SCHEDULE 2METHODS OF ANALYSIS

PART I

1.    General

(a)When two or more methods are prescribed in this part of this Schedule determine a component of a fertiliser the choice of the method shall, exceeds where otherwise indicated, be left to the agricultural analyst concerned; the method used must however be indicated in the certificate of analysis.

(b)Any reference to water in this Schedule means purified water as defined in the European Pharmacopoeia.

2.    Reagents and Apparatus

(a)All reagents used shall be of analytical quality.

(b)For the determination of any form of nitrogen, water must be free of a nitrogenous compounds and carbon dioxide.

(c)Solutions for which no solvents are prescribed must be aqueous.

(d)Only special instruments or apparatus requiring special standards a mentioned in the descriptions of the methods of analysis.

3.    Methods of Analysis

Preparation of the sample for analysis

Determination of ammoniacal nitrogen

Determination of nitrate and ammoniacal nitrogen-Ulsch method

bdetermination of nitrate and ammoniacal nitrogen-Arnd method

cDetermination of nitrate and ammoniacal nitrogen-Devarda method

Determination of nitrogen in calcium cyanamide-in the absence of nitrate

bDetermination of nitrogen in calcium cyanamide-in the presence of nitrate

Determination of total nitrogen in urea

Determination of cyanamide nitrogen

Determination of biuret in urea

Determination of different forms of nitrogen-in the presence of cyanamide nitrogen

bDetermination of different forms of nitrogen-in the absence of cyanamide nitrogen

Extraction of total phosphorus-by mineral acids

bExtraction of phosphorus-by 2% formic acid

cExtraction of phosphorus-by 2% citric acid

dExtraction of phosphorus-by neutral ammonium citrate

eExtraction of phosphorus-by alkaline ammonium citrate (Petermann’s method) at 65°C

fExtraction of phosphorus-by alkaline ammonium citrate (Petermann’s method) at ambient temperature

gExtraction of phosphorus-by alkaline ammonium citrate (Joulie’s method)

hExtraction of phosphorus-by water

Determination of extracted phosphorus

Determination of water-soluble potassium

Determination of water-soluble magnesium-atomic absorption spectro-photometric method

bDetermination of water-soluble magnesium-EDTA method

Determination of total magnesium-atomic absorption spectrophoto-metric method

bDetermination of total magnesium-EDTA method

Determination of chlorides, in the absence of organic matter

Determination of fineness of grinding—dry method

bDetermination of fineness of grinding-for soft natural phosphates

Methods of analysis and test procedures for ammonium nitrate fertiliser containing more than 28% nitrogen by weight

Methods for the application of thermal cycles

Determination of oil retention

Determination of the combustible ingredients

Determination of the pH value

Determination of particle size

Determination of the chloride content (as chloride ion)

Determination of copper