No 90131-58-1]

[F2Peroxide value less than 10 mmoles/L (*]
[F2121]

[F23-Carene

CAS No 13466-78-9

3,7,7-Trimethylbicyclo[

4.1.0]hept-3-ene

(isodiprene)]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2122]

[F2Cedrus atlantica wood oil and extract

CAS No 92201-55-3]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2123]

[F2Cupressus sempervirens leaf

oil and extract

CAS No 84696-07-1]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2124]

[F2Turpentine gum (Pinus spp.)

CAS No 9005-90-7]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2125]

[F2Turpentine oil and rectified oil

CAS No 8006-64-2]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2126]

[F2Turpentine, steam distilled (Pinus spp.)

CAS No 8006-64-2]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2127]

[F2Terpene alcohols acetates

CAS No 69103-01-1]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2128]

[F2Terpene hydrocarbons

CAS No 68956-56-9]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2129]

[F2Terpenes and terpenoids with

the exception of limonene (d-, l-, and dl-isomers) listed under reference numbers 88, 167 and 168 of Part 1 of this Schedule

CAS No 65996-98-7]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2130]

[F2Terpene terpenoids sinpine

CAS No 68917-63-5]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2131]

[F2α-Terpinene

CAS No 99-86-5

p-Mentha-1,3-diene]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2132]

[F2γ-Terpinene

CAS No 99-85-4

p-Mentha-1,4-diene]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2133]

[F2Terpinolene

CAS No 586-62-9

p-Mentha-1,4(8)-diene]

[F2Peroxide value less than 10 mmoles/L (*)]
[F2134]

[F2Acetyl hexamethyl indan

CAS No 15323-35-0

1,1,2,3,3,6-Hexamethylindan- 5-yl methyl ketone]

[F2(a) Leave-on products] [F2(a) 2%]
[F2(b) Rinse-off products]
[F2135]

[F2Allyl butyrate

CAS No 2051-78-7

2-Propenyl Butanoate]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2136]

[F2Allyl cinnamate

CAS No 1866-31-5

2-Propenyl 3-Phenyl-2-

propenoate]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2137]

[F2Allyl cyclohexylacetate

CAS No 4728-82-9

2-Propenyl Cyclohexaneacetate]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2138]

[F2Allyl cyclohexylpropionate

CAS No 2705-87-5

2-Propenyl 3-Cyclohexanepropanoate]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2139]

[F2Allyl heptanoate

CAS No 142-19-8

2-Propenyl heptanoate]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2140]

[F2Allyl caproate

CAS No 123-68-2

Allyl hexanoate]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2141]

[F2Allyl isovalerate

CAS No 2835-39-4

2-Propenyl 3-Methylbutanoate]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2142]

[F2Allyl octanoate

CAS No 4230-97-1

2-Allyl caprylate]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2143]

[F2Allyl phenoxyacetate

CAS No 7493-74-5

2-Propenyl Phenoxyacetate]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2144]

[F2Allyl phenylacetate

CAS No 1797-74-6

2-Propenyl Benzeneacetate]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2145]

[F2Allyl 3,5,5-trimethylhexanoate

CAS No 71500-37-3]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2146]

[F2Allyl cyclohexyloxyacetate

CAS No 68901-15-5]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2147]

[F2Allyl isoamyloxyacetate

CAS No 67634-00-8]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2148]

[F2Allyl 2-methylbutoxyacetate

CAS No 67634-01-9]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2149]

[F2Allyl nonanoate

CAS No 7493-72-3]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2150]

[F2Allyl propionate

CAS No 2408-20-0]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2151]

[F2Allyl trimethylhexanoate

CAS No 68132-80-9]

[F2Level of free allyl alcohol in the ester should be less than 0.1%]
[F2152]

[F2Allyl heptine carbonate

CAS No 73157-43-4

(allyl oct-2-ynoate)]

[F20.002%]

[F2This material should not be used in

combination with any other

2-alkynoic acid ester (e.g methyl heptine carbonate)]

[F2153]

[F2Amylcyclopentenone

CAS No 25564-22-1

2-Pentylcyclopent-2-en-1-one]

[F20.1%]
[F2154]

[F2Myroxylon balsamum var

pereirae. extracts and distillates

CAS No 8007-00-9

Balsam Peru oil, absolute and

anhydrol

(Balsam Oil Peru)]

