SCHEDULE 10Sampling and analysis for parameters other than radioactive substances in water bottled and labelled as “spring water” or “dŵr ffynnon” and bottled drinking water
PART 1General
Analysis of samples1
1
The food authority must ensure that each sample is analysed in accordance with Annex III to Directive 98/83 and this Schedule.
2
For each parameter specified in the first column of Table 1 in Part 2 of this Schedule the method of analysis is specified in the second column of that table.
3
For each parameter specified in the first column of Table 2 in Part 2 of this Schedule the method of analysis is one that is capable of—
a
measuring concentrations and values with the trueness and precision specified in the second and third columns of that table; and
b
detecting the parameter at the limit of detection specified in the fourth column of that table.
4
For hydrogen ion, the method of analysis must be capable of measuring a value with a trueness of 0.2pH unit and a precision of 0.2pH unit.
5
The method of analysis used for odour and taste parameters must be capable of measuring values equal to the parametric value with a precision of 1 dilution number at 25ºC.
6
For the purposes of this paragraph—
“limit of detection” (“terfyn canfod”) is—
- a
three times the relative within-batch standard deviation of a natural sample containing a low concentration of the parameter; or
- b
five times the relative within-batch standard deviation of a blank sample;
- a
“precision” (“trachywiredd”) (the random error) is twice the standard deviation (within a batch and between batches) of the spread of results about the mean;
“trueness” (“cywirdeb”) (the systematic error) is the difference between the mean value of the large number of repeated measurements and the true value.
Authorisation of alternative methods of analysis2
1
The Agency may authorise a method different from that set out in Part 2 of this Schedule if satisfied that it is at least as reliable.
2
An authorisation may be time-limited and may be revoked at any time.
Sampling and analysis by persons other than food authorities3
1
A food authority may enter into an arrangement for any person to take and analyse samples on its behalf.
2
A food authority must not enter into an arrangement under sub-paragraph (1) unless—
a
it is satisfied that the task will be carried out promptly by a person competent to perform it; and
b
it has made arrangements that ensure that any breach of these Regulations is communicated to it immediately, and any other result is communicated to it within 28 days.