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Commission Regulation (EU) No 231/2012Show full title

Commission Regulation (EU) No 231/2012 of 9 March 2012 laying down specifications for food additives listed in Annexes II and III to Regulation (EC) No 1333/2008 of the European Parliament and of the Council (Text with EEA relevance)

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E 954 SACCHARIN AND ITS Na. K AND Ca SALTSU.K.

(i)SACCHARINU.K.

Synonyms
Definition
Einecs201-321-0
Chemical name3-Oxo-2,3dihydrobenzo(d)isothiazol-1,1-dioxide
Chemical formulaC7H5NO3S
Molecular weight183,18
AssayNot less than 99 % and not more than 101 % of C7H5NO3S on the anhydrous basis
DescriptionWhite crystals or a white crystalline powder, odourless or with a faint, aromatic odour. Approximately between 300 and 500 times as sweet as sucrose
Identification
SolubilitySlightly soluble in water, soluble in basic solutions, sparingly soluble in ethanol
Purity
Loss on dryingNot more than 1 % (105 °C, 2 hours)
Melting range226 to 230 °C
Sulphated ashNot more than 0,2 % (expressed on dry weight basis)
Benzoic and salicylic acidTo 10 ml of a 1 in 20 solution, previously acidified with five drops of acetic acid, add three drops of an approximately molar solution of ferric chloride in water. No precipitate or violet colour appears
o-ToluenesulphonamideNot more than 10 mg/kg (expressed on dry weight basis)
p-ToluenesulphonamideNot more than 10 mg/kg (expressed on dry weight basis)
Benzoic acid p-sulphonamideNot more than 25 mg/kg (expressed on dry weight basis)
Readily carbonisable substancesAbsent
ArsenicNot more than 3 mg/kg (expressed on dry weight basis)
SeleniumNot more than 30 mg/kg (expressed on dry weight basis)
LeadNot more than 1 mg/kg (expressed on dry weight basis)

(ii)SODIUM SACCHARINU.K.

SynonymsSaccharin; Sodium salt of saccharin
Definition
Einecs204-886-1
Chemical nameSodium o-benzosulphimide; sodium salt of 2,3-dihydro-3-oxobenzisosulphonazole; oxobenzisosulphonazole; 1,2-benzisothiazolin-3-one-1, 1-dioxide sodium salt dihydrate
Chemical formulaC7H4NNaO3S·2H2O
Molecular weight241,19
AssayNot less than 99 % and not more than 101 % of C7H4NNaO3S on the anhydrous basis
DescriptionWhite crystals or a white crystalline efflorescent powder, odourless or with a faint odour. Approximately between 300 and 500 times as sweet as sucrose in dilute solutions
Identification
SolubilityFreely soluble in water, sparingly soluble in ethanol
Purity
Loss on dryingNot more than 15 % (120 °C, 4 hours)
Benzoic and salicylic acidTo 10 ml of a 1 in 20 solution, previously acidified with five drops of acetic acid, add three drops of an approximately molar solution of ferric chloride in water. No precipitate or violet colour appears
o-ToluenesulphonamideNot more than 10 mg/kg (expressed on dry weight basis)
p-ToluenesulphonamideNot more than 10 mg/kg (expressed on dry weight basis)
Benzoic acid p-sulphonamideNot more than 25 mg/kg (expressed on dry weight basis)
Readily carbonisable substancesAbsent
ArsenicNot more than 3 mg/kg (expressed on dry weight basis)
SeleniumNot more than 30 mg/kg (expressed on dry weight basis)
LeadNot more than 1 mg/kg (expressed on dry weight basis)

(iii)CALCIUM SACCHARINU.K.

SynonymsSaccharin; Calcium salt of saccharin
Definition
Chemical nameCalcium o-benzosulphimide; calcium salt of 2,3-dihydro-3-oxobenzisosulphonazole; 1,2-benzisothiazolin-3-one-1,1-dioxide calcium salt hydrate (2:7)
Einecs229-349-9
Chemical formulaC14H8CaN2O6S2·3½H2O
Molecular weight467,48
AssayNot less than 95 % of C14H8CaN2O6S2 on the anhydrous basis
DescriptionWhite crystals or a white crystalline powder, odourless or with a faint odour. Approximately between 300 and 500 times as sweet as sucrose in dilute solutions
Identification
SolubilityFreely soluble in water, soluble in ethanol
Purity
Loss on dryingNot more than 13,5 % (120 °C, 4 hours)
Benzoic and salicylic acidTo 10 ml of a 1 in 20 solution, previously acidified with five drops of acetic acid, add three drops of an approximately molar solution of ferric chloride in water. No precipitate or violet colour appears
o-ToluenesulphonamideNot more than 10 mg/kg expressed (on dry weight basis)
p-ToluenesulphonamideNot more than 10 mg/kg expressed (on dry weight basis)
Benzoic acid p-sulphonamideNot more than 25 mg/kg expressed (on dry weight basis)
Readily carbonisable substancesAbsent
ArsenicNot more than 3 mg/kg (expressed on dry weight basis)
SeleniumNot more than 30 mg/kg (expressed on dry weight basis)
LeadNot more than 1 mg/kg (expressed on dry weight basis)

(iv)POTASSIUM SACCHARINU.K.

SynonymsSaccharin; Potassium salt of saccharin
Definition
Einecs
Chemical namePotassium o-benzosulphimide; potassium salt of 2,3-dihydro-3-oxobenzisosulphonazole; potassium salt of 1,2-benzisothiazolin-3-one-1,1-dioxide monohydrate
Chemical formulaC7H4KNO3S·H2O
Molecular weight239,77
AssayNot less than 99 % and not more than 101 % of C7H4KNO3S on the anhydrous basis
DescriptionWhite crystals or a white crystalline powder, odourless or with a faint odour, having an intensely sweet taste, even in very dilute solutions. Approximately between 300 and 500 times as sweet as sucrose
Identification
SolubilityFreely soluble in water, sparingly soluble in ethanol
Purity
Loss on dryingNot more than 8 % (120 °C, 4 hours)
Benzoic and salicylic acidTo 10 ml of a 1 in 20 solution, previously acidified with five drops of acetic acid, add three drops of an approximately molar solution of ferric chloride in water. No precipitate or violet colour appears
o-ToluenesulphonamideNot more than 10 mg/kg (expressed on dry weight basis)
p-ToluenesulphonamideNot more than 10 mg/kg (expressed on dry weight basis)
Benzoic acid p-sulphonamideNot more than 25 mg/kg (expressed on dry weight basis)
Readily carbonisable substancesAbsent
ArsenicNot more than 3 mg/kg (expressed on dry weight basis)
SeleniumNot more than 30 mg/kg (expressed on dry weight basis)
LeadNot more than 1 mg/kg (expressed on dry weight basis)

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