[F20.4%]
[F2155]

[F24-tert.-Butyldihydrocinnamaldehyde

CAS No 18127-01-0

3-(4-tert-Butylphenyl)propionaldehyde]

[F20.6%]
[F2156]

[F2Cuminum cyminum fruit oil and extract

CAS No 84775-51-9]

[F2(a) Leave-on products] [F2(a) 0.4% of Cumin oil]
[F2(b) Rinse-off products]
[F2157]

[F2cis-Rose ketone-1 (**)

CAS No 23726-94-5

(Z)-1-(2,6,6-Trimethyl-

2-cyclohexen-1-yl)-2-

buten-1-one

(cis-α-Damascone)]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.02%]
[F2158]

[F2trans-Rose ketone-2 (**)

CAS No 23726-91-2

(E)-1-(2,6,6-Trimethyl-

1-cyclohexen-1-yl)-2-

buten-1-one

(trans-β-Damascone)]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.02%]
[F2159]

[F2trans-Rose ketone-5 (**)

CAS No 39872-57-6

(E)-1-(2,4,4-Trimethyl-

2-cyclohexen-1-yl)-2-

buten-1-one

(Isodamascone)]

[F20.02%]
[F2160]

[F2Rose ketone-4 (**)

CAS No 23696-85-7

1-(2,6,6-Trimethylcyclohexa-

1,3-dien-1-yl)-2-buten-1-one

(Damascenone)]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.02%]
[F2161]

[F2Rose ketone-3 (**)

CAS No 57378-68-4

1-(2,6,6-Trimethyl-3-

cyclohexen-1-yl)-2-

buten-l-one

(Delta-Damascone)]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.02%]
[F2162]

[F2cis-Rose ketone-2 (**)

CAS No 23726-92-3

1-(2,6,6-Trimethyl-l-cyclohexen-

1-yl)-2-

buten-l-one

(cis-β-Damascone)]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.02%]
[F2163]

[F2trans-Rose ketone-1 (**)

CAS No 24720-09-0

1-(2,6,6-Trimethyl-2-

cyclohexen-1-yl)-2-

buten-l-one

(trans-α-Damascone)]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.02%]
[F2164]

[F2Rose ketone-5 (**)

CAS No 33673-71-1

1-(2,4,4-Trimethyl-2-

cyclohexen-1-yl)-2-

buten-l-one]

[F20.02%]
[F2165]

[F2trans-Rose ketone-3 (**)

CAS No 71048-82-3

1-(2,6,6-Trimethyl-3-

cyclohexen-1-yl)-2-

buten-l-one

(trans-delta-Damascone)]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.02%]
[F2166]

[F2trans-2-hexenal

CAS No 6728-26-3]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.002%]
[F2167]

[F2l-Limonene

CAS No 5989-54-8

(S)-p-Mentha-1,8-diene]

[F2Peroxide value less than

20 mmoles/L (*)]

[F2168]

[F2dl-Limonene (racemic)

CAS No 138-86-3

1,8(9)-p-Menthadiene;

p-Mentha-1,8-diene

(Dipentene)]

[F2Peroxide value less than

20 mmoles/L (*)]

[F2169]

[F2Perillaldehyde

CAS No 2111-75-3

p-Mentha-1,8-dien-7-al]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.1%]
[F2170]

[F2Isobergamate

CAS No 68683-20-5

Menthadiene-7- methyl formate]

[F20.1%]
[F2171]

[F2Methoxy dicyclopentadiene

carboxaldehyde

CAS No 86803-90-9

Octahydro-5-methoxy-

4,7-Methano-1H-indene-

2-carboxaldehyde]

[F20.5%]
[F2172]

[F23-methylnon-2-enenitrile

CAS No 53153-66-5]

[F20.2%]
[F2173]

[F2Methyl octine carbonate

CAS No 111-80-8

Methyl non-2-ynoate]

[F2(a) Oral products]
[F2(b) Other products]

[F2(b) 0.002% when used alone

When present in

combination with methyl heptine

carbonate, the

combined level in the finished

product should

not exceed 0.01%

(of which methyl octine carbonate

should not be

more than

0.002%)]

[F2174]

