SCHEDULE 3Classification of and hazard warning signs for substances (including preparations) dangerous for carriage

PART ITABLE OF CHARACTERISTIC PROPERTIES, CLASSIFICATION AND HAZARD WARNING SIGNS

Column 1

Column 2

Column 3

Characteristic properties of the substance

Classification and category of danger

Hazard warning sign

A substance which—

  1. a

    has a critical temperature below 50°C or which at 50°C has a vapour pressure of more than 3 bars absolute; and

  2. b

    is carried at a pressure of more than 500 millibars above atmospheric pressure or in liquefied form,

other than a toxic gas or a flammable gas.

Non-flammable compressed gas.

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A substance which has a critical temperature below 50°C or which at 50°C has a vapour pressure of more than 3 bars absolute and which is toxic.

Toxic gas.

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A substance which has a critical temperature below 50°C or which at 50°C has a vapour pressure of more than 3 bars absolute and is flammable. (See Note 1)

Flammable gas.

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A liquid with a flash point of 55°C or below except a liquid which—

  1. a

    has a flash point equal to or more than 21°C and less than or equal to 55°C; and

  2. b

    when tested at 55°C in the manner described in Schedule 2 to the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations (Northern Ireland) 197555 does not support combustion.

(See Notes 1 and 2)

Flammable liquid.

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A solid which is readily combustible under conditions encountered in carriage or which may cause or contribute to fire through friction.

Flammable solid.

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A substance which is liable to spontaneous heating under conditions encountered in carriage or to heating in contact with air being then liable to catch fire.

Spontaneously combustible substance.

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A substance which in contact with water is liable to become spontaneously combustible or to give off a flammable gas.

Substance which in contact with water emits flammable gas

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A substance other than an organic peroxide which, although not necessarily combustible, may by yielding oxygen or by a similar process cause or contribute to the combustion of other material.

Oxidizing substance

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A substance which is—

  1. a

    an organic peroxide; and

  2. b

    an unstable substance which may undergo exothetmic self-accelerating decomposition.

Organic peroxide

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A substance known to be so toxic to man as to afford a hazard to health during carriage or which, in the absence of adequate data on human toxicity, is presumed to be toxic to man.

Toxic substance.

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A substance known to be toxic to man or, in the absence of adequate data on human toxicity, is presumed to be toxic to man but which is unlikely to afford a serious acute hazard to health during carriage.

Harmful substance.

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A substance which by chemical action will—

  1. a

    cause severe damage when in contact with living tissue; or

  2. b

    materially damage other freight or equipment if leakage occurs.

Corrosive substance.

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A substance which is listed in Part 2 of the approved carriage list and which may create a risk to the health or safety of persons in the conditions encountered in carriage whether or not it has any of the characteristic properties referred to above.

Other dangerous substance.

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Packages containing two or more dangerous substances which have different characteristic properties.

Mixed hazards.

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  • Note 1

    An aerosol which is flammable in accordance with paragraph 1 of Part II of Schedule 1 shall have the classification of a flammable gas. Other aerosols need not be classified as flammable gas or flammable liquid.

  • Note 2

    Viscous preparations which comply with the conditions in Part III shall not be required to be classified as flammable.