[F2Amylvinylcarbinyl acetate

CAS No 2442-10-6

1-Octen-3-yl acetate]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.3%]
[F2175]

[F2Propylidenephthalide

CAS No 17369-59-4

3-Propylidenephthalide]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.01%]
[F2176]

[F2Isocyclogeraniol

CAS No 68527-77-5

2,4,6-Trimethyl-3-

cyclohexene-1-methanol]

[F20.5%]
[F2177]

[F22-Hexylidene cyclopentanone

CAS No 17373-89-6]

[F2(a) Oral products]
[F2(b) 0.01 %] [F2(b) 0.06%]
[F2178]

[F2Methyl heptadienone

CAS No 1604-28-0

6-Methyl-3,5-heptadien-2-one]

[F2(a) Oral products]
[F2(b) Other products] [F2(b) 0.002%]
[F2179]

[F2p-methylhydrocinnamic

aldehyde

CAS No 5406-12-2

Cresylpropionalde-hyde

p-Methyldihydrocinnamaldehyde]

[F20.2%]
[F2180]

[F2Liquidambar orientalis

Balsam oil and extract

CAS No 94891-27-7

(styrax)]

[F20.6%]
[F2181]

[F2Liquidambar styraciflua

balsam oil and extract

CAS No 8046-19-3

(styrax)]

[F20.6%]
[F2182]

[F2Acetyl hexamethyl tetralin

CAS No 21145-77-7

CAS No 1506-02-1

1-(5,6,7,8-Tetrahydro-

3,5,5,6,8,8-hexamethyl-

2-naphthyl)ethan-1-one

(AHTN)]

[F2All cosmetic products,

with the exception of

oral products]

[F2(a) leave-on products:

0.1%

except:

hydro

alcoholic products:

1%

fine fragrance:

2.5%

fragrance cream:

0.5%

(b) rinse-off products:

0.2%]

[F2183]

[F2Commiphora erythrea engler var. glabrescens engler gum extract and oil

CAS No 93686-00-1]

[F20.6%]
[F2184]

[F2Opopanax chironium resin

CAS No 93384-32-8]

[F20.6%]
[F6185

Toluene

(CAS No 108-88-3)

(EC No 203-625-9)

Nail products25%

Keep out of reach of children

To be used by adults only

186

Diethylene glycol (DEG) (CAS No 111-46-6)

(EC No 203-872-2)

2,2’-oxydiethanol

Traces in ingredients0.1%
187

Butoxydiglycol

(CAS No 112-34-5)

(EC No 203-961-6)

diethylene glycol monobutyl ether (DEGBE)

Solvent in hair dye products9%No use in aerosol dispensers (sprays)
188

Butoxyethanol

(CAS No 111-76-2)

(EC No 203-905-0)

ethylene glycol monobutyl ether (EGBE)

Solvent in oxidative hair dye products4.0%No use in aerosol dispensers (sprays)
Solvent in non-oxidative hair dye products2.0%No use in aerosol dispensers (sprays)]
[F3189

Trisodium 5-hydroxy-1-(4-sulphophenyl) -4-(4-sulphophenylazo) pyrazole-3-carboxylate and aluminium lake (11)

Acid Yellow 23

CAS 1934-21-0

EINECS 217-699-5

Acid Yellow 23 Aluminum lake

CAS 12225-21-7

EINECS 235-428-9

CI 19140

Hair dye substance in non-oxidative hair dye products 0.5%
190

Benzenemethanaminium, Nethyl-N-[4-[[4-[ethyl-[(3-sulfophenyl)-methyl]-amino]-phenyl] [2-sulfophenyl)-methylene]-2,5-cyclohexadien-1-ylidene]-3-sulfo, inner salt, disodium salt and its ammonium and aluminium salts (11)

Acid Blue 9

CAS 3844-45-9

EINECS 223-339-8

Acid Blue 9 Ammonium salt

CAS 2650-18-2

EINECS 220-168-0

Acid Blue 9 Aluminum lake

CAS 68921-42-6

EINECS 272-939-6

CI 42090

Hair dye substance in non-oxidative hair dye products0.5%
191

Disodium 6-hydroxy-5-[(2-methoxy-4-sulphonato-m-tolyl) azo]naphthalene-2-sulphonate (11)

Curry Red

CAS 25956-17-6

EINECS 247-368-0

CI 16035

Hair dye substance in non-oxidative hair dye products0.4%
192

Trisodium 1-(1-naphthylazo)-2-hydroxynaphthalene-4′,6,8-trisulphonate and aluminium lake (11)

Acid Red 18

CAS 2611-82-7

EINECS 220-036-2

Acid Red 18 Aluminum lake

CAS 12227-64-4

EINECS 235-438-3

CI 16255

Hair dye substance in non-oxidative hair dye products0.5%
193

Hydrogen 3,6-bis(diethylamino)-9-(2,4-disulphonatophenyl) xanthylium, sodium salt (11)

Acid Red 52

CAS 3520-42-1

EINECS 222-529-8

CI 45100

(a) Hair dye substance in oxidative hair dye products

(a) After mixing under oxidative conditions the maximum concentration applied to hair must not exceed 1.5%.

(a) The mixing ratio must be printed on the label.

(b) Hair dye substance in non-oxidative hair dye products

(b) 0.6%

194

Disodium 5-amino-4-hydroxy-3-(phenylazo)naphthalene-2,7-disulphonate (11)

Acid Red 33

CAS 3567-66-6

EINECS 222-656-9

CI 17200

Hair dye substance in non-oxidative hair dye products

0.5%

195

Sodium 1-amino-4-(cyclohexylamino)-9,10-dihydro-9,10-dioxoanthracene-2-sulphonate (11)

Acid Blue 62

CAS 4368-56-3

EINECS 224-460-9

CI 62045

Hair dye substance in nonoxidative hair dye products

0.5%

— Do not use with nitrosating systems

— Maximum nitrosamine content: 50 μg/kg

— Keep in nitrite-free containers

196

1-[(2′,-Methoxyethyl) amino]-2′,-nitro-4-[di-(2′,-hydroxyethyl) amino] benzene (11)

HC Blue No 11

CAS 23920-15-2

EINECS 459-980-7

Hair dye substance in nonoxidative hair dye products

2.0%

— Do not use with nitrosating systems

— Maximum nitrosamine content: 50 μg/kg

— Keep in nitrite-free containers

197

1,5-Di-(ß-hydroxyethylamino)-2-nitro-4-chlorobenzene (11)

HC Yellow No 10

CAS 109023-83-8

EINECS 416-940-3

Hair dye substance in nonoxidative hair dye products

0.1%

— Do not use with nitrosating systems

— Maximum nitrosamine content: 50 μg/kg

— Keep in nitrite-free containers

198

3-Methylamino-4-nitrophenoxyethanol (11)

3-Methylamino-4-nitrophenoxyethanol (INCI)

CAS 59820-63-2

EINECS 261-940-7

Hair dye substance in non-oxidative hair dye products

0.15%

— Do not use with nitrosating systems

— Maximum nitrosamine content: 50 μg/kg

— Keep in nitrite-free containers

199

2,2′,-[[4-[(2-hydroxyethyl) amino]-3-nnitrophenyl]imino]bisethanol (11)

HC Blue No 2

CAS 33229-34-4

EINECS 251-410-3

Hair dye substance in non-oxidative hair dye products

2.8%

— Do not use with nitrosating systems

— Maximum nitrosamine content: 50 μg/kg

— Keep in nitrite-free containers

Can cause allergic reaction

200

1-Propanol, 3-[[4-[bis(2-hydroxyethyl)amino]-2-nitrophenyl]amino] (11) HC Violet No 2

CAS 104226-19-9

EINECS 410-910-3

Hair dye substance in non-oxidative hair dye products

2.0%

— Do not use with nitrosating systems

— Maximum nitrosamine content: 50 μg/kg

— Keep in nitrite-free containers

Can cause allergic reaction

201

Phenol, 2-chloro-6-(ethylamino)-4-nitro- (11)

2-Chloro-6-ethylamino-4-nitrophenol

CAS 131657-78-8

EINECS 411-440-1

Hair dye substance in non-oxidative hair dye products

3.0%

— Do not use with nitrosating systems

— Maximum nitrosamine content: 50 μg/kg

— Keep in nitrite-free containers

Can cause allergic reaction
202

4,4′,-[1,3-Propanediylbis(oxy)]-bisbenzene-1,3-diamine and its tetrahydrochloride salt (11)

1,3-bis-(2,4-Diaminophenoxy)-propane

CAS 81892-72-0

EINECS 279-845-4

1,3-bis-(2,4-Diaminophenoxy)-propane HCl

CAS 74918-21-1

EINECS 278-022-7

(a) Hair dye substance in oxidative hair dye products

(a) After mixing under oxidative conditions the maximum concentration applied to hair must not exceed 1.2 % calculated as free base (1.8 % as tetrahydrochloride salt).

(a) The mixing ratio must be printed on the label.

(b) Hair dye substance in non-oxidative hair dye products

(b) 1.2 % as free base (1.8 % as tetrahydrochloride salt)

For (a) and (b): Can cause allergic reaction
203

6-Methoxy-N2-methyl-2,3-pyridinediamine hydrochloride and dihydrochloride salt (11)

6-Methoxy-2-methylamino-3-aminopyridine HCl

CAS 90817-34-8 (HCl)

CAS 83732-72-3 (2HCl) EINECS 2180-622-9 2HC1

(a) Hair dye substance in oxidative hair dye products

(a) After mixing under oxidative conditions the maximum concentration applied to hair must not exceed 0.68 % calculated as free base (1.0 % as dihydrochloride).

For (a) and (b):

— Do not use with nitrosating systems

— Maximum nitrosamine content: 50 μg/kg

— Keep in nitrite-free containers

(a) The mixing ratio must be printed on the label.

(b) Hair dye substance in non-oxidative hair dye

(b) 0.68 % as free base (1.0 % as dihydrochloride)

For (a) and (b):

Can cause allergic reaction

204

2,3-Dihydro-1H-indole-5,6-diol and its hydrobromide salt (11)

Dihydroxyindoline

CAS 29539-03-5

Dihydroxyindoline HBr

CAS 138937-28-7

EINECS 421-170-6

Hair dye substance in non-oxidative hair dye products

2.0%

Can cause allergic reaction
205

4-Hydroxypropylamino-3-nitrophenol (11)

4-Hydroxypropylamino-3-nitrophenol (INCI)

CAS 92952-81-3

EINECS 406-305-9

(a) Hair dye substance in oxidative hair dye products

(a) After mixing under oxidative conditions the maximum concentration applied to hair must not exceed 2.6 % calculated as free base.

(a) The mixing ratio must be printed on the label.

(b) Hair dye substance in non-oxidative hair dye products

(b) 2.6%

For (a) and (b):

— Do not use with nitrosating systems

— Maximum nitrosamine content: 50 μg/kg

— Keep in nitrite-free containers]

Textual Amendments

F1Words in Sch. 4 Pt. 1 substituted (and, in the case of the footnote, inserted) (4.4.2009) by The Cosmetic Products (Safety) (Amendment No. 2) Regulations 2008 (S.I. 2008/2566), regs. 1(1), 2(d)(ii), Sch. Pt. 1

F6Words in Sch. 4 Pt. 1 inserted (5.11.2009 for specified purposes, 5.2.2010 in so far as not already in force) by The Cosmetic Products (Safety) (Amendment No.2) Regulations 2009 (S.I. 2009/1346), regs. 1(5), 2(c), Sch. 2

Combination RulesU.K.

A. Where a cosmetic product contains two or more substances to which this Combination Rule applies, the concentration in the product of each of those substances shall be such that the sum of the relevant quotients for those substances (as defined in Rule C below) shall not exceed 1.

B. Where a cosmetic product contains the substances to which this Combination Rule applies, the concentration in the product of each of those substances shall be such that the sum of the relevant quotients for those substances (as defined in Rule C below) shall not exceed 2; but the concentration of each substance shall not in any event exceed the limit specified for those substance in respect of the product in column 4 above.

C. The relevant quotient for each substance is the actual concentration of the substance in the product divided by the maximum concentration specified for the substance in respect of the product in Column 4 of this Schedule.

PART 2U.K.SUBSTANCES LISTED IN PART 2 OF ANNEX III TO THE DIRECTIVE WHICH ARE PROVISONALLY ALLOWED

Restrictions
Reference numberSubstanceField of application and/or useMaximum authorised concentration in the finished cosmetic productOther limitations and requirementsConditions of use and warnings which must be printed on the labelAllowed until
abcdefg
1omitted
2omitted
34-Amino-3-nitrophenol (CAS No 610-81-1) and its salts(a) Oxidising colouring agents for hair dyeing(a) 3.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.5%(a) (b) Can cause allergic reaction [F731.12.2010]
(b) Non-oxidising colouring agents for hair dyeing(b) 3.0%
42,7-Naphthalenediol (CAS No 582-17-2) and its saltsOxidising colouring agents for hair dyeing1.0%In combination with hydrogen peroxide the maximum use concentration upon application is 0.5%[F731.12.2010]
5m-Aminophenol (CAS No 591-27-5) and its saltsOxidising colouring agents for hair dyeing2.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.0%Can cause allergic reaction[F731.12.2010]
62,6-Dihydroxy-3-4-dimethylpyridine (CAS No 84540-47-6 and its salts)Oxidising colouring agents for hair dyeing2.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.0%Can cause allergic reaction[F731.12.2010]
7F8. . .
8omitted
9F8. . .
10Hydroxyethyl-2-nitro-p-toluidine (CAS No 100418-33-5) and its salts(a) Oxidising colouring agents for hair dyeing(a) 2.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.0%(a) (b) Can cause allergic reaction[F731.12.2010]
(b) Non-oxidising colouring agents for hair dyeing(b) 1.0%
112-Hydroxyethyl-picramic acid (CAS No 99610-72-7) and its salts(a) Oxidising colouring agents for hair dyeing(a) 3.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.5%(a) (b) Can cause allergic reaction[F731.12.2010]
(b) Non-oxidising colouring agents for hair dyeing(b) 2.0%
12p-Methylamino-phenol (CAS No 150-75-4) and its saltsOxidising colouring agents for hair dyeing3.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.5%Can cause allergic reaction[F731.12.2010]
13omitted
14F8. . .
15omitted
16HC Blue No 12 (CAS No 104516-93-0) and its salts(a) Oxidising colouring agents for hair dyeing(a) 1.5%In combination with hydrogen peroxide the maximum use concentration upon application is 0.75%(a) (b) Can cause allergic reaction[F731.12.2010]
(b) Non-oxidising colouring agents for hair dyeing(b) 1.5%
17omitted
18F8. . .
193-Amino-2,4-dichlorophenol (CAS No 61693-43-4) and its saltsOxidising colouring agents for hair dyeing2.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.0%Can cause allergic reaction[F731.12.2010]
20Phenyl methyl pyrazolone (CAS No 89-25-8) and its saltsOxidising colouring agents for hair dyeing0.5%In combination with hydrogen peroxide the maximum use concentration upon application is 0.25%[F731.12.2010]
212-Methyl-5-hydroxyethylaminophenol (CAS No 55302-96-0) and its saltsOxidising colouring agents for hair dyeing2.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.0%Can cause allergic reaction[F731.12.2010]
22Hydroxybenzo-morpholine (CAS No 26021-57-8) and its saltsOxidising colouring agents for hair dyeing2.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.0%Can cause allergic reaction[F731.12.2010]
23omitted
24F8. . .
252,6-Dimethoxy-3,5-pyridinediamine (CAS No 85679-78-3) and its saltsOxidising colouring agents for hair dyeing0.5%In combination with hydrogen peroxide the maximum use concentration upon application is 0.25%Can cause allergic reaction[F731.12.2010]
26HC Orange No 2 (CAS No 85765-48-6) and its saltsNon-oxidising colouring agents for hair dyeing1.0%[F731.12.2010]
27HC Violet No 1 (CAS No 82576-75-8) and its salts(a) Oxidising colouring agents for hair dyeing(a) 0.5%In combination with hydrogen peroxide the maximum use concentration upon application is 0.25%[F731.12.2010]
(b) Non-oxidising colouring agents for hair dyeing(b) 0.5%
28F8. . .
292-Hydroxy-ethylamino-5-nitro-anisole (CAS No 66095-81-6) and its saltsNon-oxidising colouring agents for hair dyeing1.0%[F731.12.2010]
30omitted
31HC Red No 13 (CAS No 94158-13-1) and its salts(a) Oxidising colouring agents for hair dyeing(a) 2.5%In combination with hydrogen peroxide the maximum use concentration upon application is 1.25%[F731.12.2010]
(b) Non-oxidising colouring agents for hair dyeing(b) 2.5%
321,5-Naphthalenediol (CAS No 83-56-7) and its saltsOxidising colouring agents for hair dyeing1.0%In combination with hydrogen peroxide the maximum use concentration upon application is 0.5%[F731.12.2010]
33Hydroxypropyl bis (N-hydroxyethyl-p-phenylenediamine) (CAS No 128729-30-6) and its saltsOxidising colouring agents for hair dyeing3.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.5%Can cause allergic reaction[F731.12.2010]
34o-Aminophenol (CAS No 95-55-6) and its saltsOxidising colouring agents for hair dyeing2.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.0%[F731.12.2010]
354-Amino-2-hydroxytoluene (CAS No 2835-95-2) and its saltsOxidising colouring agents for hair dyeing3.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.5%[F731.12.2010]
362,4-Diaminophen-oxyethanol (CAS No 66422- 95-5) and its saltsOxidising colouring agents for hair dyeing4.0%In combination with hydrogen peroxide the maximum use concentration upon application is 2.0%[F731.12.2010]
372-Methylresorcinol (CAS No 608-25-3) and its saltsOxidising colouring agents for hair dyeing2.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.0%[F731.12.2010]
384-Amino-m-cresol (CAS No 2835-99-6) and its saltsOxidising colouring agents for hair dyeing3.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.5%[F731.12.2010]
392-Amino-4-hydroxyethylaminoanisole (CAS No 83763-47-7) and its saltsOxidising colouring agents for hair dyeing3.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.5%[F731.12.2010]
40omitted
41omitted
42omitted
43omitted
44Hydroxyethyl-3,4-methylene-dioxyaniline(CAS No 81329-90-0) and its saltsOxidising colouring agents for hair dyeing3.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.5%[F731.12.2010]
45omitted
46omitted
47F8. . .
483-Nitro-p-hydroxyethyla-minophenol (CAS No 65235-31-6) and its salts(a) Oxidising colouring agents for hair dyeing(a) 6.0%In combination with hydrogen peroxide the maximum use concentration upon application is 3.0%[F731.12.2010]
(b) Non-oxidising colouring agents for hair dyeing(b) 6.0%
494-Nitrophenyl aminoethylurea (CAS No 27080-42-8) and its salts(a) Oxidising colouring agents for hair dyeing(a) 0.5%In combination with hydrogen peroxide the maximum use concentration upon application is 0.25%[F731.12.2010]
(b) Non-oxidising colouring agents for hair dyeing(b) 0.5%
50HC Red No 10 + HC Red No 11 (CAS No 95576-89-9+ 95576-92-4) and its salts(a) Oxidising colouring agents for hair dyeing(a) 2.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.0%[F731.12.2010]
(b) Non-oxidising colouring agents for hair dyeing(b) 1.0%
51omitted
52omitted
53omitted
54omitted
552-Chloro-6-ethylamino-4-nitrophenol (CAS No 131657-78-8) and its salts(a) Oxidising colouring agents for hair dyeing(a) 3.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.5%[F731.12.2010]
F9. . .F9. . .
562-Amino-6-chloro-4-nitrophenol (CAS No 6358-09-4) and its salts(a) Oxidising colouring agents for hair dyeing(a) 2.0%In combination with hydrogen peroxide the maximum use concentration upon application is 1.0%[F731.12.2010]
(b) Non-oxidising colouring agents for hair dyeing(b) 2.0%
57F8. . .
58F8. . .
59Ponceau SX (CAS No 4548-53-2) (CI 14700) and its saltsNon-oxidising colouring agents for hair dyeing2.0%31.12.2009
60Basic Violet 14 (CAS No 632-99-5) (CI 42510) and its salts(a) Oxidising colouring agents for hair dyeing(a) 0.3%In combination with hydrogen peroxide the maximum use concentration upon application is 0.15%31.12.2009

Textual Amendments

F8Words in Sch. 4 Pt. 2 revoked (14.10.2009 for specified purposes, 15.5.2010 for remaining purposes) by The Cosmetic Products (Safety) (Amendment No.3) Regulations 2009 (S.I. 2009/2562), regs. 1(2), 2(b)(ii)(bb)

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